Abstract Inductively coupled plasma analytical techniques are widely used in forensic geochemistry because they can provide concentration data for a wide range of major and trace elements relatively rapidly and at reasonable cost. A pilot study was undertaken to identify the relative importance of uncertainty resulting from instrumental measurement sources and that due to the procedures used to prepare the samples initially. Three soils with a range of major and trace element concentrations were collected to permit an evaluation of uncertainty. A reference sample of demonstrated homogeneity was also prepared and analysed. Samples were prepared in replicate (five preparations) of each, and assessment made of uncertainty in the instrumental measurement alone and for replicated preparations of the same material. Small sample sizes (0.05g) were used to mimic the situation common in forensic investigation. Results show that, while instrumental variability may be an important factor during measurement, between-sample variation has a dominant effect on uncertainty in the final result. It is clear that, without replicated measurement and preparation, the uncertainty of the measured data is unknown. Thus, critical samples, on which a case might depend, must be analysed in a way that defines clearly that uncertainty.
The Glen Doll and Juan Jorge Complexes are two contrasting late Caledonian calc-alkaline plutons intruded into Middle Dalradian metasediments at the northern end of Glen Clova, in the Angus district of Tayside, Scotland. The Glen Doll Complex (12 km squared) constitutes a wide range of rock types from olivine gabbro, through diorite to adamellite. The bulk (> 80%) of the succession consists of heterogeneous hornblende- and pyroxene-bearing diorites. Partially assimilated rafted metasedimentary xenoliths, are common in the intermediate rock types. The basic rocks are cumulates which display wall-parallel layering. Mineralogical variation displays a transition from pyroxene-dominated anhydrous assemblages to amphibole-dominated assemblages. The diorites by contrast display floor-parallel layering and typically contain cumulate magnetite and ilmenite. Petrographic and mineralogical data suggests that fractionation played an important role in the evolution of the cumulate rocks.