Slags coming from stainless steel (SS) and ferrochromium (FeCr) production generally contain between 1 and 10% Cr, mostly present in entrapped metallic particles (Fe–Cr alloys) and in spinel structures. To recover Cr from these slags, magnetic and gravity separation techniques were tested for up-concentrating Cr in a fraction for further processing. In case of SS slag and low carbon (LC) FeCr slag a wet high intensity magnetic separation can up-concentrate Cr in the SS slag (fraction <150 µm) from 2.3 wt.% to almost 9 wt.% with a yield of 7 wt.%, and in the LC FeCr slag from 3.1 wt.% to 11 wt.% with a yield of 3 wt.%. Different behavior of Cr-containing spinel’s in the two slag types observed during magnetic separation can be explained by the presence or absence of Fe in the lattice of the Cr-containing spinel’s, which affects their magnetic susceptibility. The Cr content of the concentrates is low compared to chromium ores, indicating that additional processing steps are necessary for a recovery process. In the case of high carbon (HC) FeCr slag, a Cr up-concentration by a factor of more than three (from 9 wt.% to 28 wt.%) can be achieved on the as received slag, after a single dry low intensity magnetic separation step, due to the well-liberated Cr-rich compounds present in this slag. After gravity separation of the HC FeCr slag, a fraction with a Cr content close to high grade Cr ores (≥50% Cr2O3) can be obtained. This fraction represents 12 wt.% of the HC FeCr slag, and can probably be used directly in traditional smelting processes.
ABSTRACT South of the Caledonian Brabant‐Wales Massif a more than 200 m thick Tournaisian to Lower Visean replacive dolomite unit can be followed for several hundred kilometres from the Boulonnais (France) to Aachen (Germany). Field observations, of features such as karst cavities occurring at the top of the Lower Visean dolomite which are filled by Lower Visean crinoidal limestone, indicate that dolomitization and karstification took place during the Early Visean. This early development of the dolomite is in agreement with the presence of stylolites cutting the dolomite fabric. The minor element composition of the majority of the dolomites remains almost uniform throughout the entire studied area. Values for Fe, Mn, Na and Sr are normally in the range 700–4700 ppm, 15–400 ppm, 80–300 ppm and 50–200 ppm, respectively. The δ 13 C values (range‐0.72 to +5.31% o ) mainly reflect the carbon isotopic composition of the precursor limestones. The δ 18 O values, in contrast, are highly variable: ranging from‐19.15 to +0.85% o . This rather large range of δ 18 O values is explained by multiple‐step re‐equilibration/recrystallization during progressive burial and subsequent uplift of the dolomites. These processes are also responsible for the high 87 Sr/ 86 Sr values of the dolomites which range from about 0.7088 to 0.7098. They are distinctly more radiogenic than Lower Visean marine carbonates (0.7076–0.7078). Correlation, however, of δ 18 O values or 87 Sr/ 86 Sr ratios with dolomite and/or cathodoluminescenec (CL) textures has not been very successful. This suggests that recrystallization may remain unrecognized if only petrographic techniques are used. Nevertheless, certain CL textures can be related to specific interactions with the ambient recrystallizing fluids.
