SMOS-based estimation and validation of Total Alkalinity in the Mediterranean basin
Roberto SabiaEstrella OlmedoGianpiero CossariniAïda Alvera AzcarateVerónica González‐GambauDiego Fernández‐Prieto
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<p>ESA SMOS satellite [1] has been providing first-ever Sea Surface Salinity (SSS) measurements from space for over a decade now. Until recently, inherent algorithm limitations or external interferences hampered a reliable provision of satellite SSS data in semi-enclosed basin such as the Mediterranean Sea. This has been however overcome through different strategies in the retrieval scheme and data filtering approach [2, 3]. This recent capability has been in turn used to infer the spatial and temporal distribution of Total Alkalinity (TA - a crucial parameter of the marine carbonate system) in the Mediterranean, exploiting basin-specific direct relationships existing between salinity and TA.</p><p>Preliminary results [4] focused on the differences existing in several parameterizations [e.g, 5] relating these two variables, and how they vary over a seasonal to interannual timescale.</p><p>Currently, to verify the consistency and accuracy of the derived products, these data are being validated against a proper ensemble of in-situ, climatology and model outputs within the Mediterranean basin. An error propagation exercise is also being planned to assess how uncertainties in the satellite data would translate into the final products accuracy.</p><p>The resulting preliminary estimates of Alkalinity in the Mediterranean Sea will be linked to the overall carbonate system in the broader context of Ocean Acidification assessment and marine carbon cycle.</p><p>References:</p><p>[1] J. Font et al., "SMOS: The Challenging Sea Surface Salinity Measurement From Space," in Proceedings of the IEEE, vol. 98, no. 5, pp. 649-665, May 2010. doi: 10.1109/JPROC.2009.2033096</p><p>[2] Olmedo, E., J. Martinez, A. Turiel, J. Ballabrera-Poy, and M. Portabella,&#160; &#8220;Debiased non-Bayesian retrieval: A novel approach to SMOS Sea Surface Salinity&#8221;. Remote Sensing of Environment 193, 103-126 (2017).</p><p>[3] Alvera-Azc&#225;rate, A., A. Barth, G. Parard, J.-M. Beckers, Analysis of SMOS sea surface salinity data using DINEOF, In Remote Sensing of Environment, Volume 180, 2016, Pages 137-145, ISSN 0034-4257, https://doi.org/10.1016/j.rse.2016.02.044.</p><p>[4] Sabia, R., E. Olmedo, G. Cossarini, A. Turiel, A. Alvera-Azc&#225;rate, J. Martinez, D. Fern&#225;ndez-Prieto, Satellite-driven preliminary estimates of Total Alkalinity in the Mediterranean basin, Geophysical Research Abstracts, Vol. 21, EGU2019-17605, EGU General Assembly 2019, Vienna, Austria, April 7-12, 2019.</p><p>[5] Cossarini, G., Lazzari, P., and Solidoro, C.: Spatiotemporal variability of alkalinity in the Mediterranean Sea, Biogeosciences, 12, 1647-1658, https://doi.org/10.5194/bg-12-1647-2015, 2015.</p><p>&#160;</p><p>&#160;</p>Keywords:
Alkalinity
Mediterranean Basin
<p>The Mediterranean Sea (MS) is a semi-enclosed sea characterized by a zonal west-east gradient of oligotrophy, where microbial growth is controlled by phosphate availability in most situations. External inputs of nutrients including Gibraltar inputs, river inputs and atmospheric deposition are therefore of major importance for the biogeochemistry of the MS. The latter has long been considered to be driven mainly by nutrient exchanges at Gibraltar. However, recent studies indicate that river inputs significantly affect nutrients concentrations in the Mediterranean Sea, although their resulting impact on its biogeochemistry remains poorly understood. In this study, our aim was to help fill this knowledge gap by addressing the large-scale and long-term impact of variations in river inputs on the biogeochemistry of the Mediterranean Sea over the last decades, using a coupled physical- biogeochemical 3D model (NEMO-MED12/Eco3M-Med). As a first result, it has been shown by the model that the strong diminution (60%) of phosphate (PO4) in river inputs into the Mediterranean Sea since the end of the 1980s induced a significant lowering of PO4 availability in the sub-surface layer of the Eastern Mediterranean Basin (EMB). One of the main consequences of PO4 diminution is the rise, never previously documented, of dissolved organic carbon (DOC) concentrations in the surface layer (by 20% on average over the EMB). Another main result concerns the gradual deepening of the top of the phosphacline during the period studied, thus generating a shift between the top of the nitracline and the top of the phosphacline in the EMB. This shift has already been observed in situ and documented in literature, but we propose here a new explanation for its occurrence in the EMB. The last main result is the evidence of the decline in abundance and the reduction of size of copepods calculated by the model over the years 1985&#8211;2010, that could partially explain the reduction in size of anchovy and sardine recently recorded in the MS. In this study, it is shown for the first time that the variations in river inputs that occurred in the last decades may have significantly altered the biogeochemical cycles of two key elements (P and C), in particular in the EMB.</p>
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Biogeochemical Cycle
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Abstract Apoglossum gregarium , a minute deep-water red alga considered an alien in the Mediterranean Sea, was previously known only from the western basin. The present paper reports A. gregarium for the first time off Greece, in the eastern Mediterranean basin. It was found on artificial substrata at 50 m depth in the southeastern Ionian Sea. The Greek specimens were identical to previous Mediterranean descriptions. Moreover, the Greek habitat is the deepest ever recorded for the species. Associated flora as well as biogeographical data are also provided. Based on its worldwide distribution, the possibility that A. gregarium is native to the Mediterranean Sea should not be ruled out.
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Alien species
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The deep water in the western Mediterranean Sea was found to be significantly affected by a climatic event that took place in the eastern Mediterranean during the 1990s. Numerical simulations of the entire Mediterranean Sea showed that multiple equilibria states in the eastern Mediterranean can exist under present-day-like conditions. The two stable states that were found are associated with intermediate water exchange between the eastern Mediterranean's Aegean and Adriatic Basins. In the first state, the Adriatic acts as a source of deep water that flows into the deep layers of the eastern Mediterranean; in the second state, there is no source of deep water in the Adriatic and the eastern Mediterranean intermediate water is warmer and saltier. We studied the water pathways, in both stable states, into the western Mediterranean and found that the eastern Mediterranean water's properties signature can be seen as far as the Gulf of Lion, which is an important open-ocean deep water convection site. Meaning that, the eastern Mediterranean water characteristics are manifested in deep and intermediate water properties all over the Mediterranean Sea. The water propagating from the eastern to the western Mediterranean also has different flow regimes, in both states, through the Sicily Strait and in the Tyrrhenian Basin, as seen from a Lagrangian analysis.
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At present, the Mediterranean is connected to the Atlantic Ocean through the narrow Strait of Gibraltar (only 13 km wide). The latter, in the late Miocene, most probably did not exist, and the Mediterranean – Atlantic water exchange took place through the Betic (Southern Spain) and Rifian (Northern Morocco) corridors. Studying the evolution of such gateways is fundamental when investigating the extraordinary event known as the Messinian Salinity Crisis (5.96 – 5.33 Ma), when the connection between the Mediterranean Sea and Atlantic Ocean significantly diminished or even ceased. In this work we present a new high resolution geochemical (XRF and stable isotope) record of the Tortonian – Messinian interval of the Montemayor-1 and Huelva-1 cores located in the Betic corridor, current Guadalquivir Basin. Our new data enabled in the first place the high-resolution tuning of the 7.4 – 5.8 Ma time interval, and consequently to precisely date environmental changes and relate them to Mediterranean and global events.Our results indicate that, at 7.17 Ma and in concomitance with a shallowing of the basin, the bottom water residence time, temperature and salinity increased. These changes have been associated with a reduction of the Mediterranean Outflow Water reaching the Guadalquivir Basin as a consequence of the restriction of the last strand of the Betic corridor connecting the Mediterranean and the Atlantic. This hypothesis is in line with the analogous changes observed in several Mediterranean Sea locations, where from 7.17 Ma a reduced Mediterranean – Atlantic connection is visible. Nonetheless, even if such reduction of the connection was feasible, the same changes in isotope record and analogous cyclicity observed both in the Guadalquivir and Alboran Basin record imply that the Mediterranean signal was still reaching the Betic gateway to some degree. In addition, the significant offset present between our and North Atlantic oxygen stable isotope records entails how the signal in the Guadalquivir basin could not have been purely Atlantic. Consequently, we conclude that a significant Mediterranean signal was still present in the Betic corridor during the Messinian.
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The well known changes in the deep thermohaline circulation of the eastern Mediterranean Sea, the so‐called Eastern Mediterranean Transient (EMT), which modified the outflow characteristics through the Sicily Strait, led to significant changes in the western Mediterranean Sea since the early 90's. In spring 2005 an oceanographic survey, carried out in the central part of the western basin, showed the presence of a recently formed layer of western Mediterranean deep water, spreading at the bottom of the whole Algero‐Provençal Basin. It was characterized by unusual θ‐ S shapes, as its temperature, salinity and density were higher with respect both to the resident deep waters and to the climatological values. The possible influence of the EMT on the deep water formation processes occurred in the Gulf of Lions in the previous winter is here evidenced, even taking into account other data sets previously collected in the western Mediterranean.
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Outflow
Temperature salinity diagrams
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