The Jiaodong Peninsula is located on the junction of the North China Craton (NCC) and South China Block (SCB), where Mesozoic igneous rocks are widespread. However, the petrogenesis and tectonic settings for these Mesozoic igneous rocks are still controversial. In this study, we present detailed geochronological and geochemical analyses of quartz monzonite, monzogranite, syenogranite, and alkali feldspar granite in the Qingdao area, east of the Jiaodong Peninsula, to constrain their petrogenesis and tectonic setting. Zircon U–Pb dating shows that they mainly formed in the Early Cretaceous (120.5–113.1 Ma). Quartz monzonite exhibits adakitic geochemical features (e.g., low Y and high Sr/Y). Combined with its Sr–Nd–Hf isotopic features, we suggest that quartz monzonite may have been produced by the partial melting of phengite-bearing eclogites at the base of the thickened continental crust of the NCC. In contrast, monzogranite and syenogranite exhibit I-type granite affinities, whereas alkali feldspar granite exhibits features consistent with A-type granite. The strongly negative εHf(t) and εNd(t) values of the I-type rocks indicate that they were most likely produced through partial melting of granitic gneisses from the NCC, whereas A-type magmas may be formed through fractional crystallization from the non-adakitic granitic magma. Combined with previous studies, we suggest that these granitoids were formed in a lithospheric extensional setting via the rollback of the subducted Paleo-Pacific slab, which resulted in the reworking of the deep crust beneath the Sulu ultrahigh-pressure metamorphic belt.
Carbonate recycling in subduction zones has a strong influence on arc magmatism and carbon reservoirs in the mantle. However, geochemical evidence of carbonate recycling during subduction, especially at sub-arc depths, is rare and the related process is poorly understood. In this study, we document high-Mg olivines (81–91 mol.% forsterite) with extremely low Ni concentrations (mostly <600 ppm), which occur in host dacites recovered from the southwestern Okinawa Trough (SWOT). The temperature–pressure of crystallization had a negligible effect on the Ni contents of the olivines, and reactions between primary basaltic magmas and the lithospheric mantle were also insignificant. Small sulphide droplets are present in the olivines, which suggest that sulphide–silicate melt immiscibility occurred during the early stages of magmatic evolution. Although early segregation of sulphide melts could reduce the Ni contents of the primitive magmas, our forward modelling suggests that sulphide segregation cannot solely explain the low Ni contents. Therefore, the most likely explanation for low Ni concentrations is the interaction between Ca-rich carbonate melts and the mantle wedge, forming an olivine-rich mantle source by consumption of orthopyroxene, as indicated by the extremely low Ni/Mg and high Ca/Fe ratios of magmatic olivines. Given that the SWOT is located just ~100 km above the Wadati–Benioff zone, our results provide rare evidence for carbonate recycling at sub-arc depths in an active subduction zone.
Common commercial porcine acellular dermal matrix (PADM) products take the form of a thin membrane. Given its dense structure, delaying vascularization after implantation remains an issue to be solved. In addition, overlaying multiple sheets to address deep wounds and large tissue defects that are difficult to repair by self-tissues could hinder tissue ingrowth, angiogenesis, and integration. Here, we creatively prepared PADM microparticles through a homogenizing treatment and crosslinked them to ADM sponges by thermal crosslinking (VT-ADM) and thermal-glutaraldehyde crosslinking (GA-ADM). The resulting VT-ADM was thicker than GA-ADM, and both maintained the natural dermal matrix microstructure and thermal stability. The porosity of GA-ADM (mean 82%) was lower than that of VT-ADM (mean 90.2%), but the mechanical strength and hydrophilicity were significantly higher. The two types of ADM sponges showed no obvious difference in cell adhesion and proliferation without cytotoxicity. Furthermore, the human adipose stem cells were co-cultured with ADM sponges which promoted proliferation, tube formation, and migration of endothelial cells, and the GA-ADM group exhibited better migration behavior. There were no markable differences among expressions of pro-angiogenesis genes, including vascular endothelial growth factor, insulin-like growth factor-1, and epidermal growth factor. In a nude mouse model, the VT-ADM and GA-ADM pre-cultured with human adipose stem cells for 1 week in advance were implanted subcutaneously. The VT-ADM and the GA-ADM showed great histocompatibility without local redness, swelling, or necrosis. The vascular density of the local skin flap above the material was visualized using indocyanine green and showed no statistical difference between the two groups. The collagen tissue deposition in the pores and vessel formation within the sponges increased with time. Although VT-ADM had a higher degradation rate in vivo, the integrity of the two scaffolds was preserved. Collectively, the VT-ADM and the GA-ADM retained a natural matrix structure and presented biocompatibility. Thus, the above-mentioned two crosslinking methods for ADM sponges are safe and practicable. The novel ADM sponges with good physicochemical and biological properties are no longer limited to membrane tissue regeneration but could also realize structure remodeling where they act as scaffolds for a soft tissue filler and three-dimensional reconstruction of the tissue with strength requirements.
<p>Dehydrated fluids expelled from serpentinized mantle in the subducted slab are gradually recognised as a vital role in generating arc magmatism and element cycling in the Earth. However, it remains not clear about their recycling at various depth in subduction zones and if slab serpentinite-derived fluids contribute to the genesis of lavas from the back-arc basins. Here, we study the magnesium (Mg) isotopic compositions of lavas from the Okinawa Trough (OT) and Lau basin (LB) as Mg isotopes have shown great potential to trace dehydration of slab serpentinites in recent years. Overall, lavas from the OT and LB have averagely heavier Mg isotopic compositions relative to the mid-ocean ridge basalt (MORB) mantle, which could be attributed to the involvement of slab serpentinite-derived fluids rather than crustal assimilation or input of subducted sediments as indicated by the isotopic modelling results. The &#948;<sup>26</sup>Mg values of the southern OT (SOT) and southern LB (SLB) are generally higher than the middle OT (MOT) and northern LB (NLB), respectively, with an average of -0.11 &#177; 0.06&#8240; (2SD, n=5) for the SOT, -0.20 &#8240; &#177; 0.04 (2SD, n=5) for the MOT, -0.13 &#8240; &#177; -0.08 for the SLB (2SD, n=6) and -0.19 &#8240; &#177; 0.06 (2SD, n=10) for the NLB. The binary modelling results have shown that various amounts of serpentinite-derived fluids could explain the variations in Mg isotopic compositions observed in the OT and LB. Combined published &#948;<sup>26</sup>Mg values in subduction zones with our data, the thermal structure of inter-subduction zone may play a first control on the signal of Mg-rich serpentinite-derived fluids. By contrast, the contributions of these fluids to different segments in a specific subduction zone may depend on the slab depth beneath magmatic activity sites.</p>
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