Recent Ar–Ar and U–Pb zircon geochronology from across the British and Irish Caledonides has revealed a prolonged period of arc-ophiolite formation ( c . 514–464 Ma) and accretion ( c . 490–470 Ma) to the Laurentian margin during the Grampian orogeny. The Slieve Gallion Inlier of Northern Ireland, an isolated occurrence of the Tyrone Volcanic Group, records the development of a peri-Laurentian island arc–backarc and its obduction to an outboard microcontinental block. Although a previous biostratigraphic age constraint provides a firm correlation of at least part of the volcanic succession to the Ca1 Stage of the Arenig ( c . 475–474 Ma), there is uncertainty on its exact statigraphic position in the Tyrone Volcanic Group. Earliest magmatism is characterized by light rare earth element (LREE) depleted island-arc tholeiite. Overlying deposits are dominated by large ion lithophile and LREE-enriched, hornblende-phyric and feldspathic calc-alkaline basaltic andesites and andesitic tuffs with strongly negative ϵNd t values. Previously published biostratigraphic age constraints, combined with recent U–Pb zircon geochronology and new petrochemical correlations, suggest that the Slieve Gallion Inlier is equivalent to the lower Tyrone Volcanic Group. Temporal and geochemical correlations between the Slieve Gallion Inlier and Charlestown Group of Ireland suggest that they may be part of the same arc system, which was accreted at a late stage ( c . 470 Ma) in the Grampian orogeny. A switch from tholeiitic volcanism to calc-alkaline dominated activity within the Lough Nafooey Group of western Ireland occurred prior to c . 490 Ma, some 15–20 Myr earlier than at Tyrone and Charlestown. Supplementary materials: Sampling and geochemical results (major elements, loss on ignition, trace elements, REE and Nd isotopes) are available at www.geolsoc.org.uk/SUP18640 .
Abstract A statistical analysis of reserves in fold and thrust belts, grouped by their geological attributes, indicates which of the world's fold and thrust belts are the most prolific hydrocarbon provinces. The Zagros Fold Belt contains 490f reserves in fold and thrust belts and has been isolated during the analysis to avoid bias. Excluding the Zagros Fold Belt, most of the reserves are in thin-skinned fold and thrust belts that have no salt detachment or salt seal, are partially buried by syn- or post-orogenic sediments, are sourced by Cretaceous source rocks and underwent their last phase of deformation during the Tertiary. A significant observation is that the six most richly endowed fold and thrust belts have no common set of geological attributes, implying that these fold belts all have different structural characteristics. The implication is that deformation style is a not critical factor for the hydrocarbon endowment of fold and thrust belts; other elements of the petroleum system must be more significant. Other fold and thrust belts may share the structural attributes but the resource-rich fold belts overwhelmingly dominate the total reserves in that group of fold belts. There is nothing intrinsic in fold and thrust belts that differentiates them from other oil- and gas-rich provinces other than the prolific development of potential hydrocarbon traps. Many of the prolific, proven fold and thrust belts still have significant remaining exploration potential as a result of politically challenging access and remote locations.
An intrusion of trachy-andesite, representative of a newly discovered suite of high-K–Ba–Sr, calc-alkaline minor intrusions (termed herein the Sperrin Mountains suite), hosted within the Grampian terrane in the north of Ireland, has been dated by U–Pb zircon at 426.69 ± 0.85 Ma (mid-Silurian; Wenlock–Ludlow boundary). Geochemistry reveals a close association with the Fanad, Ardara and Thorr plutons of the Donegal Batholith and the Argyll and Northern Highlands Suite of Scotland. The deep-seated Omagh Lineament appears to have limited eastward propagation of the Sperrin Mountains suite from beneath the main centre of granitic magmatism in Donegal. A Hf depleted mantle model age (TDMHf) of c. 800 Ma for trachy-andesite zircons indicates partial melting from a source previously separated from the mantle. Whole-rock geochemistry of the suite is consistent with a model of partial melting, triggered by slab break-off, following thrusting of Ganderia–Avalonia under the Southern Uplands–Down–Longford accretionary prism (i.e. Laurentian margin). The new age constrains the timing of this event in the north of Ireland and is consistent with the petrogenesis of Late Caledonian high-K granites, appinites and minor intrusions across the Caledonides of northern Britain and Ireland.
Abstract: Neoproterozoic basaltic magmatism in the Dalradian Supergroup of Scotland and Ireland was associated with the break-up of the Rodinia supercontinent. Magmas were erupted in rift-related basins along a strike length of at least 700 km and during a time period of c . 80 Ma. New major and trace element analyses of metabasalts from several formations are presented to trace the variations in magma compositions in time and space. The primary magmas resulted from variable degrees of mixing of melts derived from mantle sources similar to those of normal and enriched mid-ocean ridge basalts; some younger lavas also show evidence of contamination with continental crust. In contrast to speculations about magmatism elsewhere in Rodinia, the evidence here suggests that there was no involvement of a mantle plume in basalt generation. For example, the Scottish promontory of Laurentia drifted rapidly southwards through c . 25° over the duration of the magmatism, with no evidence of significant elevation above sea level, as might be expected from involvement of a plume. Generation of the primary magmas might have taken place predominantly through decompression melting in depleted upper mantle containing enriched streaks and blobs. Both the Dalradian lithostratigraphy and the metabasaltic compositions are consistent with extreme lithospheric stretching and possibly rupture during the earliest phase of magmatism, whereas generation of later magmatism appears to have been associated with major fault systems, possibly on a foundering continental margin. Supplementary material: Chemical analyses of Dalradian metavolcanic rocks (major elements recalculated to 100%, anhydrous) are available at www.geolsoc.org.uk/SUP18468 .
The Tellus high-resolution airborne magnetic and radiometric maps define previously unmapped zones within the Newry Igneous Complex, County Down.High-precision uranium-lead zircon dating of nine rock samples from different parts of the complex provides a robust set of age constraints (c.414-407 Ma), which confirm that the different plutons of the complex young towards the south-west.Combined, these new data allow an innovative model of intrusion to be developed, with intrusion beginning in the north-east and progressing towards the south-west.
Elevated arsenic concentrations (up to 19 μg L−1) occur in private groundwater wells in fractured bedrock aquifers close to the contact between Silurian greywackes of the Longford-Down Terrane, and the Palaeogene Slieve Gullion and Carlingford igneous complexes in NE Ireland. Palaeogene basaltic intrusions intersected in two drill cores were found to contain up to 80 mg kg−1 arsenic; concentrations that are elevated compared with the global averages for basalt. Fine grained (c. 5 μm) disseminated sulfarsenides, associated with cobalt and nickel were identified in the basalts as the primary sources of groundwater arsenic in this fractured bedrock aquifer system. Many of the high-As waters exhibit relatively high pH, arguing against a simple single-stage sulphide oxidation model for arsenic solubilisation. This observation coupled with the widespread presence of iron oxyhydroxide coatings on natural rock fractures intersected in the drill cores suggests a multi-stage As mobilisation process. This interpretation envisages sulfarsenide mineral oxidation, adsorption of dissolved As to iron oxyhydroxide mineral surfaces, and finally desorptive release of oxyanion As species from these surfaces as waters evolve to higher pH as a result of water-rock reactions.
'%3e%3cpath fill='%23012169' d='M0 0v30h60V0z'/%3e%3cpath stroke='%23fff' stroke-width='6' d='m0 0 60 30m0-30L0 30'/%3e%3cpath stroke='%23C8102E' stroke-width='4' d='m0 0 60 30m0-30L0 30' clip-path='url(%23b)'/%3e%3cpath stroke='%23fff' stroke-width='10' d='M30 0v30M0 15h60'/%3e%3cpath stroke='%23C8102E' stroke-width='6' d='M30 0v30M0 15h60'/%3e%3c/g%3e%3c/svg%3e)
'/%3e%3cpath d='M200 752.362h200v300H200z' style='fill:%23fff;fill-opacity:1;stroke:none' transform='translate(0 -752.362)'/%3e%3cpath d='M400 752.362h200v300H400z' style='fill:%23ff883e;fill-opacity:1;stroke:none' transform='translate(0 -752.362)'/%3e%3c/svg%3e)
'/%3e%3cuse xlink:href='%23a' transform='rotate(23.036 .093 25.536)'/%3e%3cuse xlink:href='%23a' transform='rotate(45.87 1.273 16.18)'/%3e%3cuse xlink:href='%23a' transform='rotate(69.945 .996 12.078)'/%3e%3cuse xlink:href='%23a' transform='rotate(20.66 -19.689 31.932)'/%3e%3c/svg%3e)