Understanding the tectonics that gave rise to the formation of Tibet is critical to our understanding of crustal deformation processes. The unusual geomorphology of the drainage basins of East Asia's major rivers has been proposed to be the result of either (1) distortion and attenuation of antecedent drainages as India indents into Asia, which can therefore be used as passive strain markers of horizontal shear, or (2) due to fragmentation by river captures and flow reversals of an originally continental-scale drainage, in which the major East Asian rivers once flowed into the palaeo-Red River. If the latter hypothesis is correct, then it has been proposed that dating the drainage fragmentation constrains the timing of uplift of Tibet. A number of sedimentary provenance studies have been undertaken in order to determine whether the palaeo-Red River was once a river of continental proportions into which the upper reaches of the Yangtze, Salween, Mekong, Irrawaddy, and Yarlung drained. We have assessed the evidence that the Yarlung originally flowed into the palaeo-Red river, and then sequentially into the Irrawaddy and Brahmaputra, connecting to the latter first via the Lohit and then the Siang. For this river system, we have integrated our new data from the Paleogene-Recent Irrawaddy drainage basin (detrital zircon U-Pb with Hf and fission track, rutile U-Pb, mica Ar-Ar, bulk rock Sr-Nd, and petrography) with previously published data, to produce a palaeodrainage model that is consistent with all datasets. In our model, the Yarlung never flowed into the Irrawaddy drainage: during the Paleogene, the Yarlung suture zone was an internally drained basin, and from Neogene times onwards the Yarlung drained into the Brahmaputra in the Bengal Basin. The Central Myanmar Basin, through which the Irrawaddy River flows today, received predominantly locally-derived detritus until the Middle Eocene, the Irrawaddy initiated as a through-going river draining the Mogok Metamorphic Belt and Bomi-Chayu granites to the north sometime in the Late Eocene to Early Oligocene, and the river was dominated by a stable MMB-dominated drainage throughout the Neogene to present day. Existing evidence does not support any connection between the Yarlung and the Red River in the past, but there is a paucity of suitable palaeo-Red River deposits with which to make a robust comparison. We argue that this limitation also precludes a robust assessment of a palaeo-connection between the Yangtze/Salween/Mekong and the Red River; it is difficult to unequivocally interpret the recorded provenance changes as the result of specific drainage reorganisations. We highlight the palaeo-Red River deposits of the Hanoi Basin as a potential location for future research focus in view of the near-complete Cenozoic record of palaeo-Red River deposits at this location. A majority of previous studies consider that if a major continental-scale drainage ever existed at all, it fragmented early in the Cenozoic. Such a viewpoint would agree with the growing body of evidence from palaeoaltitude studies that large parts of SE Tibet were uplifted by this period. This then leads towards the intriguing question as to the mechanisms which caused the major period of river incision in the Miocene in this region.
A routine procedure is presented to analyse Pb isotopes in K-feldspar minerals and mineral inclusions in zircon by LA-MC-ICP-MS, with a spot size down to 10 μm.
Granitoids from the Pilbara Craton in Western Australia are one of the most ancient and best-preserved records of early processes of continental crust generation.No consensus has been reached on whether this early crust originated from a chondritic or depleted mantle reservoir in the Eo/Palaeoarchaean.Zircon U-Pb and Lu-Hf isotopes data for granitoids sampled across the Mount Edgar Dome record four main magmatic events between 3.47 and 3.23 Ga.Whole-rock major and trace element analyses suggest that the samples belong to two distinct petrogenetic groups.The first group is part of the Tonalite-Trondhjemite-Granodiorite (TTG) suite, representing highly fractionated magmas initially formed by partial melting of a basaltic source.The second group, here classified as granites, is best interpreted by the remelting of a more felsic source.Strikingly, TTG-like and granitic magmas occurred coevally in time and space while showing a clear change from superchondritic to subchondritic Hf isotope compositions between 3.47 and 3.23 Ga.The superchondritic Hf isotope composition of the 3.47 Ga granitoids substantiates derivation from a depleted mantle source that separated from the chondritic mantle prior to 3.8 Ga.The presence of ca.3.5 Ga inherited zircons in 3.3 and 3.23 Ga magmas suggests that crustal remelting processes were involved in their generation.We propose that all granitoids investigated in this study originated from a single mantle-crust differentiation event.This event resulted in the separation of two distinct crustal reservoirs from the depleted mantle, i.e., a mafic crust and a more felsic crust.Overall, our data suggest that protracted intracrustal remelting processes and differentiation have played a key role in the formation, evolution and maturation of the building blocks of continents during the Palaeoarchaean.
The Earth is the only known planet where plate tectonics is active, and different studies have concluded that plate tectonics commenced at times from the early Hadean to 700 Ma. Many arguments rely on proxies established on recent examples, such as paired metamorphic belts and magma geochemistry, and it can be difficult to establish the significance of such proxies in a hotter, older Earth. There is the question of scale, and how the results of different case studies are put in a wider global context. We explore approaches that indicate when plate tectonics became the dominant global regime, in part by evaluating when the effects of plate tectonics were established globally, rather than the first sign of its existence regionally. The geological record reflects when the continental crust became rigid enough to facilitate plate tectonics, through the onset of dyke swarms and large sedimentary basins, from relatively high-pressure metamorphism and evidence for crustal thickening. Paired metamorphic belts are a feature of destructive plate margins over the last 700 Myr, but it is difficult to establish whether metamorphic events are associated spatially as well as temporally in older terrains. From 3.8–2.7 Ga, suites of high Th/Nb (subduction-related on the modern Earth) and low Th/Nb (non-subduction-related) magmas were generated at similar times in different locations, and there is a striking link between the geochemistry and the regional tectonic style. Archaean cratons stabilised at different times in different areas from 3.1–2.5 Ga, and the composition of juvenile continental crust changed from mafic to more intermediate compositions. Xenon isotope data indicate that there was little recycling of volatiles before 3 Ga. Evidence for the juxtaposition of continental fragments back to ~2.8 Ga, each with disparate histories highlights that fragments of crust were moving around laterally on the Earth. The reduction in crustal growth at ~ 3 Ga is attributed to an increase in the rates at which differentiated continental crust was destroyed, and that coupled with the other changes at the end of the Archaean are taken to reflect the onset of plate tectonics as the dominant global regime.
Plate tectonics exerts a first-order control on the interaction between Earth’s reservoirs. Atmospherically-altered surface materials are recycled to the mantle via subduction, while volatiles from the mantle are liberated to the atmosphere via volcanism. This cycle regulates much of Earth’s climate, ocean levels and metallogenetic processes within the continental crust. However, the interplay between Earth’s atmospheric changes and the geochemical evolution of mantle-derived magmas has remained obscure for the ancient geological history. This has led to multiple conflicting models for the crustal evolution in the early Earth. A time-integrated evolution of the mantle-crust-atmosphere-hydrosphere interaction is yet to be fully established. For instance, secular change of the ocean and atmosphere system is evident from several proxies but the feedback of these changes to magmatic and geochemical processes in the lithosphere remain unclear. Moreover, no clear consensus has been reached on the timing of modern-style plate tectonic initiation and the evolution of net growth of the continental crust. To explain overt and cryptic global trends in the geochemistry of magmatic rocks, a better understanding of mineral reactions and how these control trace element evolution in magmas at the lithosphere-scale is paramount. For example, the elemental and isotopic composition of apatite inclusions hosted by zircon offers a way to better understand the evolution of magmas and, to some extent, the nature of magma sources. These proxies rely on the robust data acquisition of other isotope systems with different geochemical behaviour, such as U-Pb and Lu-Hf analyses in the host zircon crystal. A combination of methods and proxies including the elemental composition of apatite via EPMA and the oxygen fugacity based on sulphur speciation via μ-XANES of apatite inclusions was applied to ancient sub-arc magmas formed in regions akin to modern subduction zones. These magmas share a common mantle source but crystallised more than 200 million years apart (at 2.35 and 2.13 billion years ago). Importantly, they bracket the Great Oxidation Event, when atmospheric oxygen levels increased by five orders of magnitude, causing a permanent and dramatic change in Earth’s surface chemistry. As such, these sub-arc magmas were investigated as potential tracers of the interaction between Earth’s atmosphere and the mantle. The information from several inclusions from co-magmatic rocks can then be interpreted in the light of U-Pb, Lu-Hf, trace elements and oxygen isotope analyses of the host zircon grains. Altogether, the results show a shift in oxygen fugacity of sub-arc magmas across the Great Oxidation Event. The change in oxygen fugacity is thought to be caused by recycling into the mantle of sediments that had been geochemically altered at the surface by the increase in atmospheric oxygen levels. This study opens a wide window of opportunities for the time-integrated investigation of the interaction between atmosphere and oceans with the evolving terrestrial mantle.
In situ Sr isotopes analysis of apatite by LA-(MC)-ICP-MS is challenged by the difficulty to monitor and correct isobaric interferences from atomic and polyatomic ions. We present a new routine procedure for analysing rock-forming apatites with a Thermo Scientific Neptune XT MC-ICP-MS coupled with a Teledyne Cetac Analyte Excite+ 193 nm laser ablation system. Five apatite standards that cover a large range of REE/Sr ratios were selected, and their 87Sr/86Sr ratios were measured in solution after dissolution and purification of Sr [Durango: 0.706321(5); Madagascar: 0.711814(5); Slyudyanka; 0.707705(4); Sumé: 0.707247(4); and Ipirá: 0.710487(4)]. The optimisation of both instrument setup and data reduction schemes was achieved through repeated measurements of calibration solutions and of apatite standards at four different rectangular-shaped laser ablation beam sizes (50 × 50, 25 × 25, 13 × 13 and 10 × 10 μm). Two complementary methods were developed for data reduction: Method 1, which corrects measured intensities for gas blank and instrumental mass bias only; and Method 2, which additionally corrects for isobaric interferences of 87Rb+, 166, 168 and 170Er++, 170, 172, 174 and 176Yb++, 40Ca44Ca+, 40Ca46Ca+, 44Ca43Ca+ and 40Ca48Ca+. A precision of ca. 100 ppm (2 s.e.) can be achieved on the 87Sr/86Sr ratio with a 50 μm laser ablation beam when using Method 2, and it remains better than 3000 ppm at 10 μm with Method 1. Method 1 gives precise and accurate 87Sr/86Sr ratios when 173Yb++ is below the global limit of detection (with LODglobal = 3 s.d. of the means of all gas blanks measurements). When 173Yb++ is above the LODglobal, Method 2 should be preferred as it provides more accurate 87Sr/86Sr ratios. Overall, this study offers a robust and reliable approach for LA-MC-ICP-MS analysis of Sr isotopes in rock-forming apatite at a high spatial resolution (i.e. down to 10 μm), overcoming previous limitations associated with instrumental set up and data reduction.
Continental crust is the archive of Earth history. The spatial and temporal distribution of Earth’s record of rock units and events is heterogeneous; for example, ages of igneous crystallization, metamorphism, continental margins, mineralization, and seawater and atmospheric proxies are distributed about a series of peaks and troughs. This distribution reflects the different preservation potential of rocks generated in different tectonic settings, rather than fundamental pulses of activity, and the peaks of ages are linked to the timing of supercontinent assembly. The physio-chemical resilience of zircons and their derivation largely from felsic igneous rocks means that they are important indicators of the crustal record. Furthermore, detrital zircons, which sample a range of source rocks, provide a more representative record than direct analysis of grains in igneous rocks. Analysis of detrital zircons suggests that at least ∼60%–70% of the present volume of the continental crust had been generated by 3 Ga. Such estimates seek to take account of the extent to which the old crustal material is underrepresented in the sedimentary record, and they imply that there were greater volumes of continental crust in the Archean than might be inferred from the compositions of detrital zircons and sediments. The growth of continental crust was a continuous rather than an episodic process, but there was a marked decrease in the rate of crustal growth at ca. 3 Ga, which may have been linked to the onset of significant crustal recycling, probably through subduction at convergent plate margins. The Hadean and Early Archean continental record is poorly preserved and characterized by a bimodal TTG (tonalites, trondhjemites, and granodiorites) and greenstone association that differs from the younger record that can be more directly related to a plate-tectonic regime. The paucity of this early record has led to competing and equivocal models invoking plate-tectonic– and mantle-plume–dominated processes. The 60%–70% of the present volume of the continental crust estimated to have been present at 3 Ga contrasts markedly with the <10% of crust of that age apparently still preserved and requires ongoing destruction (recycling) of crust and subcontinental mantle lithosphere back into the mantle through processes such as subduction and delamination.
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