Abstract. Carbon dioxide is considered an inert gas that rarely participates in atmospheric chemical reactions. However, we show here that CO2 is involved in some important photo-oxidation reactions in the atmosphere through the formation of carbonate radicals (CO3∙-). This potentially active intermediate CO3∙- is routinely overlooked in atmospheric chemistry regarding its effect on sulfate formation. Present work demonstrates that SO2 uptake coefficient is enhanced by 17 times on mineral dust particles driven by CO3∙-. It can be produced through two routes over mineral dust surfaces: i) hydroxyl radical + CO32-; ii) holes (h+) + CO32-. Employing a suite of laboratory investigations of sulfate formation in the presence of carbonate radical on the model and authentic dust particles, field measurements of sulfate and (bi)carbonate ions within ambient PM, together with density functional theory (DFT) calculations for single electron transfer processes in terms of CO3∙--initiated S(IV) oxidation, a new role of carbonate radical in atmospheric chemistry is elucidated.
Forests are composed of landscape spatial units (patches) of different sizes, shapes, and characteristics. The forest landscape pattern and its trends are closely related to resistance to disturbance, restoration, stability, and the biodiversity of the forest landscape and directly influence the benefits and sustainable exploitation of forest landscape resources. Therefore, forest landscape patterns and the driving forces have increasingly attracted the attention of researchers. The present study analyzed the spatial and temporal dynamics of woodland landscape patterns in typical hilly mountainous areas in southern China using ArcGIS, landscape pattern index, and morphological spatial pattern analysis. Meanwhile, a logistic regression model was used to analyze the drivers of woodland change in Anyuan County from three aspects: natural, geographic location, and socio-economic conditions. The total area of woodland decreased during the 10-year study period, with a net decrease of 4959.27 ha, mainly due to conversion into cultivated land, garden land, and construction land. Patch density, edge density, and aggregation index of woodlands increased over time, indicating enhanced fragmentation, stable and complex patch edges, and increased patch connectivity. Conversely, the highest patch index values exhibited decreasing trends, indicating decreases in the dominant patch type. Morphological spatial pattern analysis results showed that the core area was dominant and the islet area increased over time, which also indicates enhanced fragmentation. Forest landscape change is the result of environmental change, ecological processes, and human disturbance, with geographical location and social economy having greater influences on forest landscape change. Human activities such as navel orange cultivation, returning cultivated land to forest, and land occupation for construction were the major factors driving woodland change. The results provide reference that could facilitate forest management and sustainable forest resource utilization.
Land use changes are important aspects of global change and affect regional water cycles, environmental quality, biodiversity and terrestrial ecosystems. To understand the temporal and spatial land use change in the Jialing River Basin and its impacts on the hydrological cycle, land use change models and the variable infiltration capacity (VIC) model were applied separately to the Jialing River Basin. Real change and final change were analyzed to determine the consequences of land use changes and their hydrological consequences. Real change is defined as the total variation during a fixed period, including increases and decreases. Thus, real change is the sum of the absolute values of the decrease and the increase. Final change is defined as the difference between the beginning and end of a given period for a specific factor. Overall, the amounts of settlement and shrub land area changed significantly in the entire Jialing River (with final change rates of 20.77% and −16.07%, respectively, and real change rates of 34.2% and 30.1%, respectively, from 1985 to 1995, as well as final and real change rates of 29.37%, 12.40%, 39.9% and 32.8%, respectively, from 1995 to 2000). Compared with the final change, the real change highlighted the rate of change and the change in woodland area. The land use changes in the Lueyang (LY), Shehong (SH) and Fengtan (FT) subcatchments were more dynamic than in the other subcatchments. The economy, population and macro-policy were the main factors responsible for driving the land use changes. The decrease in woodland area in the LY subcatchment corresponded with an increase in evapotranspiration (ET) and with decreases in the other hydrological elements. Overall, the final changes in the hydrological elements in the LY, SH and FT subcatchments were not significant due to the average and compensation effects. The LY subcatchment was mainly affected by the average effect, whereas the SH and FT subcatchments were affected by the average and compensation effects. The use of real change can increase the detectability of hydrological elements changes caused by land use change in SH and FT. The results of this study provide new insights regarding the examination of the effects of land use changes on hydrological regimes. These results are useful for land use planners and water resource managers.
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