Non-KREEP origin for Chang’e-5 basalts in the Procellarum KREEP Terrane
Heng‐Ci TianHao WangYi ChenWei YangQin ZhouChi ZhangHonglei LinChao HuangShitou WuLihui JiaLei XuDi ZhangXiaoguang LiRui ChangYue‐Heng YangLie‐Wen XieDan‐Ping ZhangGuangliang ZhangSaihong YangFu‐Yuan Wu
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Abstract:
Mare volcanics on the Moon are the key record of thermo-chemical evolution throughout most of lunar history1-3. Young mare basalts-mainly distributed in a region rich in potassium, rare-earth elements and phosphorus (KREEP) in Oceanus Procellarum, called the Procellarum KREEP Terrane (PKT)4-were thought to be formed from KREEP-rich sources at depth5-7. However, this hypothesis has not been tested with young basalts from the PKT. Here we present a petrological and geochemical study of the basalt clasts from the PKT returned by the Chang'e-5 mission8. These two-billion-year-old basalts are the youngest lunar samples reported so far9. Bulk rock compositions have moderate titanium and high iron contents with KREEP-like rare-earth-element and high thorium concentrations. However, strontium-neodymium isotopes indicate that these basalts were derived from a non-KREEP mantle source. To produce the high abundances of rare-earth elements and thorium, low-degree partial melting and extensive fractional crystallization are required. Our results indicate that the KREEP association may not be a prerequisite for young mare volcanism. Absolving the need to invoke heat-producing elements in their source implies a more sustained cooling history of the lunar interior to generate the Moon's youngest melts.Keywords:
Lunar mare
This note examines critically recent attempts to identify or closely correlate lunar surface samples-on the basis of alpha-scattering analysis-with terrestrial igneous rocks (basalts) or with eucrite meteorites. Basalts show considerable variety; but all have chemical characteristics inherited from terrestrial mantle rock melted under a limited range of terrestrial pressure-temperature conditions. What is characteristic is not so much the content of any particular element or oxide-e.g., SiO(2) 47-52 per cent-but rather a complete chemical pattern in which such ratios as Fe/Mg and Ca/(Na + K) show consistent relationships to Si content. These are the chemical criteria that might be useful in comparing terrestrial basalt with extraterrestrial rocks. Basalts also have distinctive mineralogical and textural characteristics; and if a lunar or meteoritic rock is to be identified as basalt it must possess these, too.Turkevich's analysis of alpha-scattering data for lunar samples (Surveyor V) show significant departure from basaltic composition: Very high (Ca + K)/Na associated with distinctly high Fe/Mg. In basalts relatively high (Ca + K)/Na-in no case approaching the reported lunar values-tends to be associated with Fe/Mg values lower than average. The same "lunar" pattern of high (Ca + K)/Na and Fe/Mg appears in recorded analyses of eucrite meteorites. In the lunar samples, Ti is notably higher than in basalts, and even more so than in eucrites. If eucrites are of lunar origin their Ti values are, so far, a real anomaly.
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Samples returned from the Apollo 15 site consist of mare basalts and breccias with a variety of premare igneous rocks. The mare basalts are from at least two different lava flows. The bulk chemical compositions and textures of these rocks confirm the previous conclusion that the lunar maria consist of a series of extrusive volcanic rocks that are rich in iron and poor in sodium. The breccias contain abundant clasts of anorthositic fragments along with clasts of basaltic rocks much richer in plagioclase than the mare basalts. These two rock types also occur as common components in soil samples from this site. The rocks and soils from both the front and mare region exhibit a variety of shock characteristics that can best be ascribed to ray material from the craters Aristillus or Autolycus.
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Lunar mare
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