Abstract Found on a specimen in the mineral collection of the National Museum of Wales, no. NMW 27.111.GR414, from the Aberllyn mine, Llanrwst mining field, North Wales, with hydrozincite on a breccia cemented by sphalerite, quartz, calcite, and ankerite. Atomic absorption and TGA analyses gave ZnO 37.8, CuO 22.0, SO 3 14.9, H 2 O 24.5, total 99.2%, corresponding to (Zn 2.50 Cu 1.49 ) Σ3.99 S 1.00 O 7 ·7.32 H 2 O on the basis of total O = 7 in the anhydrous part. The ideal formula is (Zn,Cu) 4 SO 4 (OH) 6 ·4H 2 O where Zn > Cu. It is hexagonal a 8.29, c 10.50 ± 0.01 Å, possible space groups P 6, P , P 6/ m , P 622, P 6 mm , P m 2, P 2 m , and P 6/ mmm . Isomorphous with synthetic Zn,SO 4 (OH) 6 6·4H 2 O and (Zn,Cu) 4 SO 4 (OH) 6 ·4H 2 O. Strongest X-ray powder diffractions are: 10.59(100)0001, 5.31(15)0002, 4.15(25)11 0, 2.71(42)21 0, 2.63(41)21 1,0004, 2.41(22)21 2, 1.57(23)32 2, 1.55(20)41 1. Namuwite is pale sea-green in colour, lustre pearly, streak very pale green, H (Mohs) 2. Cleavage {0001}, perfect. Density (g/cm 3 ) 2.77 (meas.), 2.81 (calc. on the normalized empirical formula). It is optically uniaxial, sign not determined owing to the extremely low birefringence. Refractive index n = 1.577(5)(Na D ). The mineral and name have been approved by the Commission on New Minerals and Mineral Names, IMA.
Abstract Fluid inclusion and stable isotope data from quartz and carbonate minerals in fracture fillings and ‘ironstone’ nodules from the South Wales Coalfield have been used to characterise the fluids generated during basin evolution and associated coalification. Carbonates grew first, probably at relatively shallow depths and low temperatures (<100°C). The carbonates exhibit a trend of increasing C‐isotopic values across the coalfield, ranging from δ 13 C = −12‰ VPDB in the SE of the coalfield to 0‰ VPDB in the NW, possibly as a result of increasing methanogenesis in the deeper (NW) parts of the coalfield. Quartz formed at a later stage of basin formation, probably at temperatures between 150 and 200°C. Fluid inclusions in these minerals suggest that burial and coalification of the sediments were associated with mixed aqueous–petroleum fluids. Furthermore, the density of these petroleum fluids decreases towards the NW of the coalfield, where the rank of the associated coal increases to anthracite grade. The study confirms that the composition and temperature of these fluids closely correlate with the variations in coal rank, indicating a possible causal link. The data also give general support to models that propose regional fluid flow in the basin. and are consistent with the erosion of approximately 2 km of section which is not preserved today. A geothermal gradient (at maximum burial) of 45°C km −1 is proposed, and thus no exceptionally anomalous thermal regime is required to explain coal rank variation.
ABSTRACT. Basalts and basal tic andesites interbedded with sandstones in the molassic Baucarit Formation of northwestern Mexico show contrasting zeolite and clay assemblages in amygdales and in veins cross-cutting the flows. In amygdales, heulandite-clinoptilolite, chabazite, offretite/erionite and phillipsite are associated with a di-smectite clay. In veins, mesolite, analcime and stilbite are associated with minor clay, quartz and calcite. The low temperature nature of the zeolites and clays suggests that the infiltrating fluid had a temperature below 100°C and probably ca. 60°C. The absence of a pervasive alteration and a lack of correspondence between clay and host-rock chemistry suggest that this fluid was probably of a meteoric and fresh water character, which subsequently evolved into a more alkaline nature following interaction with glassy material in the interbedded mollassic sediments. RESUMEN. Procesos de ceolitizacion en lavas basicas de la Formacion Baucarit, noroeste de Mexico. Los basaltos y andesitas basalticas interestratificados con areniscas en la formacion molasica Baucarit del noroeste de Mexico poseen asociaciones contrastantes de ceolitas y minerales arcillosos contenidas en amigdalas y en venas que atraviesan las coladas. En las amigdalas, heulandita-clinoptilolita, chabacita, offretita/erionita y phillipsita estan asociadas con una diesmectita. En las venas, mesolita, analcita y estilbita se asocian con cuarzo, calcita y cantidades menores de minerales arcillosos. La ausencia de una alteracion pervasiva y la falta de correspondencia entre la composicion quimica de los minerales arcillosos y la roca huesped sugieren una precipitacion a partir de un fluido de origen externo. El caracter de baja temperatura de las ceolitas y minerales arcillosos sugiere que el fluido infiltrado tenia una temperatura inferior a 100°C y posiblemente cercana a 60°C. Este fluido era, probablemente, agua dulce de caracter meteorico que posteriormente evoluciono hacia una naturaleza mas alcalina a consecuencia de su interaccion con el material vitreo contenido en los sedimentos molasicos interestratificados.