Historic Environment Scotland (HES), a non-departmental public body of the Scottish Government charged with safeguarding the nation’s historic environment, is directly responsible for 335 sites of national significance, most of which are built from stone. Similar to other heritage organisations, HES needs a system that can store and present conservation and maintenance information for historic sites; ideally, the same system could be used to plan effective programmes of maintenance and repair. To meet this need, the British Geological Survey (BGS) has worked with HES to develop an integrated digital site assessment system that provides a refined survey process for stone-built (and other) historic sites. Based on the BGS System for Integrated Geoscience Mapping (BGS▪SIGMA)—an integrated workflow underpinned by a geo-spatial platform for data capture and interpretation—the system is built on top of ESRI’s ArcGIS software, and underpinned by a relational database. Users can populate custom-built data entry forms to record maintenance issues and repair specifications for architectural elements ranging from individual blocks of stone to entire building elevations. Photographs, sketches, and digital documents can be linked to architectural elements to enhance the usability of the data. Predetermined data fields and supporting dictionaries constrain the input parameters to ensure a high degree of consistency and facilitate data extraction and querying. Presenting the data within a GIS provides a versatile planning tool for scheduling works, specifying materials, identifying skills needed for repairs, and allocating resources. The overall condition of a site can be monitored accurately over time by repeating the survey at regular intervals (e.g. every 5 years). Other datasets can be linked to the database and other geospatially referenced datasets can be superimposed in GIS, adding considerably to the scope and utility of the system. The system can be applied to any geospatially referenced object in a wide range of situations thus providing many potential applications in conservation, archaeology and related fields.

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Photoactivatable metal complexes: from theory to applications in biotechnology and medicine

Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences (2013)

Nichola A. Smith Peter J. Sadler

This short review highlights some of the exciting new experimental and theoretical developments in the field of photoactivatable metal complexes and their applications in biotechnology and medicine. The examples chosen are based on some of the presentations at the Royal Society Discussion Meeting in June 2012, many of which are featured in more detail in other articles in this issue. This is a young field. Even the photochemistry of well-known systems such as metal-carbonyl complexes is still being elucidated. Striking are the recent developments in theory and computation (e.g. time-dependent density functional theory) and in ultrafast-pulsed radiation techniques which allow photochemical reactions to be followed and their mechanisms to be revealed on picosecond/nanosecond time scales. Not only do some metal complexes (e.g. those of Ru and Ir) possess favourable emission properties which allow functional imaging of cells and tissues (e.g. DNA interactions), but metal complexes can also provide spatially controlled photorelease of bioactive small molecules (e.g. CO and NO)--a novel strategy for site-directed therapy. This extends to cancer therapy, where metal-based precursors offer the prospect of generating excited-state drugs with new mechanisms of action that complement and augment those of current organic photosensitizers.

10.1098/rsta.2012.0519

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The development of digital field data collection systems to fulfil the British Geological Survey mapping requirements

Colm Jordan Emma Bee Nichola A. Smith Russell Lawley Jon Ford

Geological mapping with pen and paper is proving inefficient in many respects in the digital age. With this in mind, the British Geological Survey (BGS) instigated the System for Integrated Geospatial MApping programme (SIGMA) to improve the mapping workflow by evaluating and implementing effective digital procedures for baseline data review, geological data acquisition, and geological mapping and modelling. The project has developed digital field data capture systems to collect information for output to a Geographical Information System (GIS) and digital geological maps. BGS first explored the concept of digital field data collection in the early 1990’s with the conclusion that the mobile computing hardware available at the time was not suitable. An effective digital field data capture system will have a number of advantages over the conventional analogue recording systems. The first is to increase the efficiency of data collection and its subsequent manipulation, predominantly by reducing the time spent copying analogue field data to databases/GIS. The system design will ensure that all field geologists record the same range of structured data and also that mandatory or important information is not omitted. Drop-down menus and approved dictionaries are incorporated to standardise nomenclature. An additional advantage of a digital field system is that a GIS of baseline data (e.g. a series of historic topographic maps) can be uploaded onto the mobile PC, ensuring that new data are collected in the context of prior geological knowledge and with a wide range of other geographic and environmental datasets. It should be noted that while we strive to guarantee corporate consistency and common standards by structuring our data collection, there must also be a degree of flexibility so that geologists are not unduly constrained. Moreover, when we replicate functions that are ideally suited to pencil and paper, such as drawing sketches, we must ensure that the digital solutions are fit for purpose and do not leave field geologists yearning for ‘the old days’.

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