Research Article| September 01, 2014 Structural Control, Hydrothermal Alteration Zonation, and Fluid Chemistry of the Concealed, High-Grade 4EE Iron Orebody at the Paraburdoo 4E Deposit, Hamersley Province, Western Australia Warren S. Thorne; Warren S. Thorne † 1Centre for Exploration Targeting, School of Earth and Geographical Sciences, University of Western Australia, Crawley, WA 6009, Australia †Corresponding author: e-mail, specularite@hotmail.com Search for other works by this author on: GSW Google Scholar Steffen G. Hagemann; Steffen G. Hagemann 1Centre for Exploration Targeting, School of Earth and Geographical Sciences, University of Western Australia, Crawley, WA 6009, Australia Search for other works by this author on: GSW Google Scholar David Sepe; David Sepe 1Centre for Exploration Targeting, School of Earth and Geographical Sciences, University of Western Australia, Crawley, WA 6009, Australia Search for other works by this author on: GSW Google Scholar Hilke J. Dalstra; Hilke J. Dalstra 2Rio Tinto Exploration, 37 Belmont Avenue, Belmont, WA 6984, Australia Search for other works by this author on: GSW Google Scholar David A. Banks David A. Banks 3School of Earth and Environment, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, United Kingdom Search for other works by this author on: GSW Google Scholar Economic Geology (2014) 109 (6): 1529–1562. https://doi.org/10.2113/econgeo.109.6.1529 Article history received: 10 Feb 2013 accepted: 02 Nov 2013 first online: 09 Mar 2017 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn MailTo Tools Icon Tools Get Permissions Search Site Citation Warren S. Thorne, Steffen G. Hagemann, David Sepe, Hilke J. Dalstra, David A. Banks; Structural Control, Hydrothermal Alteration Zonation, and Fluid Chemistry of the Concealed, High-Grade 4EE Iron Orebody at the Paraburdoo 4E Deposit, Hamersley Province, Western Australia. Economic Geology 2014;; 109 (6): 1529–1562. doi: https://doi.org/10.2113/econgeo.109.6.1529 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyEconomic Geology Search Advanced Search Abstract High-grade iron ore of the 4EE orebody of the 4E deposit (>200 Mt at 63.5 wt % Fe) occurs as a southerly dipping sheet within banded iron formation (BIF) of the Paleoproterozoic Dales Gorge and Joffre members of the Brockman Iron Formation. Structural reconstruction of the 4E deposit shows that reactivation of the 18E fault and development of the NW-striking, steeply SW dipping 4E and 4EE normal faults resulted in preservation of the 4EE orebody below the 4E deposit, and 400 m below the modern topographic surface.Three hypogene alteration zones between low-grade BIF and high-grade iron ore are observed: (1) distal magnetite-quartz-dolomite-stilpnomelane-hematite ± pyrite, (2) intermediate magnetite-dolomite-hematite-chlorite-quartz-stilpnomelane, and (3) proximal hematite-dolomite-chlorite ± pyrite ± magnetite. Hydrothermal alteration is temporally and spatially constrained by NW-trending dolerite dikes that intruded the 4E and 4EE faults prior to hypogene alteration. Six vein types (V1–V6) are recognized at the 4E deposit. The veins both cut and parallel the primary BIF layers and were emplaced contemporaneously with the hydrothermal alteration zones that record the transformation of low-grade BIF to high-grade iron ore.Our integrated structural-hydrothermal alteration and fluid flow model proposes that during early stage 1a, hypogene fluid flow in the 4E orebody occurred during a period of continental extension and enhanced heat flow within sedimentary basins to the south of the Paraburdoo Range. Heated basinal brines were focused by the NW-striking, steeply SW dipping 4E and 4EE normal faults and reacted with BIF of the Dales Gorge and Joffre members. The warm to hot (160°–255°C), Ca-rich (26.6–31.9 equiv wt % CaCl2) basinal brine interacted with magnetite-chert layers, transforming them into magnetite-quartz-dolomite-stilpnomelane-hematite-pyrite BIF. The iron-rich brine (up to 2.8 wt % Fe) likely originated from evaporated seawater that had lost Mg and Na and gained Li and Ca through fluid-rock reactions with volcaniclastic rocks and carbonate successions within the Wittenoom Formation. The first incursion of deeply circulating, low-salinity (5.8–9.5 wt % NaCl equiv), heated (106°–201°C) modified meteoric water is recorded in late stage 1a minerals. This modified meteoric water had lost some of its Na through wall rock interaction with plagioclase, possibly by interaction with dolerite of the Weeli Wooli Formation that directly overlies the Joffre and Dales Gorge members.Stage 1b involved continuing reactions between the hydrothermal fluids and the magnetite-quartz-dolomite-stilpnomelane-hematite-pyrite BIF, and produced both the intermediate magnetite-dolomite-hematite-chlorite-pyrite and the proximal hematite-dolomite-magnetite-stilpnomelane alteration assemblages. Microplaty (10–80 μm), platy (100–250 μm), and anhedral hematite increasingly replace magnetite in the intermediate alteration zone, forming the proximal alteration zones that consist of microplaty, platy, anhedral hematite and magnetite. The intermediate and proximal alteration zones represent the mixing of a hot (250°–400°C), high-salinity, Ca-rich (30–40 wt % CaCl2 equiv), Sr-rich basinal brine with low-temperature and low-salinity (~5 wt % NaCl equiv) modified meteoric water that was heated (~100°–200°C) during its descent into the upper crust. Heterogeneous mixing of the two end-member fluids resulted in the trapping of primary fluid inclusion assemblages containing a wide range of trapping temperatures (up to 200°C) and salinities (up to 25 wt % NaCl equiv).Stage 1c of the hypogene hydrothermal fluid is characterized by low-temperature (<110°C), low-salinity (~5 wt % NaCl) meteoric water that interacted with the proximal hematite-dolomite-magnetite-stilpnomelane–altered BIF, leaving a porous, hematite-apatite high-grade ore. Supergene alteration affected the orebody since the Cretaceous and produced a hematite-goethite alteration assemblage, resulting in destruction of the hypogene alteration zones that are only preserved below the depth of modern weathering.Discovery of the concealed 4EE orebody of the 4E deposit demonstrates that structural geology plays a critical role in the exploration for high-grade iron orebodies. Structural reconstruction should be considered a critical exploration activity in structurally complex terranes where concealed orebodies may exist. You do not have access to this content, please speak to your institutional administrator if you feel you should have access.
Abstract The punctuated distribution of major gold deposits along orogenic belts is poorly understood. In northern Perú, gold deposits cluster along trends that transect the subparallel Phanerozoic belts that accreted onto the western margin of the Archean–Proterozoic Amazonian craton. This suggests the influence of as yet unrecognized pre-Andean basement structures in controlling the localization of Phanerozoic deposits. We report the newly discovered Tomac ophiolite, which represents a missing link in tracing a cryptic basement collisional suture striking obliquely to the Peruvian Andes. The Tomac ophiolite signals the opening of a former Neoproterozoic ocean basin between the Amazonian craton and a continental ribbon of dispersed microterranes. Re-accretion of the continental ribbon resulted in the formation of a collisional belt between ca. 465 and 440 Ma. Rifting and re-accretion occurred parallel to the strike of the ca. 1400–1000 Ma Grenvillian-Sunsás orogen, indicating that structural corridors that transect the Andes at an oblique strike angle reflect inheritance of preexisting lithospheric weak zones. Our study demonstrates that Phanerozoic gold deposits in northern Perú cluster at the intersection between the newly defined basement suture and the superimposed Andean belt and associated well-documented cross faults. Gold mineralization was localized at ancient structural intersections, where enhanced permeability facilitated anomalous energy and mass transfer, promoting major ore accumulation during episodes of accretion.
In the Val d'Or camp, Archean Abitibi greenstone belt, Canada, numerous gold-mineralized second- and third-order fault zones are spatially associated with the transcrustal Cadillac Tectonic Zone (CTZ). This situation is used to test whether fluid systems in the CTZ have a similar structural timing to those in the gold-hosting structures, and hence the CTZ could represent the main fluid conduit in the camp. The transcrustal CTZ at Orenada No. 2 contains structurally complex vein systems, with mineralized quartz-tourmaline veins related to both D 2 oblique-reverse faulting and F 3 dextral asymmetric folding, both of which have been overprinted by unmineralized subhorizontal and subvertical quartz veins. Quartz ± tourmaline veins within second- and third-order shear zones at Paramaque and Rivière Héva also formed during D 2 deformation and have been, at least at Rivière Héva, deformed by F 3 asymmetric folding. In contrast, mineralized quartz vein systems at Cartier Malartic are controlled by F 3 folding and overprinted by late-stage D 3 faults which host late quartz-tourmaline veins. Quartz vein textures are consistent with these timing relations, because D 2 -controlled veins contain deformed quartz grains, whereas quartz in D 3 -controlled veins is unstrained. The D 2 and D 3 timing of mineralized quartz veins in the transcrustal CTZ and in second- and third-order structures is consistent with the notion that the CTZ represents the main fluid conduit and that mineralization occurred in linked second- and third-order structures. The different timing of quartz-tourmaline veins in different shear zones indicates that the veins were probably hydraulically linked to the CTZ during at least two different episodes. The location of Cartier Malartic structurally below the CTZ indicates that fluids travelled either downward from the main conduit or that the shear zone was part of the CTZ.
Mississippian arc magmatic suites of the Au-rich Pataz and Cu-dominated Montañitas regions in Peru reveal distinct modes of magmatic-hydrothermal petro- and metallogenesis. The distinction is remarkable due to their broad contemporaneity (336–322 Ma), arc-parallel position, and close distance (< 50 km) to each other. In both arc regions, petrography, geochemistry, and the tectonic setting of magmatic suites suggest a rapid switch from syn-collisional/compressional to post-collisional/extensional (with 'A2-type' signature) emplacement regime. Rocks of the Au-rich Pataz region originate from mixed sources with a contribution from the mantle (εHf > 0 and δ18O of ~ 5.3‰) and assimilated old crust (variously low εHf and δ18O > 5.3‰). The ultimate source of Au in the mineralised Pataz batholith was oxidised (fO2 at FMQ buffer; based on zircon trace chemistry) and alkali-, LILE- and HFSE-enriched, most likely represented by the metasomatised mantle. The syn-extensional emplacement of the relatively reduced (ΔFMQ < 0), but unmineralised, A2-type suite involved assimilation of reduced crust. Associated, reduced, magmatic-hydrothermal fluids infiltrated the Au-bearing batholith suite and effectively mobilised and transported and concentrated Au. In the Montañitas region, rocks are oxidised (ΔFMQ > 0) and dominantly mantle derived without significant incorporation of crustal material. Samples from the Cu-mineralised suites indicate the additional contribution of a δ18O < 5.3‰ source, potentially melted layer-2 gabbro. In addition, the elevated whole-rock La/Yb and Sr/Y ratios are compatible with minor addition of slab-derived material, which may have enhanced Cu endowment in this region. Late-magmatic, oxidised fluids derived from the younger A2-type suite controlled Cu mobilisation and concentration, while Au behaved largely refractory. In general terms, it is postulated that source mixing in continental arcs is a first-order control of contrasting Cu and Au endowment and that sequential intrusion processes facilitate late-magmatic-hydrothermal mobilisation and concentration of specific metal assemblages.