Detrital Zircon Data from the Eastern Mixteca Terrane, Southern Mexico
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ABSTRACT Using the ion microprobe SHRIMP we have analysed zircons from the Ben Vuirich, Glen Kyllachy, Inchbae and Vagastie Bridge granites from the Scottish Caledonides, in an attempt to resolve the ages of inherited zircons shown to be present in these granites by previous conventional multigrain analyses. Middle Proterozoic age components were found in inherited zircons from all four granites. Late Proterozoic (900–1,100 Ma) components have been identified in zircons from the Glen Kyllachy and Ben Vuirich granites in the Grampian Highlands. A Late Archaean age has only been detected in one zircon from the Glen Kyllachy granite. The distribution of inherited components in the granite zircon populations could reflect fundamental divisions in the age composition of granite source rocks; however, detailed assessment of this possibility must await further ion microprobe analyses on zircons from many more granites. SHRIMP isotopic and U, Th and Pb analyses were made on successive shells of zoned zircon surrounding inherited cores from the Glen Kyllachy granite to monitor chemical changes during magmatic zircon growth. Results show that zircon shells have characteristic but significantly different Th, U and Pb concentrations. Magmatic zircon from the Vagastie Bridge granite also forms as clearly defined oscillatory zoned shells around unzoned nuclei of inherited zircon. However, the distinction between magmatic and inherited zircon in zircons from the Inchbae granite is less clear. Zircons from the Ben Vuirich granite occur as euhedral, magmatic zircons, or as rounded, subhedral, inherited zircon grains. A SHRIMP age of 597 ± 11 (2σ) Ma for euhedral magmatic zircon from this granite is identical, within the uncertainty, to the conventional multigrain zircon age of 590 ± 2 (2σ) Ma reported by Rogers et al. (1989) and confirms the conclusions of those authors that sedimentation of the Dalradian sequence took place in the Precambrian.
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Abstract The Epembe Complex is one of the Mesoproterozoic (~1200 Ma) carbonatite alkaline complexes situated along the southern margin of the Congo Craton in northwestern Namibia. Nepheline syenites and minor syenites constitute the main lithologies, cross-cut by a calcite-carbonatite dyke. In order to constrain zircon forming-processes and magma sources, cathodoluminescence (CL) imaging combined with trace elements (including REE) as well as Hf isotope compositions of zircon grains extracted from one syenite, five nepheline syenite samples and one carbonatite sample are presented. Syenite zircons are generally unaltered and are characterised by positively sloping REE patterns in a chondrite-normalised diagram, with positive Ce anomalies. Syenite zircon further displays significant negative Eu anomalies attributed to earlier plagioclase formation and fractionation. These features are consistent with zircon formation in a magmatic environment. In the nepheline syenite samples, two zircon types are recognised. Type 1 zircon is magmatic, with homogeneous-grey, unzoned and oscillatory-zoned domains in CL, while type 2 zircon underwent low temperature fluid alteration and displays a cloudy appearance. Type 2 zircon is characterised by enrichment in LREE, Nb and Ti when compared to magmatic type 1 zircon. Carbonatite zircon displays a variety of textures and variable chemical compositions suggestive of the presence of both xenocrystal, altered and magmatic zircon. The Hf concentration and Hf isotope composition of type 1 and type 2 zircon are similar suggesting that zircon alteration did not affect the Hf isotope systematics. The similarity of ƐHf(t) values in zircon from syenite (+0.5 ± 0.4 to +1.5 ± 0.4), nepheline syenite (+1.6 ± 0.3 to +2.7 ± 0.5) and carbonatite (+1.5 ± 0.2 to +1.9 ± 0.1) is consistent with the melts having been derived from a moderately Depleted Mantle.
Carbonatite
Nepheline syenite
Baddeleyite
Nepheline
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Granitoids play a key role in the geological structure of the Ros-Tikych megablock. Supercrustal rocks of the Ros-Tikych series have been preserved in the granitoids only in the form of isolated fragments such as elongated remains, small skialites and even smaller "melted" xenoliths. In particular, in the Ostrivsky quarry, located on the right bank of the Ros River east of Bila Tserkva, granitoids are found (even-grained, porphyry-like granites) among which, as a rule, small bodies of granodiorites, plagiogranites and amphibolites occur. In order to determine the source of the parent magmas of rocks the properties of zircon crystals and the isotopic composition (87Sr/86Sr ratio) of apatite were studied. An analysis of the zircon crystals of the crystalline rocks exposed at the Ostrivsky quarry allows us to propose that the and plagio- and difeldspar granites were formed from one protolith. This is because they contain similar virtually identical zircon relics as nucleus. In addition, none of the granitoids contain zircon crystals whose internal structure is similar to zircon crystals found in amphibolite. This suggests that the granitoids were not derived by melting of amphibolites. Most likely, amphibolites are relicts of the protolith that were not assimilated during granite formation. The occurrence of heterogeneous zircon crystals (relic zircon cores of the protolith) in the protolith of the various studied granitoids indicates that they formed from volcanic-sedimentary rocks. Apatites in plagiogranitoids and porphyry granite contain strontium of similar isotopic composition. Their 87Sr/86Sr isotopic ratio is 0.70680 in apatite granodiorite and 0.70822 in granite. A high ratio of 87Sr/86Sr = 0.77940 was measured for apatite from monazite-bearing granite, thus indicating a different source for its parent magma.
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New and compiled detrital zircon U–Pb ages from the southern Neoproterozoic–Cambrian Ribeira Belt, SE Brazil, demonstrate Laurentian affinity of the Embu Terrane which is statistically distinct from the adjoining Apiaí and São Roque terranes with cratonic affinity (e.g., São Francisco Craton). Zircon provenance results indicate that the type-area of the Embu Terrane is dominated by detrital zircon age modes at ca. 1200 Ma, 1400 Ma, and 1800 Ma, with maximum depositional age of ca. 1000 Ma. In contrast, the Apiaí and São Roque terranes are dominated by Paleoproterozoic detrital zircon ages (ca. 2200–2000 Ma age dominant component), with maximum depositional ages of ca. 1400 Ma and 1750 Ma, respectively. Multidimensional scaling (MDS) analysis of non-parametric similarity measurements on zircon age populations indicates for the first time that the Embu Terrane encompass two statistically distinct detrital zircon age spectra, which is also reflected in the metamorphic zircon age record. The statistical characterization of the Embu Terrane through populational metrics allow a quantitative comparison with surrounding tectonic domains and rock samples classified such as Embu-type. Our results clearly highlight the distinction between the statistically differentiated Embu Terrane from the Apiaí and São Roque terranes, supporting an allochthonous interpretation. In addition, we demonstrate that rocks samples previously classified as Embu-type are significantly dissimilar to the definition of Embu Terrane, failing to support alternative tectonic models (e.g., intracontinental evolution). Detrital zircon age spectra reveal that the Apiaí and São Roque terranes have similar zircon provenance to domains sourced from the São Francisco Craton, whereas detrital zircon populations from the Embu Terrane have greater affinity with SW Laurentia basins (and their inferred sediment sources), consistent with previous findings. Therefore, we interpret the Embu Terrane as a Rodinia descendant developed along the active margin of the SW Laurentia that collided with the Ribeira Belt during early Neoproterozoic (810–760 Ma).
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Diorite
Radiogenic nuclide
Hadean
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ABSTRACT The Avalon terrane of southeastern New England is a composite terrane in which various crustal blocks may have different origins and/or tectonic histories. The northern part (west and north of Boston, Massachusetts) correlates well with Avalonian terranes in Newfoundland, Nova Scotia, and New Brunswick, Canada, based on rock types and ages, U-Pb detrital zircon signatures of metasedimentary rocks, and Sm-Nd isotope geochemistry data. In the south, fewer data exist, in part because of poorer rock exposure, and the origins and histories of the rocks are less well constrained. We conducted U-Pb laser ablation–inductively coupled plasma–mass spectrometry analysis on zircon from seven metasedimentary rock samples from multiple previously interpreted subterranes in order to constrain their origins. Two samples of Neoproterozoic Plainfield Formation quartzite from the previously interpreted Hope Valley subterrane in the southwestern part of the southeastern New England Avalon terrane and two from the Neoproterozoic Blackstone Group quartzite from the adjacent Esmond-Dedham subterrane to the east have Tonian youngest detrital zircon age populations. One sample of Cambrian North Attleboro Formation quartzite of the Esmond-Dedham subterrane yielded an Ediacaran youngest detrital zircon age population. Detrital zircon populations of all five samples include abundant Mesoproterozoic zircon and smaller Paleoproterozoic and Archean populations, and are similar to those of the northern part of the southeastern New England Avalon terrane and the Avalonian terranes in Canada. These are interpreted as having a Baltican/Amazonian affinity based primarily on published U-Pb and Lu-Hf detrital zircon data. Based on U-Pb detrital zircon data, there is no significant difference between the Hope Valley and Esmond-Dedham subterranes. Detrital zircon of two samples of the Price Neck and Newport Neck formations of the Neoproterozoic Newport Group in southern Rhode Island is characterized by large ca. 647–643 and ca. 745–733 Ma age populations and minor zircon up to ca. 3.1 Ga. This signature is most consistent with a northwest African affinity. The Newport Group may thus represent a subterrane, terrane, or other crustal block with a different origin and history than the southeastern New England Avalon terrane to the northwest. The boundary of this Newport Block may be restricted to the boundaries of the Newport Group, or it may extend as far north as Weymouth, Massachusetts, as far northwest as (but not including) the North Attleboro Formation quartzite and associated rocks in North Attleboro, Massachusetts, and as far west as Warwick, Rhode Island, where eastern exposures of the Blackstone Group quartzite exist. The Newport Block may have amalgamated with the Amazonian/Baltican part of the Avalon terrane prior to mid-Paleozoic amalgamation with Laurentia, or it may have arrived as a separate terrane after accretion of the Avalon terrane. Alternatively, it may have arrived during the formation of Pangea and been stranded after the breakup of Pangea, as has been proposed previously for rocks of the Georges Bank in offshore Massachusetts. If the latter is correct, then the boundary between the Newport Block and the southeastern New England Avalon terrane is the Pangean suture zone.
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The petrogenesis of the Pridoli to Early Lochkovian granites in the Miramichi Highlands of New Brunswick, Canada, is controversial. This study focuses on the Pridoli Nashwaak Granite (biotite granite and two-mica granite). In situ trace elements and O and Hf isotopes in zircon, coupled with O isotopes in quartz, are used to reveal its magmatic sources and evolution processes. In the biotite granite, inherited zircon cores have broadly homogenous δ18OZrc ranging from +6.7‰ to 7.4‰, whereas magmatic zircon rims have δ18OZrc of +6.3‰ to 7.2‰ and εHf(t) of −0.39 to −5.10. The Hf and Yb/Gd increase with decreasing Th/U. Quartz is isotopically equilibrated with magmatic zircon rims. The biotite granite is interpreted to be solely derived by partial melting of old basement rocks of Ganderia and fractionally crystallized at the fO2 of 10−21 to 10−10 bars. The two-mica granite has heterogeneous inherited zircon cores (δ18OZrc of +5.2‰ to 9.9‰) and rims (δ18OZrc of +6.2‰ to 8.7‰), and εHf(t) of −11.7 to −1.01. The two-mica granite was derived from the same basement, but with supracrustal contamination. This open-system process is also recorded by Yb/Gd and Th/U ratios in zircon and isotopic disequilibrium between magmatic zircon rims and quartz (+10.3 ± 0.2‰).
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