The addition of crustal sulphur to magma can trigger sulphide saturation, a process fundamental to the development of some Ni–Cu–PGE deposits. In the British Palaeogene Igneous Province, mafic and ultramafic magmas intrude a thick sedimentary sequence offering opportunities to elucidate mechanisms of magma–crust interaction in a setting with heterogeneous S isotope signatures. We present S-isotopic data from sills and dykes on the Isle of Skye. Sharp contrasts exist between variably light δ34S in Jurassic sedimentary sulphide (−35‰ to −10‰) and a local pristine magmatic δ34S signature of −2.3 ± 1.5‰. Flat-lying sills have restricted δ34S (−5‰ to 0‰) whereas steeply dipping dykes are more variable (−0‰ to −2‰). We suggest that the mechanism by which magma is intruded exerts a fundamental control on the degree of crustal contamination by volatile elements. Turbulent flow within narrow, steep magma conduits, discordant to sediments, and developed by brittle extension or dilation have maximum contamination potential. In contrast, sill-like conduits emplaced concordantly to sediments show little contamination by crustal S. The province is prospective for Ni–Cu–PGE mineralization analogous to the sill-hosted Noril’sk deposit, and Cu/Pd ratios of sills and dykes on Skye indicate that magmas had already reached S-saturation before reaching the present exposure level.
Abstract During the earliest Jurassic, a widespread hydrothermal event occurred in western Europe producing large veins and stratiform F-Ba-Pb-Zn ore deposits. Previous work argued about genetic processes involving circulation of mineralising brines. Two main alternative genetic models are proposed. The first one proposes a convection of brines through the crust to produce ore deposits, the second an early infiltration of brine in the basement followed by expulsion during Mesozoic extension. In the northern French Massif Central, new data on the F-Ba Chaillac deposit suggest that the genesis of these mineralising brines requires a new discussion. Located in the northern French Massif Central, the Chaillac barite and fluorite ore deposit is an exceptional site where a stratiform deposit is rooted onto a vein. The ore deposition is split in two stages: 1) precipitation of green and purple fluorite within the vein (Fg-p stage), with associated fluid inclusions indicating 135°C for deposition from a low salinity fluid, and 2) yellow fluorite and barite stage (Fy-Ba) filling the vein and forming the stratiform deposit. Fluid inclusions depict a mineralising brine at 110°C. The 87Sr/86Sr and 143Nd/144Nd isotopic ratios measured in the fluorite are compared to those of French Massif Central rocks. The ratios in green and purple fluorite are similar to those of monzogranite and granodiorite of the basement; those measured in yellow fluorite involve the granulites and other metamorphic rocks of the basement. Measurements of the Sr isotopic ratio and δ34SCDT in barite and δD in fluorite fluid inclusions suggest a deposition process by the mixing of a hydrothermal fluid with meteoric water. At the scale of the northern Massif Central district, the successive hydrothermal fluid salinities are highly contrasted as in Chaillac deposit. We propose that the two types of hydrothermal fluids have been produced by the boiling of a single fluid at depth.
The ∼60 m thick Magilligan Sill is part of the British Palaeogene Igneous Province in the North Atlantic. The sill comprises layers of dolerite and olivine gabbro, and it intrudes a thick sequence of Mesozoic mudstones and marls, which are locally baked at the sill margins. Since 2014, the sill has been an exploration target for orthomagmatic Ni – Cu – platinum group element (PGE) sulfide mineralisation analogous to the Noril’sk-Talnakh intrusion in Russia. We present new petrological, geochemical, and S isotope data to assess the prospectivity of the sill and the underlying magmatic plumbing system. Most sulfides in the dolerite portions of the sill are <50 μm in size and comprise only pyrite with PGE abundances below the detection limit. In the olivine gabbros, >150 μm size pentlandite, chalcopyrite, and pyrrhotite grains contain <4 ppm total PGE, 1460 ppm Co, and 88 ppm Ag. Pyrite from the dolerites have δ 34 S ranging from −10.0‰ to +3.4‰ and olivine gabbro sulfides range from −2.5‰ to −1.1‰, suggesting widespread crustal contamination. The S/Se ratios of sulfides in the dolerites and olivine gabbros range from 3500 to 19 500 and from 1970 to 3710, respectively, indicating that the latter may have come from upstream in the magma plumbing system. The Magilligan Sill records multiple injections of mafic magma into an inflating sill package, each with distinct mechanisms towards S saturation. Whilst the sulfide minerals in the sill do not constitute significant mineralisation themselves, detailed in situ studies highlight a divergence in S saturation histories and suggest that a larger volume of olivine gabbro sulfides at depth may be prospective.
<p>Faults, joints and stylolites are ubiquitous features in fold-and-thrust belts commonly used to reconstruct the past fluid flow (or plumbing system) at the scale of folded reservoir/basins. Through the textural and geochemical study of the minerals that fills the fractures, it is possible to understand the history of fluid flow in an orogen, requiring a good knowledge of the burial history and/or of the past thermal gradient. In most of the case, the latter derives from the former, itself often argued over, limiting the interpretations of past fluid temperatures. We present the results of a multi-proxy study that combines novel development in both structural analysis of a fracture-stylolite network and isotopic characterization of calcite vein cements/fault coating. Together with new paleopiezometric and radiometric constraints on burial evolution and deformation timing, these results provide a first-order picture of the regional fluid systems and pathways that were present during the main stages of contraction in the Tuscan Nappe and Umbria-Marche Apennine Ridge (Northern Apennines). We reconstruct four steps of deformation at the scale of the belt: burial-related stylolitization, Apenninic-related layer-parallel shortening with a contraction trending NE-SW, local extension related to folding and late stage fold tightening under a contraction still striking NE-SW. We combine the paleopiezometric inversion of the roughness of sedimentary stylolites - that provides a temperature-free constraint on the range of burial depth of strata prior to layer-parallel shortening -, with burial models and U-Pb absolute dating of fault coatings in order to determine the timing of development of mesostructures. In the western part of the ridge, layer-parallel shortening started in Langhian time (~15 Ma), then folding started at Tortonian time (~8 Ma), late stage fold tightening started by the early Pliocene (~5 Ma) and likely lasted until recent/modern extension occurred (~3 Ma onward). The textural and geochemical (&#948;<sup>18</sup>O, &#948;<sup>13</sup>C, &#8710;<sub>47</sub>CO<sub>2</sub> and <sup>87</sup>Sr/<sup>86</sup>Sr) study of calcite vein cements and fault coatings reveals that most of the fluids involved in the belt during deformation are basinal brines evolved from various degree of fluid rock interactions between pristine marine fluids (&#948;<sup>18</sup>O<sub>fluids</sub> = 0&#8240; SMOW) and surrounding limestones (&#948;<sup>18</sup>O<sub>fluids</sub> = 10&#8240; SMOW). The precipitation temperatures (35&#176;C to 75&#176;C) appear consistent with the burial history unraveled by sedimentary stylolite roughness paleopiezometry (600 m to 1500m in the range) and geothermal gradient (23&#176;C/km). However, the western edge of the ridge recorded isotopically depleted past fluids of which corresponding precipitation temperature (100&#176;C to 130&#176;C) are inconsistent with local burial history (1500m). We interpret then pulses of eastward migration of hydrothermal fluids (>140&#176;C), driven by the tectonic contraction and by the difference in structural style of the subsurface between the eastern Tuscan Nappe and the Umbria-Marche Apennine Ridge. Allowed by an unprecedented combination of paleopiezometry and isotopic geochemistry, this fluid flow model illustrates how the larger scale structures control the fluid system at the scale of the range.</p>
High-resolution (partly in-situ) sulfur isotope measurements on sulfides in 17 samples from 5 different Pb-Zn deposits of the Drau range have been carried out. High-resolution sulfur isotope investigations provide knowledge on small-scale variations in the sulfur isotopic composition of coexisting sulfides and can help to interpret the mineralization processes. The sulfur isotopic composition provides evidence for different sulfur reservoirs and fluids involved in the mineralization process. Small-scale isotope heterogeneities can be related to textural aspects and this enables to recognize different sulfur reservoirs, one providing bacteriogene reduced sulfur (BSR) and another one responsible for thermochemical reduced sulfur (TSR). Both reservoirs were involved into ore formation and were able to contribute reduced sulfur during the whole mineralization process.
In addition to isotopic measurements, major, minor and trace element analyses by electron microprobe (EMP) have been carried out on sphalerites in order to investigate if any relation between sulfur isotopic and chemical composition exists.
Aynak is the largest known copper deposit in Afghanistan, with indicated resources of 240 Mt grading 2.3% Cu placing it in the 'giant' category. Host rocks are Neoproterozoic metasediments comprising dolomitic marble, carbonaceous quartz schist and quartz-biotite-dolomite schist containing garnet, scapolite and apatite. Chalcopyrite and bornite dominate the hypogene ore with lesser pyrite, pyrrhotite, cobaltite and chalcocite, and rare sphalerite, molybdenite, uraninite and barite. Sulphides occur as bedding-parallel laminae, disseminations, metamorphic segregations and crosscutting veins. Sulphide δ34S ratios range –14.5 to +17.3‰ in bedded and disseminated sulphides (n = 34). This broad range favours biogenic reduction of seawater sulphate as a major source of sulphur, although thermochemical reduction processes are not precluded. The narrower δ34S range of –6 to +12.2‰ in vein and segregation sulphides (n = 21) suggests localized redistribution and partial homogenization during metamorphism. Geochemical associations suggest that Al, P, Ca, Ti and Fe were primary sedimentary constituents whereas Cu, Mg, S, Se, As, Co and Bi were introduced subsequently. We infer that Aynak originated as a shale- and carbonate-hosted stratabound replacement deposit, resembling orebodies of the Central African Copperbelt, although underlying red-beds are absent at Aynak and mafic volcanics were the probable copper source. These giant deposits formed worldwide in the Cryogenian probably due to marine enrichment in copper, magnesium and sulphate coincident with profuse basaltic volcanism and ocean oxidation.
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