Physical and biogeochemical heterogeneity dramatically impacts fluid flow and reactive solute transport behaviors in geological formations across scales. From micro pores to regional reservoirs, upscaling has been proven to be a valid approach to estimate large-scale parameters by using data measured at small scales. Upscaling has considerable practical importance in oil and gas production, energy storage, carbon geologic sequestration, contamination remediation, and nuclear waste disposal. This review covers, in a comprehensive manner, the upscaling approaches available in the literature and their applications on various processes, such as advection, dispersion, matrix diffusion, sorption, and chemical reactions. We enclose newly developed approaches and distinguish two main categories of upscaling methodologies, deterministic and stochastic. Volume averaging, one of the deterministic methods, has the advantage of upscaling different kinds of parameters and wide applications by requiring only a few assumptions with improved formulations. Stochastic analytical methods have been extensively developed but have limited impacts in practice due to their requirement for global statistical assumptions. With rapid improvements in computing power, numerical solutions have become more popular for upscaling. In order to tackle complex fluid flow and transport problems, the working principles and limitations of these methods are emphasized. Still, a large gap exists between the approach algorithms and real-world applications. To bridge the gap, an integrated upscaling framework is needed to incorporate in the current upscaling algorithms, uncertainty quantification techniques, data sciences, and artificial intelligence to acquire laboratory and field-scale measurements and validate the upscaled models and parameters with multi-scale observations in future geo-energy research.
This paper examines the remediation techniques of cadmium (Cd)-contaminated dredged river sediments after land disposal in a city in East China. Three remediation techniques, including stabilization, soil leaching, and phytoremediation, are compared by analyzing the performance of the techniques for Cd-contaminated soil remediation. The experimental results showed that the stabilization technique reduced the leaching rate of soil Cd from 33.3% to 14.3%, thus effectively reducing the biological toxicity of environmental Cd, but the total amount of Cd in soil did not decrease. Leaching soil with citric acid and oxalic acid achieved Cd removal rates of 90.1% and 92.4%, respectively. Compared with these two remediation techniques, phytoremediation was more efficient and easier to implement and had less secondary pollution, but it took more time, usually several years. In this study, these three remediation techniques were analyzed and discussed from technical, economic, and environmental safety perspectives by comprehensively considering the current status and future plans of the study site. Soil leaching was found to be the best technique for timely treatment of Cd contamination in dredged river sediments after land disposal.
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