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    Fault and stratigraphic controls on volcanogenic massive sulphide deposits in the Strelley Belt, Pilbara Craton, Western Australia
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    Abstract The Upper Devonian ABM deposit is a bimodal-felsic, replacement-style volcanogenic massive sulfide (VMS) deposit within the Finlayson Lake district in Yukon, Canada. The deposit is hosted by predominantly felsic volcanic rocks of the upper Kudz Ze Kayah formation that were deposited in an active back-arc basin in three sequences consisting of interbedded felsic volcaniclastic rocks and argillites, and felsic lava flows and domes, and felsic and mafic sills. The felsic rocks fall into two groups, Felsic A and Felsic B (FA and FB), based on immobile elements and their ratios. Relative to the FB group, the FA group has high Zr concentrations (>550 ppm) and generally higher contents of high field strength elements. The FA/FB chemostratigraphy roughly coincides with the lithostratigraphic sequences. Sequence 2 hosting the mineralization consists of FB felsic rocks; the hanging-wall Sequence 3 and footwall Sequence 1 felsic rocks have FA signatures. An argillite lens, recording a period of volcanic quiescence, occurs at the upper contact of Sequence 2. From reconstruction of the basin architecture, two sets of synvolcanic faults are inferred. The synvolcanic faults were interpreted based on thickness changes of volcanosedimentary units and the distribution of coherent rocks. During breaks in volcanism, synvolcanic faults acted as conduits for upwelling hydrothermal fluids, which were diverted laterally into unconsolidated volcaniclastic rocks and formed the replacement-style VMS mineralization. Although the mineralized lenses are hosted by FB felsic rocks, their replacement-style nature implies that the mineralizing processes occurred during the break in volcanism and were genetically associated with the overlying FA felsic volcanic rocks.
    Felsic
    Citations (6)
    Abstract The Neoproterozoic-Cambrian Wales Group and Ordovician-early Silurian Moira Sound unit of Prince of Wales Island, Alaska, USA, host numerous volcanic-hosted massive sulfide (VHMS) deposits and occurrences, including the Niblack VHMS deposits. Previous attempts to determine the age of the felsic volcanic host rocks in the Niblack area have resulted in conflicting results and interpretations. We have utilized chemical abrasion-isotope dilution-thermal ionization mass spectrometry (CA-ID-TIMS) U-Pb zircon geochronology to acquire highly precise crystallization and maximum depositional ages for a total of six samples of felsic volcanic and intrusive rocks from Niblack. This study establishes age constraints for the Niblack felsic succession of (1) crystallization ages of 565.1 ± 0.9 and 564.8 ± 1.0 Ma for coherent rhyolite flows, (2) maximum depositional ages of 565.3 ± 0.9 and 565.2 ± 0.9 Ma for felsic volcaniclastic rocks, (3) a crystallization age of 565.2 ± 0.9 Ma for a quartz-feldspar-phyric subvolcanic sill, and (4) a crystallization age of 564.8 ± 1.0 Ma for a felsic dike that crosscuts the Niblack felsic succession. These results indicate that the ~200-m-thick Niblack felsic succession and VHMS deposits formed during one episode of felsic volcanism at ca. 565.1 ± 0.9 Ma and are thus confirmed as part of the Neoproterozoic Wales Group. Results of this study provide the first chronostratigraphic framework for felsic volcanism associated with VHMS deposit formation at Niblack and have implications for mineral exploration on Prince of Wales Island and elsewhere in the Alexander terrane.
    Felsic
    Geochronology
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    The lower stratigraphy of Agnew-Wiluna greenstone belt is composed of two main elements; a mafic/komatiite domain and a felsic/komatiite/basalt domain. Previous stratigraphic models show the mafic domain overlying the felsic domain. Komatiites in the latter host the vast majority of the nickel sulphide endowment of the belt (>20 significant deposits) whereas those in the mafic domain contain 3 and 4 relatively small deposits. Recently published geochemical data from well-preserved mafic domain rocks exposed in the Agnew area opens up the possibility to match these units with mafic rocks within the more structurally disrupted felsic domain. Analytical data from basalts at the Cliffs and Mount Keith Ni deposits and from the Wiluna Au mine sequence show that these can be matched to the basalt sequence stratigraphically below the Agnew Komatiite at Agnew and also show that basalts previously thought to occupy different stratigraphic positions (Centenary Bore and MacFarlanes Basalts) are laterally equivalent but structurally displaced. The revised stratigraphic model together with available age dates show that komatiites in both domains, Mount Keith and Cliffs/Agnew Komatiites, are laterally equivalent and part of the 2705 Ma Kalgoorlie-Kurnalpi komatiite LIP. This greatly enhances the Ni prospectivity of komatiites within the mafic domain which, previously being thought younger, were historically considered less prospective. The footwall to the komatiite is composed of basalt (Never Can Tell Basalt, in the mafic domain) and felsic sequences (Mount Keith Dacite in the felsic domain) that are laterally separated but occupy the same stratigraphic position and together with the komatiite correlate with the Kambalda Sequence in the south of the Kalgoorlie Terrane. The oldest crystallisation ages from the Mount Keith Dacite are 2719–2725 Ma but whether these rocks belong to the Kalgoorlie or Youanmi Terrane is currently unknown. The Kalgoorlie-aged sequence has an unconformable contact with underlying Youanmi-aged sequence (the latter including dates of 2724–2729, 2734, 2749 Ma) composed of basalt, komatiitic basalt, komatiite and minor felsic volcanic (in decreasing stratigraphic order; felsic volcanics, Songvang Basalt, Hickies Bore Basalt, Donegal Komatiite, Butchers Well Basalt). The Youanmi sequence is exposed throughout the AWB, is present in the Leonora area to the immediate south and extends eastward to other areas within the northern part of the Kalgoorlie-Kurnalpi Terranes.
    Felsic
    Greenstone belt
    Yilgarn Craton
    The Dunnage Zone of the Newfoundland Appalachians hosts diverse Cambrian–Ordovician volcanogenic massive sulfide (VMS) deposits. The peri-Laurentian Notre Dame Subzone contains Cu–Zn–Au mafic and bimodal mafic deposits in ∼501–485 Ma ophiolitic rocks and Zn–Pb–Cu–(Au–Ag) deposits in ∼471–465 Ma bimodal rifted continental arc sequences (e.g., Buchans). The peri-Gondwanan rocks of the Exploits Subzone host Zn–Pb–Cu–(Au–Ag) bimodal felsic, felsic siliciclastic, and Zn–Ag–Au hybrid bimodal felsic deposits in the ∼513–486 Ma Victoria Lake supergroup; Cu–Zn bimodal felsic to bimodal mafic deposits of the ∼486 Ma Wild Bight Group; and Cu–(Au) mafic siliciclastic deposits of the ∼466 Ma Great Burnt Lake/South Pond belt. Regardless of age or stratigraphic hosts, all VMS deposits are associated with specific magmatic assemblages and extensional tectonism (i.e., rifting). Gold-enriched deposits of the Rambler-Ming district are associated with felsic rocks that formed via slab melting and subsequent melt-mantle wedge interaction, which likely enhanced precious metal enrichment in these deposits. Whereas many deposits exhaled on the seafloor, some deposits formed via subseafloor replacement of host units or as re-sedimented sulfides generated in sediment-gravity flows. Metals in the deposits were derived from leaching of underlying footwall rocks; however, Au–Ag- and epithermal suite element-enriched deposits show evidence for metal contributions from magmatic hydrothermal fluids. Sulfur in deposits was derived predominantly from leaching of H 2 S from underlying footwall rocks and from thermochemical sulfate reduction of seawater sulfate, with lesser input from bacteria-derived H 2 S and magmatic-hydrothermal-derived H 2 S. Despite recent research advances and historic mining, numerous questions remain unresolved and provide opportunities for future study.
    Felsic
    Siliciclastic
    Continental arc
    Metallogeny
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    Abstract The Rio Tinto deposit is a giant volcanogenic massive sulfide deposit (VMS) that contains more than 500 Mt of pyrite-rich massive sulfides and more than 2 Gt of mineralized stockwork. Three broad lithostratigraphic groups occur in the regional stratigraphy: the phyllite-quartzite group, the volcano-sedimentary complex, and the Baixo Alentejo Flysch Group. These three major packages reflect the evolution of a depositional environment from a stable platform to deposition in pull-apart continental basins during oblique subduction and collision and coeval synorogenic flysch sequence. The volcano-sedimentary complex, which hosts massive sulfide mineralization at Rio Tinto, can be divided into four major units: (1) the Mafic Siliciclastic Unit, (2) the Lower Sedimentary Unit, (3) the Felsic Unit, and (4) the Upper Sedimentary Unit. The Felsic Unit is further subdivided based on new U-Pb zircon geochronology into three distinct subunits. Felsic Unit I (ca. 356 Ma) includes dome complexes dominated by rhyodacite and reflects the onset of felsic magmatism in the region. Felsic Unit II (ca. 352–348 Ma) represents the main interval of volcanic activity, also dominated by rhyodacite domes and related aprons, and is associated with widespread VMS mineralization. Felsic Unit III (ca. 340 Ma) reflects a late pulse of rhyolitic volcanism. Massive sulfides occur as two different styles of mineralization: (1) replacive ores as discordant pipes hosted by glass-rich felsic rocks and enclosed by a large zone of stockwork-like mineralization and (2) overlying shale-hosted exhalative mineralization in small anoxic basins, probably formed during the collapse of the volcanic domes of Felsic Unit II in the Middle-Late Tournaisian. New lithogeochemical data illustrate two types of mafic rocks in the Mafic Siliciclastic Unit: a basaltic andesite and a high–Ti-Zr basalt, both of tholeiitic affinity. Using immobile element ratios (heavy rare earth elements [HREEs], Al, Y, Zr, and Ti) of the Felsic Unit, fundamental differences have been recognized between the subunits. The unmineralized Felsic Unit I is characterized by high Zr content (225–300 ppm) and a pronounced Eu negative anomaly, and probably represents the most fractionated rocks. Felsic Unit II is characterized by Zr values between 50 and 200 ppm. The low Zr values of the mineralized unit contrast with the typically high Zr values of the felsic rocks related to volcanogenic massive sulfides elsewhere and, at a regional scale, can help to discriminate potentially fertile domes from barren volcanism.
    Felsic
    Stockwork
    Geochronology
    Citations (9)