In this paper, the ageing behaviour of suspensions of laponite with varying salt concentration is investigated using rheological tools. It is observed that ageing is accompanied by an increase in the complex viscosity. The creep experiments performed at various ages show damped oscillations in the strain. The characteristic time scale of the damped oscillations, the retardation time, shows a prominent decrease with increasing age of the system. However, this dependence weakens with an increase in the salt concentration, which is known to change the microstructure of the system from glass like to gel like. We postulate that a decrease in the retardation time can be represented as a decrease in the viscosity (friction) of the dissipative environment surrounding the arrested entities that oppose elastic deformation of the system. We believe that ageing in colloidal glass leads to a greater ordering that enhances relative spacing between the constituents, thereby reducing the frictional resistance. However, since a gel state is inherently different in structure (fractal network) to that of a glass state (disordered), ageing in the gel does not induce ordering. Consequently, we observe an inverse dependence of retardation time on age, which becomes weaker with an increase in the salt concentration. We analyse these results from the perspective of ageing dynamics of both glass and gel states of laponite suspensions.
Soft, disordered, micro-structured materials are ubiquitous in nature and industry, and are different from ordinary fluids or solids, with unusual, interesting static and flow properties. The transition from fluid to solid -at the so-called jamming density- features a multitude of complex mechanisms, but there is no unified theoretical framework that explains them all. In this study, a simple yet quantitative and predictive model is presented, which allows for a variable, changing jamming density, encompassing the memory of the deformation history and explaining a multitude of phenomena at and around jamming. The jamming density, now introduced as a new state-variable, changes due to the deformation history and relates the system's macroscopic response to its microstructure. The packing efficiency can increase logarithmically slow under gentle repeated (isotropic) compression, leading to an increase of the jamming density. In contrast, shear deformations cause anisotropy, changing the packing efficiency exponentially fast with either dilatancy or compactancy. The memory of the system near jamming can be explained by a microstatistical model that involves a multiscale, fractal energy landscape and links the microscopic particle picture to the macroscopic continuum description, providing a unified explanation for the qualitatively different flow-behavior for different deformation modes. To complement our work, a recipe to extract the history-dependent jamming density from experimentally accessible data is proposed, and alternative state-variables are compared. The proposed simple macroscopic constitutive model is calibrated with the memory of microstructure. Such approach can help understanding predicting and mitigating failure of structures or geophysical hazards, and will bring forward industrial process design/optimization, and help solving scientific challenges in fundamental research.
In this study, we estimated the depth of Moho and velocity structure beneath fourteen three-component stations located in Garhwal Himalayas using receiver function followed by its inversion using non-linear direct search Neighbourhood Algorithm (NA). These 14 stations are oriented along SE-NE trend having a southernmost station located at Main Frontal Thrust (MFT) and northernmost station located at South Tibetan Detachment (STD) spanning 79 to 80° E. Teleseismic earthquakes recorded during 2011 and 2012 have been used for conducting this study. The inverted shear wave velocity models show crustal thickness
variation from 36 to 44 km for Lower Himalayas and 46 to 52 km for Upper Himalayas. As a
result, a slight dip is observed towards NE direction for the moho based upon preceding result. The aforementioned argument is further concretized by the fact for some stations we are getting different Ps arrival timing with varying backazimuth which in turn tells us about varying depth of moho observed from a different direction, which can only happen if there is anisotropy or if there is dipping structure or can be both of the above. The average crustal shear velocity in this region varies from 3.33 to 3.36 km/s. The average Vp/Vs ratio varies in this region from 1.7 to 1.8.