The continuous integration of renewable energy into the grid has reduced its inertia and damping levels. When disturbances occur, the grid is prone to frequency excursion issues, which restrict the further utilization of renewable energy. Consequently, an increasing number of grid codes require active participation of renewable energy sources in the system’s frequency regulation (FR). Direct-drive permanent magnet synchronous wind power systems, characterized by their simple structure and high reliability, have gradually become the mainstream in wind power systems. By controlling the pitch angle to reserve surplus power, the wind turbines can actively engage in frequency regulation during disturbances. However, due to limited power reserve capacity, traditional FR methods struggle with parameters tuning, thus failing to achieve the desired effect. To this end, this paper proposes an FR strategy for direct-drive permanent magnet synchronous wind power systems based on the principle of rapid power compensation (RPC). It circumvents the challenges associated with parameter tuning, and achieves optimal FR performance for wind turbine inverter under power-limited conditions. Firstly, it is demonstrated that the proposed RPC control, when making full use of power reserves, can achieve FR effects equivalent to optimal PD control through rigorous mathematical analysis. Subsequently, the RPC control is divided into four operating modes to address FR requirements under different conditions. The transitions between these modes are explained, and the detailed implementation of the RPC control is provided. Finally, the effectiveness and superiority of the proposed control strategy are validated through simulation based on Matlab/Simulink.
Ether solvents are suitable for formulating solid-electrolyte interphase (SEI)-less ion-solvent cointercalation electrolytes in graphite for Na-ion and K-ion batteries. However, ether-based electrolytes have been historically perceived to cause exfoliation of graphite and cell failure in Li-ion batteries. In this study, we develop strategies to achieve reversible Li-solvent cointercalation in graphite through combining appropriate Li salts and ether solvents. Specifically, we design 1M LiBF4 1,2-dimethoxyethane (G1), which enables natural graphite to deliver ~91% initial Coulombic efficiency and >88% capacity retention after 400 cycles. We captured the spatial distribution of LiF at various length scales and quantified its heterogeneity. The electrolyte shows self-terminated reactivity on graphite edge planes and results in a grainy, fluorinated pseudo-SEI. The molecular origin of the pseudo-SEI is elucidated by ab initio molecular dynamics (AIMD) simulations. The operando synchrotron analyses further demonstrate the reversible and monotonous phase transformation of cointercalated graphite. Our findings demonstrate the feasibility of Li cointercalation chemistry in graphite for extreme-condition batteries. The work also paves the foundation for understanding and modulating the interphase generated by ether electrolytes in a broad range of electrodes and batteries.
The direction and environment of photovoltaics (PVs) may influence their energy output. The practical PV performance under various conditions should be estimated, particularly during initial design stages when PV model types are unknown. Previous studies have focused on a limited number of PV projects, which required the details of many PV models; furthermore, the models can be case sensitive. According to the 18 projects conducted in 7 locations (latitude 29.5–51.25N) around the world, we developed polynomials for the crystalline silicon PV energy output for different accessible input variables. A regression tree effectively evaluated the correlations of the outcomes with the input variables; those of high importance were identified. The coefficient of determination, indicating the percentage of datasets being predictable by the input, was higher than 0.65 for 14 of the 18 projects when the polynomial was developed using the accessible variables such as global horizontal solar radiation. However, individual equations should be derived for horizontal cases, indicating that a universal polynomial for crystalline silicon PVs with a tilt angle in the range 0°–66° can be difficult to develop. The proposed model will contribute to evaluating the performance of PVs with low and medium tilt angles for places of similar climates.
As a promising alternative to the market-leading lithium-ion batteries, low-cost sodium-ion batteries (SIBs) are attractive for applications such as large-scale electrical energy storage systems. The energy density, cycling life, and rate performance of SIBs are fundamentally dependent on dynamic physiochemical reactions, structural change, and morphological evolution. Therefore, it is essential to holistically understand SIBs reaction processes, degradation mechanisms, and thermal/mechanical behaviors in complex working environments. The recent developments of advanced in situ and operando characterization enable the establishment of the structure–processing–property–performance relationship in SIBs under operating conditions. This Review summarizes significant recent progress in SIBs exploiting in situ and operando techniques based on X-ray and electron analyses at different time and length scales. Through the combination of spectroscopy, imaging, and diffraction, local and global changes in SIBs can be elucidated for improving materials design. The fundamental principles and state-of-the-art capabilities of different techniques are presented, followed by elaborative discussions of major challenges and perspectives.
Hot and humid areas experience constant high temperatures and high humidity during summer, causing widespread concern about outdoor thermal discomfort. This paper investigates the effects of landscape design strategies on outdoor thermal environments during typical summer and winter weather conditions in the hot–humid areas of China. The physiological equivalent temperature (PET) is used for evaluating the thermal performance of the proposed outdoor environments. ENVI-met software was validated via field measurements for this study and was used to evaluate the outdoor thermal environment under typical summer and winter weather conditions. Three kinds of common landscape elements were analyzed: tree species, pavement, and water bodies. The results show that (1) by properly arranging landscape elements, the PET can be reduced by up to 1.6 °C in summer without sacrificing relevant thermal comfort during winter. (2) Arbors with high leaf area density (LAD) values performed better than those with a low LAD value for improved outdoor thermal comfort. (3) The influence of pavement on outdoor thermal comfort differs when under conditions with and without shade. This study provides practical suggestions for landscape design in open spaces within hot–humid areas.
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