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    Abstract The Sanbagawa metamorphic terrain of the study area is divided into two units, the Shirakura and Sejiri units. The metamorphic thermal structure is interpreted on the basis of the degree of graphitization (GD) of carbonaceous material in pelitic schists. The areal variations of the metamorphic grade are presented by the distribution of GD calculated using the Lc and d 002 of carbonaceous material. As a result, the two units are classified into four metamorphic zones, respectively: A 1 , A 2 , B 1 and B 2 for the Shirakura Unit; and I 1 , I 2 , II 1 and II 2 for the Sejiri Unit. The metamorphic grades of A 1 , A 2 , I 1 and I 2 are included in the chlorite zone, and that of B 1 , B 2 , II 1 and II 2 in the garnet zone of the Sanbagawa metamorphism. The degree of graphitization at the boundary between A 2 and B 1 zones is the same as that between I 2 and II 1 zones. Detailed study on the variation of GD suggests that the present‐day structure of the study area is best interpreted as a model of shuffled‐cards structure. An estimated minimum thickness of a stack of continuous cards is about 25 m. The compositions of garnet in pelitic schists and of amphibole in basic schists are different from those in the identical metamorphic range of the Shirakura and Sejiri units. It is suggested that rocks of the Shirakura Unit were metamorphosed under higher P/T conditions than those of the Sejiri Unit.
    Pelite
    Isograd
    Amphibole
    Abstract Garnet porphyroblasts in sillimanite‐bearing pelitic schists contain complex textural and compositional zoning, with considerable variation both within and between adjacent samples. The sillimanite‐bearing schists locally occur in regional Barrovian garnet zone assemblages and are indicative of a persistent lack of equilibrium during prograde metamorphism. Garnet in these Dalradian rocks from the Scottish Highlands preserves evidence of a range of metamorphic responses including initial growth and patchy coupled dissolution–reprecipitation followed by partial dissolution. Individual porphyroblasts each have a unique and variable response to prograde metamorphism and garnet with mainly flat compositional profiles co‐exists with those containing largely unmodified characteristic bell‐shaped Mn profiles. This highlights the need for caution in applying traditional interpretations of effective volume diffusion eliminating compositional variation. Cloudy garnet with abundant fluid inclusions is produced during incomplete modification of the initial porphyroblasts and these porous garnet are then particularly prone to partial replacement in sillimanite‐producing reactions. The modification of garnet via a dissolution–reprecipitation process releases Ca into the effective whole‐rock composition, displacing the pressure–temperature positions of subsequent isograd reactions. This represents the first report of internal metasomatism controlling reaction pathways. The behaviour of garnet highlights the importance of kinetic factors, especially deformation and fluids, in controlling reaction progress and how the resulting variability influences subsequent prograde history. The lack of a consistent metamorphic response, within and between adjacent schists, suggests that on both local and regional scales these rocks have largely not equilibrated at peak metamorphic conditions.
    Sillimanite
    Pelite
    Isograd
    Dalradian
    Metasomatism
    Citations (12)