Fluid inclusion and stable isotope studies of the Kharape epizonal orogenic gold deposit, west Azerbaijan Province, Iran
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The Liziyuan gold deposit, situated on the south side of the Shangdan suture zone, West Qinling Orogen, occurs in metamorphic volcanic rocks (greenschist facies) of the early Paleozoic Liziyuan Group and in Indosinian Tianzishan monzogranite. Orebodies in the Liziyuan gold field are controlled by the ductile‐brittle shear zone, and by thrusting nappe faults related to the Indosinian orogeny. In detail, this paper analyzed the geological characteristics of the Liziyuan gold field, and the Pb isotopes of the Lziyuan host rocks, granitoids (Tianzishan monzogranite and Jiancaowan syenite porphyry), sulfides, and auriferous quartz veins by multiple‐collector inductively coupled plasma mass spectrometry (MC–ICP–MS). In addition, previous data on the sulfur, hydrogen, and oxygen isotopes were employed to discuss the possible sources of the ore‐forming fluids and materials, and to further understand the tectonic setting of the Liziyuan gold deposit. The sulfides and their host rocks (Lziyuan Group), Tianzishan monzogranite and Jiancaowan syenite porphyry, and auriferous quartz veins have similar Pb isotopic compositions. Zartman's plumbotectonic model diagram shows that most of the data for the deposit fall near the orogenic Pb evolutionary curve or within the area between the orogenic and mantle Pb evolutionary curves. In the Δβ‐Δγ diagram, which genetically classifies the lead isotopes, most of the data fall within the range of the subduction‐zone lead mixed with upper crust and mantle. This indicates that a complex source of the ore lead formed in the orogenic environment. The δ 34 S values of the sulfides range from 3.90 to 8.50‰ (average 6.80‰), with a pronounced mode at 5.00‰–8.00‰. These values are consistent with that of orogenic gold deposits worldwide, indicating that the sulfur sourced mainly from reduced metamorphic fluids. The isotopic hydrogen and oxygen compositions support a predominantly metamorphic origin of the ore‐forming fluids, with possible mixing of minor magmatic fluids, but the late stage was dominated by meteoric water. The characteristics of the Liziyuan gold deposit formed in the Indosinian orogenic environment of the Qinling Orogen are consistent with those of orogenic gold deposits found worldwide.
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Greenschist
Isotope Geochemistry
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Abstract. Primary fluid inclusions in quartz and carbonates from the Kanggur gold deposit are dominated by aqueous inclusions, with subsidiary CO 2 ‐H 2 O inclusions that have a constant range in CO 2 content (10–20 vol %). Microthermometric results indicate that total homogenization temperatures have a wide but similar range for both aqueous inclusions (120d̀ to 310d̀C) and CO 2 ‐H 2 O inclusions (140d̀ to 340d̀C). Estimates of fluid salinity for CO 2 ‐H 2 O inclusions are quite restricted (5.9∼10.3 equiv. wt% NaCl), whereas aqueous inclusions show much wider salinity ranging from 2.2 to 15.6 equivalent wt %NaCl. The 6D values of fluid inclusions in carbonates vary from ‐45 to ‐61 %, in well accord with the published δD values of fluid inclusions in quartz (‐46 to ‐66 %). Most of the δ 18 O and δD values of the ore‐forming fluids can be achieved by exchanged meteoric water after isotopic equilibration with wall rock by fluid/rock interaction at a low water/rock ratio. However, the exchanged meteoric water alone cannot explain the full range of δ 18 O and δD values, magmatic and/or meta‐morphic water should also be involved. The wide salinity in aqueous inclusions may also result from mixing of meteoric water and magmatic and/or metamorphic water.
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Abstract The Xiuwenghala gold deposit is located in the Beishan Orogen of the southern Central Asian Orogenic Belt. The vein/lenticular gold orebodies are controlled by Northeast‐trending faults and are hosted mainly in the brecciated/altered tuff and rhyolite porphyry of the Lower Carboniferous Baishan Formation. Metallic minerals include mainly pyrite and minor chalcopyrite, arsenopyrite, galena, and sphalerite, whilst nonmetallic minerals include quartz, chalcedony, sericite, chlorite, and calcite. Hydrothermal alterations consist of silicic, sericite, chlorite, and carbonate. Alteration/mineralization processes comprise three stages: pre‐ore silicic alteration (Stage I), syn‐ore quartz‐chalcedony‐polymetallic sulfide mineralization (Stage II), and post‐ore quartz‐calcite veining (Stage III). Fluid inclusions (FIs) in quartz and calcite are dominated by L‐type with minor V‐type and lack any daughter mineral‐bearing or CO 2 ‐rich/‐bearing inclusions. From Stages I to III, the FIs homogenized at 240–260°C, 220–250°C, and 150–190°C, with corresponding salinities of 2.9–10.9, 3.2–11.1, and 2.9–11.9 wt.% NaCl eqv., respectively. The mineralization depth at Xiuwenghala is estimated to be relatively shallow (<1 km). FI results indicate that the ore‐forming fluids belong to a low to medium‐temperature, low‐salinity, and low‐density NaCl‐H 2 O system. The values decrease from Stage I to III (3.7‰, 1.7–2.4‰, and −1.7 to 0.9‰, respectively), and a similar trend is found for their values (−104 to −90‰, −126 to −86‰, and −130 to −106‰, respectively). This indicates that the fluid source gradually evolved from magmatic to meteoric. δ 34 S values of the hydrothermal pyrites (−3.0 to 0.0‰; avg. −1.1‰) resemble those of typical magmatic/mantle‐derived sulfides. Pyrite Pb isotopic compositions ( 206 Pb/ 204 Pb = 18.409–18.767, 207 Pb/ 204 Pb = 15.600–15.715, 208 Pb /204 Pb = 38.173–38.654) are similar to those of the (sub)volcanic ore host, indicating that the origin of ore‐forming material was mainly the upper crustal (sub)volcanic rocks. Integrating evidence from geology, FIs, and H–O–S–Pb isotopes, we suggest that Xiuwenghala is best classified as a low‐sulfidation epithermal gold deposit.
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Arsenopyrite
Silicic
Chalcedony
Cassiterite
Ore genesis
Magmatic water
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The Yangjingou gold deposit in Jilin Province lies 11 km south of the large-scale Xiaoxinancha gold–copper deposit. Yangjingou orebodies are structurally controlled fault- or fracture-related auriferous quartz veins. This type of mineralization is significantly different from that of the Xiaoxinancha porphyry gold–copper deposit, and has mineral assemblages and fluid inclusion compositions typical of orogenic gold deposits. We suggest that the Yangjingou deposit is the first orogenic gold deposit discovered in the Yanbian area, even in all of NE China. Here, we present new isotopic dating and trace element analysis of the ore-hosting monzogranite and auriferous quartz veins within the deposit, in order to determine the age and tectonic setting of metallogenesis, and the geological conditions controlling gold mineralization. LA-ICP-MS U–Pb dating of zircons separated from the monzogranite yielded an age of 262.3 ± 1.3 Ma, indicating intrusion during the late Permian. Hydrothermal muscovite from auriferous quartz veins yielded a 40Ar/39Ar plateau age of 241.57 ± 1.2 Ma, indicating that gold mineralization occurred at 241 Ma. Trace element and REE compositions of the monzogranite and auriferous quartz veins are both indicative of the formation from a region of the upper mantle that previously underwent crustal contamination. Geochronological analysis indicates that the diagenesis and mineralization resulting in the Yangjingou gold deposit occurred during the late Permian–Early Triassic. The tectonic evolution of the region and comparison of this deposit with other mineralizing events indicate that the orebody formed during orogenesis associated with collision between the North China and Siberian cratons.
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Research Article| March 01, 2019 Mineralogy, Fluid Inclusion, and Stable Isotope Studies of the Chengchao Deposit, Hubei Province, Eastern China: Implications for the Formation of High-Grade Fe Skarn Deposits Wei Li; Wei Li 1Ministry of Natural Resources (MNR) Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences (CAGS), Beijing 100037, China2Faculty of Earth Resources, China University of Geosciences, Wuhan 430074, China Search for other works by this author on: GSW Google Scholar Guiqing Xie; Guiqing Xie 1Ministry of Natural Resources (MNR) Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences (CAGS), Beijing 100037, China †Corresponding author: e-mail, xieguiqing@cags.ac.cn Search for other works by this author on: GSW Google Scholar Jingwen Mao; Jingwen Mao 1Ministry of Natural Resources (MNR) Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences (CAGS), Beijing 100037, China Search for other works by this author on: GSW Google Scholar Qiaoqiao Zhu; Qiaoqiao Zhu 1Ministry of Natural Resources (MNR) Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences (CAGS), Beijing 100037, China Search for other works by this author on: GSW Google Scholar Jiahao Zheng Jiahao Zheng 3Department of Earth and Space Sciences, Southern University of Science and Technology, Shenzhen 518055, China Search for other works by this author on: GSW Google Scholar Economic Geology (2019) 114 (2): 325–352. https://doi.org/10.5382/econgeo.2019.4633 Article history accepted: 13 Feb 2019 first online: 27 Mar 2019 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn MailTo Tools Icon Tools Get Permissions Search Site Citation Wei Li, Guiqing Xie, Jingwen Mao, Qiaoqiao Zhu, Jiahao Zheng; Mineralogy, Fluid Inclusion, and Stable Isotope Studies of the Chengchao Deposit, Hubei Province, Eastern China: Implications for the Formation of High-Grade Fe Skarn Deposits. Economic Geology 2019;; 114 (2): 325–352. doi: https://doi.org/10.5382/econgeo.2019.4633 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyEconomic Geology Search Advanced Search Abstract The Chengchao Fe skarn deposit (280 Mt @ 45% Fe; nearly half of the total Fe reserve has an ore grade higher than 53 wt %) is the largest high-grade magnetite skarn deposit in the Middle-Lower Yangtze River metallogenic belt. The magnetite orebodies and skarns occur mainly along the contact zones between granitic (129 ± 2 Ma) rocks and diorite (133 ± 1 Ma) and Triassic strata. The paragenesis of the Chengchao deposit includes the following five stages: Na-K alteration stage (albite + K-feldspar), prograde skarn stage (garnet + pyroxene), retrograde skarn stage (magnetite + phlogopite + amphibole), sulfate-sulfide stage (anhydrite + pyrite ± garnet ± magnetite), and carbonate stage (calcite).Four generations of garnet and magnetite with distinct textures are recognized. The elemental compositions and fluid inclusion data of the three generations of garnet from the prograde skarn stage indicate fluctuating changes in the oxygen fugacity during their precipitation. Some magnetite grains from the retrograde skarn stage are characterized by well-developed zonation with respect to Al, K, Ca, and Si, with concentrations of up to hundreds of parts per million. The higher contents of (V + Ti) and (Al + Mn) in Mt2 relative to Mt1 (0.8 and 2,321 ppm for Mt1, and 182 and 10,315 ppm for Mt2, respectively) may be indicative of increasing fluid temperatures from episodic magmatic events. Fluid inclusion data show that the fluids responsible for the prograde skarn stage have high temperature (>750°C), high salinity (>50 wt % NaCl equiv) and high Fe concentration (e.g., magnetite and pyrite daughter crystals within garnet and pyroxene). Oxygen and hydrogen isotope data suggest that magmatic water was dominant during the prograde skarn stage and that increasing percentages of meteoric water were involved during later stages. Multiple episodic incursions of Fe-rich fluids, which were probably related to the emplacement of granitic rocks and diorite, were crucial for controlling the formation of the high-grade Chengchao Fe skarn deposit. You do not have access to this content, please speak to your institutional administrator if you feel you should have access.
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Mineral resource classification
Prospectivity mapping
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Abstract The temporal–spatial relationships of porphyry and orogenic gold mineralization in the Eastern Tianshan Orogenic Belt are ambiguous. The newly discovered Changshagou deposit in this belt contains both porphyry and orogenic gold mineralization, which are characterized by polymetallic–sulfide veinlets and quartz–pyrite veins, respectively. Fluid inclusions in the porphyry mineralization episode were trapped at 290–340°C with salinities of 3.0–8.0 wt% NaCl equiv . The homogenization temperatures and salinities in the orogenic mineralization episode range from 240 to 300°C and from 1.0 to 5.0 wt% NaCl equiv . Coexisting V- and L-type fluid inclusions with similar homogenization temperatures are indicative of fluid immiscibility. The δ 18 O w and δ D w values are in the ranges 7.6–9.1 and −70.9 to −84.0‰ in the porphyry mineralization episode, and 6.4–7.1 and −65.7 to −72.1‰ in the orogenic mineralization episode, overlapping magmatic and metamorphic ranges, respectively. The pyrite δ 34 S values range from 3.5 to 4.9‰, falling into the magmatic range. Pyrite in porphyry and orogenic mineralization episodes yield Re–Os isotope ages of 269.1 ± 2.9 and 257.4 ± 2.4 Ma. The porphyry and orogenic gold mineralizations are genetically associated with the quartz syenite porphyry and Kanggur strike-slip shear activity, respectively.
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