Abstract This study illustrates how decoupling of quartz and zircon can be used advantageously in provenance research. Thirty‐eight fine‐grained to coarse‐grained arkose samples of the Early Triassic intracontinental Buntsandstein Group from the Central European Basin in Germany were analysed for their petrography and 1200 grains in 23 of these for their detrital quartz cathodoluminescence characteristics. The samples represent the Hessian and Thuringian sub‐basins and the Eichsfeld–Altmark Swell separating them. The Hessian Sub‐basin includes more metamorphic lithoclasts with a larger content of plutonic grains than are found further east in the Thuringian Sub‐basin. More than 90% of the detrital quartz from the eastern Thuringian Sub‐basin produce medium to bright blue cathodoluminescence colours and corresponding spectra that are typical for igneous or high‐temperature metamorphic origin. Differently, the quartz from the Hessian Sub‐basin mostly luminesces brown and dark to medium blue, typical for a low‐temperature metamorphic origin. Quartz from the Eichsfeld–Altmark Swell and the western Thuringian Sub‐basin is a mixture between these origins. The quartz indicates different catchments for the sub‐basins, possibly the Bohemian Massif and the Massif Central, with converging transport routes on and close to the eastern fringe of the swell. Taking published zircon data from the same samples into account, light mineral‐zircon grain‐size shifts are up to 2 Φ units. That can be explained by mineral decoupling due to different transport modes for quartz and zircon and different zircon‐size availability in the source areas, exaggerated by combined aqueous–aeolian transport, as well as sample preparation‐induced sorting. This study concludes that submerged highs significantly can influence continental sediment transport. Hence, vast, flat continental areas with submerged morphological highs and a seemingly straightforward transportation pattern may be more complex than expected. The results also illustrate that analysis of detritus that has been affected by different dominating transport modes, and further sorting during sampling and preparation can reveal additional source information.
How can inorganic geochemical data from terrestrial deposits be used as a provenance tool? We demonstrate a new approach as earlier studies have focused on marine deposits. We present a review of the factors that affect the whole-rock geochemical composition of terrestrial deposits and a case study to test how geochemical provenance differentiation can be made for such deposits. We confirm that both K2O/Na2O and immobile trace-element ratios are suitable provenance indicators for terrestrial deposits. We stress that previously developed discrimination schemes constructed for marine deposits of different depositional facies, specific grain size and texture (commonly greywacke) for identification of tectonic settings are unsuitable for terrestrial deposits as they often are related to different tectonic frame, depositional facies, and sorting degree. Different terrestrial tectonic situations will influence the detrital composition such that rift, foreland, and sag basins likely have different chemical compositions. Humid climatic conditions may reduce such differences. The case study is based on the intracontinental Permian Rotliegend Group and Early Triassic Buntsandstein Group and equivalents in central Europe, mainly Germany and Denmark. Both units had mainly felsic sources. We present results from > 1500 sedimentary samples from both published and unpublished data, mostly from sandstone. K2O/Na2O efficiently differentiates sandstone from different regions. The compositional variation is in line with reported variations in feldspar compositions and indicates local catchments. Thus, the feldspar has been preserved in the arid climate due to limited weathering. Y/Co, in combination with other indices (La/Sc, La/Lu, Ti/Nb, Th/Sc), is one of the most successful mafic-felsic trace-element indices that we use. We postulate that the trace-element variation is governed by mineral inclusions mainly in feldspar in addition to individual detrital grains. V/Zr and Zr/Sc mostly correlate with Y/Co, which indicates different zircon affinity in the source rocks rather than sorting. More dominance of felsic compositions and higher Zr/Sc for Triassic than Permian strata are in line with more sedimentary recycling during the Triassic than Permian. Thus, the results reveal that source-rock differentiation can be made for different geographical areas and stratigraphic units based on K2O/Na2O due to variations in feldspar compositions in the source areas, provided little chemical weathering. Based on the case study, the mafic-felsic trace-element ratios La/Sc, Th/Sc, Y/Co, and Ti/Nb seem most promising for provenance discrimination, in combination with La/Lu, and Zr/Sc and V/Zr as tracers of heavy minerals. We conclude that the combination of arid climatic conditions and terrestrial depositional environments makes it possible to use both major oxides and trace element ratios to reveal source-rock differences. For robust provenance interpretations, we recommend to focus on immobile elements that are little affected by grain-size variations, to combine several element ratios for interpretation, to avoid comparison of data produced by different methods (for instance x-ray fluorescence and mass spectrometry), and to complement geochemical investigations with data from other methods.
The basement complex of the Sierra Madre region in north‐eastern Mexico is classified into four domains: (a) granulite facies rocks of Grenville age (ca. 1 Ga) known as the Novillo Gneiss, (b) the Palaeozoic Granjeno Schist, (c) an unmetamorphosed succession of Palaeozoic marine siliciclastic and volcanic rocks, and (d) an Ordovician plagiogranite body. We present a geochemical and provenance study of the metasedimentary rocks of the Granjeno Schist, which are associated with metavolcanic and meta‐ultramafic rocks. In the Granjeno Schist, trace element ratios (Th/Sc, La/Sch, La/Sc, and Zr/Sc) and REE compositions of the metasedimentary rocks are similar to values for the mean continental crust values and are consistent with derivation of detritus from felsic rocks. Chemical index of alteration values of 30–80 indicates low to moderate weathering of the source. The clastic metasedimentary rocks have moderately radiogenic Nd‐isotopic compositions with initial ε Nd( t ) values of −9 to −6, and model ages between 1.5 and 1.7 Ga. Ages of detrital zircon grains from the metasedimentary rocks are mostly 1.6–1.1 Ga, but some ages are 530–410 Ma. Such a Novillo Gneiss‐like age spectrum argues for short transport for the majority of zircon grains, with potential additional transport from the Maya Block. Na‐amphibole and mica geobarometer results of up to 6 kbar indicate high‐pressure subduction‐related metamorphism of the Granjeno Schist that was followed by a Pennsylvanian–Permian sub‐greenschist to greenschist metamorphic overprint in an accretionary prism. Thus, the Granjeno Schist is a representative of ocean‐plate stratigraphy that originated proximally close to a continent.
Abstract The Granjeno Schist is a meta-volcanosedimentary upper Paleozoic complex in northeastern Mexico. We suggest different tectonic settings for metamorphism of its serpentinite and talc-bearing rocks based on petrographic and geochemical compositions. According to the REE ratios (La
Abstract Central Scania, southernmost Sweden, is penetrated by more than one hundred basaltic volcanic necks of Jurassic age. Pyroclastics, related to the volcanic necks, have been investigated to reveal the volcanic environment, and the eruptive character required to produce the pyroclastics. Based on textural and petrographical evidence, a Strombolian-type eruptive character is suggested. The sediment, a lapilli tuff, is clay altered due to early diagenetic processes, but traces of palagonite reveal a former basaltic composition of the lapilli tuff. The volcanoes were part of a monogenetic volcanic field and deposition of the pyroclastic sediment took place on land, probably close to oceanic water.