Crustal-Extension Ag-Pb-Zn Veins in the Xiong'ershan District, Southern North China Craton: Constraints from the Shagou Deposit
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Abstract:
The Shagou vein-type Ag-Pb-Zn deposit in the Xiong’ershan district, southern margin of the North China craton, is hosted within amphibolite facies metamorphic rocks of the Late Archean to early Paleoproterozoic Taihua Group. The Ag-Pb-Zn veins are localized in NE- to NNE-trending brittle faults and typically display symmetrical zoning consisting of siderite, quartz + sphalerite, galena, and quartz + calcite from the margin toward the center of each vein. Ore-related hydrothermal alteration is well developed on both sides of the veins, dominated by silicification, sericitization, chloritization, and carbonatization. Sericite separates extracted from a major Ag-Pb-Zn vein yield a 40 Ar/ 39 Ar plateau age of 140.0 ± 1.0 Ma (1 σ ) and isochron age of 141.1 ± 1.6 Ma (1 σ ), indicating that mineralization occurred at the beginning of Early Cretaceous. Field and textural relationships indicate four hydrothermal stages marked by assemblages of quartz + siderite (stage I), quartz + sphalerite + ankerite (stage II), quartz + galena + silver minerals + ankerite (stage III), and quartz + calcite (stage IV), respectively. Silver minerals are abundant in all veins and are composed of, in paragenetic order, argentiferous tetrahedrite, polybasite, jalpaite, argentite, and native silver. These silver minerals commonly occur as replacements of galena, chalcopyrite, and other sulfides, or as fillings of microfractures in sulfides and quartz. Microthermometric measurements of primary fluid inclusions in quartz, carbonates, and sphalerite from various hydrothermal stages indicate that ore minerals were deposited at intermediate temperatures (267°–157°C) from aqueous-carbonic to aqueous fluids with moderate salinities (7.2–15.9 wt % NaCl equiv). Coexisting galena-sphalerite pair yields sulfur isotope equilibrium temperatures of 205° to 267°C, consistent with the overall homogenization temperatures of fluid inclusions. The microthermometric data also indicate that both fluid mixing and fluid-rock interaction were important mechanisms for ore precipitation. Carbonate minerals (siderite, ankerite, calcite) spanning the entire mineralization history have δ 13 C V-PDB values of −5.2 to −1.4‰ and δ 18 O V-SMOW of 10.9 to 15.0‰, corresponding to calculated values for the ore fluids of −6.5 to −1.8‰ and 1.4 to 5.4‰, respectively. δ 34 S V-CDT values of sulfide minerals (pyrite, sphalerite, galena) range from 1.1 to 5.5‰, consistent with a deep-seated sulfur source. Galena separates have 206 Pb/ 204 Pb ratios of 17.472 to 17.813, 207 Pb/ 204 Pb ratios of 15.411 to 15.498, and 208 Pb/ 204 Pb ratios of 38.178 to 38.506. The isotope data, together with geological and geochronological evidence, favor a primary metamorphic source for sulfur and other components in the ore fluids. A synthesis of available data suggests that the Shagou deposit is a typical vein-type Ag-Pb-Zn deposit that formed under an extensional geodynamic setting associated with tectonic reactivation of the North China craton during the late Mesozoic, a time period that is manifested by pervasive magmatism, widespread formation of metamorphic core complexes, and development of faulted basins throughout the eastern part of the craton. Metamorphic devolatilization of the Meso-Neoproterozoic marine sedimentary rocks previously subducted beneath the Xiong’ershan district, facilitated by extensive magmatism and elevated heat flow due to lithospheric extension, could have provided large amounts of ore fluids responsible for the Ag-Pb-Zn mineralization. The NE- to NNE-trending faults affiliated with the transcrustal Machaoying fault may have acted as pathways for the upward migration of deep-seated metamorphic fluids. Mixing of the metamorphically derived fluids with meteoric waters ultimately resulted in deposition of the Ag-Pb-Zn veins in brittle extensional structures.Keywords:
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The Napo Formation of Cretaceous age in the Oriente basin, Ecuador, is an important sandstone reservoir. The «U» sandstone is one oil interval within the Napo Formation. It is buried at a depth of 1500 m in the eastern part of the basin and down to 3100 m in the western part. This sandstone display higher porosity values (av. 20%) than other reservoirs in the region. The sandstone was deposited in fluvial, transitional and marine environments, and their correlation with the sequence stratigraphy is related to HST, LST, TS. «U» sandstone is fine to medium grained quartzarenite and subordinate subarkose. The principal cements are carbonates, quartz overgrowth and kaolin, with scarce amounts of pyrite and chlorite. Carbonate cements include: Eogenetic siderite (S1), mesogenetic and post-compactional calcite, Fe-dolomite, ankerite and siderite (S2). Early siderite helped to retain porosity by supporting the sandstone framework against compaction. Dissolution of feldspars and mesogenetic carbonate cements is the main mechanism for secondary porosity development during mesodiagenesis. The stable isotope composition of the S1 siderite are consistent with precipitation from meteoric waters. The anomalous low a18O� values of some of these carbonate phases could reflect the replacement and recristalization from S1 to S2 siderite at deep burial and high temperature. However, due to this higher Mg content, siderite S2 could have precipitated as a result of the thermal descarboxilation of the Mg rich organic matter. The last carbonate cements to precipitate were dolomite/ankerite. The negative a18O� in these cements is related to the continued precipitation at higher temperature and burial depth.
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Summary Aqueous CO2-containing environment is ubiquitous in oil and gas production. Carbonate scales (e.g., calcite) tend to form in such an environment. Meanwhile, the CO2 corrosion of mild steel infrastructure may result in corrosion-induced scales including siderite (FeCO3). Previously, siderite was generally treated as a corrosion problem rather than a scale problem. However, the relationship between the corrosion-induced scale and other metal carbonate scales on the steel surface is unclear. For example, how does siderite influence calcite deposition on the mild steel? In this study, the mild steel corrosion and mineral carbonate scaling behaviors were investigated simultaneously in the presence of various cations such as Ca2+ and Mg2+. We observed a two-layer scale structure on the mild steel surface under simulated oilfield conditions. The inner layer is an iron-containing carbonate scale such as ankerite or siderite, while the outer layer is calcite. In addition, calcite deposition at a very low saturation index was observed when the inner layer was present. Furthermore, a common scale inhibitor [diethylenetriaminepentakis(methylenephosphonic acid) or DTPMP] can effectively mitigate calcite, siderite, and ankerite formation on the steel surface, but meanwhile, aggravate the steel corrosion because of the absence of protective scale layers.
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Abstract Nodules containing siderite and calcite in the Yorkshire Lias have been studied quantitatively using petrographic, X-ray and chemical methods. Ankerite is recorded from the Lias for the first time. It is shown how the relative abundance of early diagenetic siderite and calcite correlates with sandiness of the sediment and provides an index of environmental change.
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Abstract Carbonates of the magnesite-siderite series have been found and analysed in carbonatites from the Lueshe, Newania, Kangankunde, and Chipman Lake complexes. This series has been represented until now only by a few X-ray identifications of magnesite and three published analyses of siderite and breunnerite (magnesian siderite). Most of the siderite identified in carbonatites in the past has proved to be ankerite, but the new data define the complete solid-solution series from magnesite to siderite. They occur together with dolomite and ankerite and in one rock with calcite. The magnesites, ferroan magnesites and some magnesian siderites may be metasomatic/hydrothermal in origin but magnesian siderite from Chipman Lake appears to have crystallized in the two-phase calcite + siderite field in the subsolidus CaCO 3 -MgCO 3 -FeCO 3 system. Textural evidence in Newania carbonatites indicates that ferroan magnesite, which co-exists with ankerite, is a primary liquidus phase and it is proposed that the Newania carbonatite evolved directly from a Ca-poor, Mg-rich carbonatitic liquid generated by partial melting of phlogopite-carbonate peridotite in the mantle at pressures >32 kbar.
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