Rare Earth Elements (REE) consumption in the US was 20,000 metric ton in 2018. China controls 97% of the global REE market. The aims for new technology are to 1. Avoid investing in extraction of cheap LREE, extract M/HREE only → increase the value of the intermediate/final product, 2. Exclude extraction and concentration of U and Th → avoid investment in rad remediation, and 3. Maximize environmental friendliness of the technology. Hints from nature can aid in achieving these amis.
The Swakane Gneiss, interpreted to represent sedimentary strata metamorphosed at 8–12 kbar, is the deepest exposed crustal levels within the exhumed North Cascades continental magmatic arc, yet the nature and age of its protolith and the mechanism by which it was transported to deep-crustal levels remains unclear. Zircons from 11 paragneiss and schist samples were analyzed for U-Pb age and Hf-isotope composition in order to investigate the tectonic history of the Swakane Gneiss from protolith deposition to metamorphism within the North Cascades arc. Zircons interpreted to have crystallized in situ during metamorphism and/or melt-crystallization within the Swakane Gneiss at depth have ca. 74–66 Ma ages. Detrital-zircon age and Hf-isotope characteristics demonstrate provenance shifts that correlate with maximum depositional ages of ca. 93–81 Ma. Samples deposited between ca. 93 and 88 Ma have dominantly Mesozoic age peaks with initial εHf values between depleted mantle and chondritic uniform reservoir (CHUR), whereas ca. 86–81 Ma sample show the addition of distinct Proterozoic populations (ca. 1380 and 1800–1600 Ma) and Late Cretaceous zircons with unradiogenic Hf-isotope compositions. Similar detrital-zircon age and Hf-isotope patterns are observed in several Upper Cretaceous forearc and accretionary wedge units between southern California and Alaska along the North American continental margin. The connection between the Swakane Gneiss and these potential protoliths located outboard of Cordilleran arc systems indicate burial by either underplating of accretionary-wedge sediments or underthrusting of forearc sediments. Therefore, the protolith and incorporation history for the Swakane Gneiss is likely similar to those of deep crustal metasedimentary units elsewhere in the North Cascades (i.e., the Skagit Gneiss Complex) and to the south along the continental margin (i.e., the Pelona-Orocopia-Rand schists and Schist of Sierra de Salinas). These observations suggest that burial of sediment outboard of continental magmatic arc systems may be a major mechanism for the transfer of sediment to the deep levels of continental arcs.
The U-Pb age and Hf-isotope composition of detrital zircons from Jurassic to Upper Cretaceous sedimentary rocks adjacent to the southern North Cascades–Coast Plutonic Complex continental magmatic arc document shifting provenance, the tectonic evolution of the arc system, and translation along the continental margin. Systematic changes in the detrital-zircon data provide insight that the western margin of North America evolved from: marginal basins adjacent to continent-fringing oceanic arcs (ca. 160–140 Ma); forearc basins adjacent to mid-Cretaceous (ca. 120–90 Ma) Andean-type continental arcs; and addition of a cratonic source to forearc and accretionary wedge units to Cordilleran arc systems in the mid-Late Cretaceous (ca. 85 Ma). Jurassic Methow terrane, Nooksack Formation, and western mélange belt units dominantly contain detrital zircons derived from accreted oceanic terranes, whereas Lower Cretaceous strata from the same units have age peaks that correspond to known pulses of magmatism in Cordilleran continental magmatic arc systems. The age peaks and Hf-isotope signature of the Jurassic and Lower Cretaceous strata are comparable to multiple sources exposed along the margin. In contrast, the Upper Cretaceous western mélange belt has distinct Precambrian zircon populations and unradiogenic Late Cretaceous zircons that are more similar to southwestern than northwestern Laurentian sources. Statistical comparisons confirm provenance similarities between rocks of the North Cascades and those 700–2000 km to the south and, thus, support margin-parallel translation from as far as the latitude of southern California.