Nitrogen (N) addition is a simple and effective field management approach to enhancing plant productivity. Nonetheless, the regulatory mechanisms governing nitrogen concentrations and their effect on soil enzyme activity, nutrient levels, and seed yield in the Festuca kirilowii seed field have yet to be elucidated. Therefore, this study sought to investigate the effect of N fertilizer application on soil enzyme activities, soil nutrients, and seed yield of F. kirilowii Steud cv. Huanhu, the only domesticated variety in the Festuca genus of the Poaceae family, was investigated based on two-year field experiments in the Qinghai–Tibet Plateau (QTP). Results showed that N input significantly affected soil nutrients (potential of hydrogen, total nitrogen, organic matter, and total phosphorus). In addition, soil enzyme activities (urease, catalase, sucrase, and nitrate reductase) significantly increased in response to varying N concentrations, inducing changes in soil nutrient contents. Introducing N improved both seed yield and yield components (number of tillers and number of fertile tillers). These findings suggest that the introduction of different concentrations of N fertilizers can stimulate soil enzyme activity, thus hastening nutrient conversion and increasing seed yield. The exhaustive evaluation of the membership function showed that the optimal N fertilizer treatment was N4 (75 kg·hm −2 ) for both 2022 and 2023. This finding provides a practical recommendation for improving the seed production of F. kirilowii in QTP.
Relatively little attention has been given to variations in ore‐forming metal sources of Pb–Zn polymetallic deposits hosted in or near the Linzizong volcanic rocks from the eastern to western Gangdese belt. Based on the S and Pb isotopic data of typical Pb–Zn polymetallic deposits from the eastern to western Gangdese, the ore‐forming sources are discerned. The δ 34 S V‐CDT values of the typical Pb–Zn polymetallic deposits in the Gangdese metallogenic belt have a relatively large range of −11.6‰ to 6.0‰, different from those of the porphyry Cu ± Mo ± Au deposits (mainly vary from −2.0‰ to 1.0‰) in the Gangdese metallogenic belt, indicating that the sulphur in the ore‐forming fluid of Pb–Zn polymetallic deposits was dominantly of magmatic origin, but also influenced by strata nearby. The Nuocang and Beina deposits in the western Gangdese have a predominantly upper crustal source of Pb (average values: 207 Pb/ 204 Pb = 15.705, 208 Pb/ 204 Pb = 39.102), while the Narusongduo and Dexin deposits in the central Gangdese and the Leqingla and Xingaguo deposits in the eastern Gangdese are characterized by a mixed source in which Pb was derived from both the subducted slab and the ancient Lhasa basement. From the eastern to western Gangdese, Pb isotopic data show a gradually increasing scale of crustal materials from the Lhasa terrane basement. Combined with the geochemical data of the ore‐related intrusions and Linzizong volcanic rocks from the six deposits, or nearby, we proposed that the heterogeneity of Lhasa terrane crust resulted in more ancient Lhasa basement components contributing to ore‐forming sources from the eastern to western Gangdese. Moreover, relatively higher contents of Au, Ag elements could be identified in the Linzizong volcanic rocks of the western Gangdese than those of in the central and eastern Gangdese. Therefore, in addition to finding the cryptoexplosive breccia, epithermal, skarn, hydrothermal vein‐type Pb–Zn polymetallic deposits, there is exploration potential for epithermal Au–Ag deposits associated with the Linzizong volcanic rocks, western Gangdese.
Nanometer-thick passive films on metals usually impart remarkable resistance to general corrosion but are susceptible to localized attack in certain aggressive media, leading to material failure with pronounced adverse economic and safety consequences. Over the past decades, several classic theories have been proposed and accepted, based on hypotheses and theoretical models, and oftentimes, not sufficiently nor directly corroborated by experimental evidence. Here we show experimental results on the structure of the passive film formed on a FeCr15Ni15 single crystal in chloride-free and chloride-containing media. We use aberration-corrected transmission electron microscopy to directly capture the chloride ion accumulation at the metal/film interface, lattice expansion on the metal side, undulations at the interface, and structural inhomogeneity on the film side, most of which had previously been rejected by existing models. This work unmasks, at the atomic scale, the mechanism of chloride-induced passivity breakdown that is known to occur in various metallic materials.
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