The Mogok metamorphic belt (MMB) in central Myanmar is well known for its complex tectonics, magmatism, and metamorphism in the framework of Tethyan subduction and India–Asia collision. It is also world renowned due to the gemstone‐class rubies and sapphires. Identification and discrimination of those petrological units in this region therefore are important for understanding the gemstone mineralization. Ultramafic massifs also crop out together with the gemstone‐bearing metamorphic rocks in the MMB. It is still poorly constrained about their origin (i.e., mantle peridotites of Jurassic–Cretaceous ophiolites or cumulate rocks) and their relationship with the gemstone generation. Here, we report petrological and geochemical data for the Mogok ultramafic rocks. Petrographic observations show that they have typical cumulate textures, with a crystallization order of olivine/spinel‐orthopyroxene‐clinopyroxene. They have low whole‐rock Al 2 O 3 and CaO, and extremely high spinel Cr# (=Cr/[Cr + Al]; up to 0.86). Clinopyroxenes of these rocks show light rare earth element enriched patterns when normalized to CI chondrite. The results suggest that the Mogok ultramafic rocks have different compositions, both whole‐rock and mineral, from mantle peridotites of Myanmar ophiolites, such as the Kalaymyo and Myitkyina ophiolites, but resemble typical Alaskan‐type ultramafic cumulates. Therefore, the Mogok ultramafic rocks are cumulates generated by high‐pressure crystallization of hydrous arc melts, probably during the subduction of the Tethyan oceanic slab. We argue that the emplacement of these arc melts may have provided additional heat for the earlier magmatic rocks and regional high‐temperature metamorphism, although there is a need to further constrain the ages of these rocks. This, along with magmatism and metamorphism during post‐collisional extension, probably collectively contributed to the generation of world‐class coloured gemstone mineralization.
Ruby (red corundum) is one of the most prominent colored gemstones in the world. The highest-quality ruby (“pigeon blood” ruby) comes from marbles of the Mogok Stone Tract in central Myanmar. Although Mogok ruby has been exploited since the 6th century AD, the formation time of this gemstone is ambiguous and controversial. In this paper, we describe a mineralogical, geochemical, and geochronological study of ruby and titanite in ruby-bearing marbles obtained from an outcrop in the Mogok Stone Tract, central Myanmar. Petrographic observations have shown that titanite generally occurs in the marble matrix or occurs as inclusions in ruby. These two types of titanite exhibit identical chemical compositions. In situ secondary ion mass spectrometer (SIMS) U–Pb dating of the separated titanite from two representative samples of ruby-bearing marbles yielded lower intercept ages of 25.15 ± 0.24 Ma (MSWD = 0.26) and 25.06 ± 0.22 Ma (MSWD = 0.15), respectively. Because the closure temperature of the U–Pb system in titanite is close to the temperature of ruby growth, the obtained U–Pb ages (~25 Ma) are suggested to represent the timing of the studied ruby formation in Mogok. The acquired ages are in agreement with the timing of post-collisional extension in the Himalaya related to the migration of the eastern Himalayan syntaxis. Combining our dating results with previous geochronological data from the Mogok Stone Tract, we suggest that the formation of the studied ruby is most likely related to the high-temperature metamorphic event in the marbles during the India–Asia collision. Our study not only confirms that texturally constrained titanite could be a precise geochronometer to date the mineralization of different types of ruby, but also provides important geochronological information linking gemstone formation to the India–Asia collision.
By means of LA-ICP-MS dating, average 206Pb/238U age of the inherited zircons from meta-basalts of the Wuguan Group is 348+18/-12 Ma. This could represent the recrystallization age of the inherited zircon metamorphosed by hot basalt magma, suggesting the Wuguang Group a Late-Devonian stratum.
Abstract. Fluid infiltration into (meta-)carbonate rocks is an important petrologic process that induces metamorphic decarbonation and potential mineralization of metals or nonmetals. The determination of the infiltration time and the compositional features of reactive fluids is essential to understand the mechanism and process of fluid–rock interactions. Zirconolite (ideal formula: CaZrTi2O7) is an important U-bearing accessory mineral that can develop in metasomatized metacarbonate rocks. In this study, we investigate the occurrence, texture, composition, and chronology of various types of zirconolite from fluid-infiltrated reaction zones in dolomite marbles from the Mogok metamorphic belt, Myanmar. Three types of zirconolite are recognized: (1) the first type (Zrl-I) coexists with metasomatic silicate and oxide minerals (forsterite, spinel, phlogopite) and has a homogeneous composition with high contents of UO2 (21.37 wt %–22.82 wt %) and ThO2 (0.84 wt %–1.99 wt %). (2) The second type (Zrl-II) has textural characteristics similar to those of Zrl-I. However, Zrl-II shows a core–rim zonation with a slightly higher UO2 content in the rims (average of 23.5 ± 0.4 wt % (n=8)) than the cores (average of 22.1 ± 0.3 wt % (n=8)). (3) The third type (Zrl-III) typically occurs as coronas around baddeleyite and coexists with polycrystalline quartz. Zrl-III has obviously lower contents of UO2 (0.88 wt %–5.3 wt %) than those of Zrl-I and Zrl-II. All types of zirconolite have relatively low rare earth element (REE) contents (< 480 µg g−1 for ΣREE). Microtextures and compositions of the three zirconolite types, in combination with in situ zirconolite U–Pb dating using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), reveal episodic fluid infiltration and element mobilization in the dolomite marbles. The first-stage infiltration occurred at ∼ 35 Ma, leading to the formation of Mg-rich silicates and oxides and accessory minerals (Zrl-I, baddeleyite, and geikielite). The reactive fluid was characterized by high contents of Zr, Ti, U, and Th. After that, some Zrl-I grains underwent a local fluid-assisted dissolution–precipitation process, which produced a core–rim zonation (i.e., the Zrl-II type). The final stage of fluid infiltration, recorded by the growth of Zrl-III after baddeleyite, took place at ∼ 19 Ma. The infiltrating fluid of this stage had relatively lower U contents and higher SiO2 activities than the first-stage infiltrating fluid. This study illustrates that zirconolite is a powerful mineral that can record repeated episodes (ranging from 35 to 19 Ma) of fluid influx, metasomatic reactions, and Zr–Ti–U mineralization in (meta-)carbonates. This mineral not only provides key information about the timing of fluid flow but also documents the chemical variation in reactive fluids. Thus, zirconolite is expected to play a more important role in characterizing the fluid–carbonate interaction, orogenic CO2 release, and the transfer and deposition of rare metals.
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