Magma degassing and fragmentation control hazardous tephra production in glaciovolcanic eruptions, and strongly influence the generation of meltwater. Characterisation of volatile species in eruptive products allows reconstruction of degassing systematics, and magmatic textures provide insight into fragmentation mechanisms and interactions with external water. In this session we will describe the methods used to quantify volatile species concentrations and magmatic textures, and use Icelandic case studies to examine how results can be used to constrain eruptive controls, quenching pressures, and interactions with meltwater.
Abstract: The volatile concentrations and thermal characteristics of hydrothermally altered rhyolitic deposits erupted under Icelandic glaciers have been studied by combined differential scanning calorimetry–thermogravimetric analysis–mass spectrometry (DSC–TGA–MS) and X-ray diffraction (XRD). Samples range from pristine obsidians to strongly perlitized and altered fragmental deposits. Four types of samples are determined to have notable differences in total volatile concentrations: obsidians (0.44–3.04 wt%), perlites (2.15–8.15 wt%), obsidian-breccias (8.49–9.41 wt%) and hyaloclastites (3.23–7.78 wt%). DSC–TGA–MS and textural data indicate that the volatile concentration of the perlitic samples increases as the amount of perlitization increases. XRD data show that the volatile-rich samples are rich in the low-temperature zeolite minerals heulandite and mordenite. The temperature at which volatile exsolution occurs is shown to decrease as the volatile concentration increases, reflecting the speciation of water as well as zeolite mineral growth. Supplementary material: Detailed grain-size fraction analysis data in table and histogram form are available at http://www.geolsoc.org.uk/SUP18366 .
Abstract Silicic volcanic eruptions commonly begin with the explosive ejection of pyroclastic material, before transitioning to gentler effusion-dominated activity. Well-exposed dissected silicic systems are scarce and poorly studied, hindering the advances in our understanding of the explosive–effusive transition needed to improve interpretations of volcanic unrest and hazard forecasting. The Mule Creek vent (New Mexico, USA) is a dissected silicic conduit that records the processes controlling conduit formation and evolution, and the role tuffisites (fractures filled with variably welded pyroclasts) play in conduit dynamics. Here, we use decimeter-scale photo-mapping of lithostratigraphic units and thin section analysis to differentiate and interpret three dominant emplacement styles during vent evolution. First, there was repeated deposition and erosion of pyroclastic material at the conduit walls, recorded by erosive surfaces in pyroclastic breccia and agglomerates at the conduit margins. Second, sub-vertical domains of dense melt-dominated magma were emplaced and preserved as glass-dominated vitrophyre and brecciated vitrophyre, with the textural hallmarks of assembly from welding of pyroclasts. Finally, the sub-horizontal fracturing of previously deposited lithologies produced laterally cross-cutting tuffisites. The vent deposits track the widening and then narrowing of the conduit through time and reflect progressive insulation and generally higher temperatures towards the conduit center as pyroclasts accumulate. Welding of pyroclastic fill and the formation of dense vitrophyres towards the conduit center lowers deposit porosity and effective wall permeability. This drives localized gas pressure increases and results in gas-driven fracturing, generating tuffisites, which act as transient outgassing pathways. The structure of the Mule Creek vent records an explosive–effusive transition, constraining the processes controlling conduit evolution and aiding our interpretation of volcanic unrest.
Silicic volcanic activity has long been framed as either violently explosive or gently effusive. However, recent observations demonstrate that explosive and effusive behavior can occur simultaneously. Here, we propose that rhyolitic magma feeding subaerial eruptions generally fragments during ascent through the upper crust and that effusive eruptions result from conduit blockage and sintering of the pyroclastic products of deeper cryptic fragmentation. Our proposal is supported by (i) rhyolitic lavas are volatile depleted; (ii) textural evidence supports a pyroclastic origin for effusive products; (iii) numerical models show that small ash particles ≲10-5 m can diffusively degas, stick, and sinter to low porosity, in the time available between fragmentation and the surface; and (iv) inferred ascent rates from both explosive and apparently effusive eruptions can overlap. Our model reconciles previously paradoxical observations and offers a new framework in which to evaluate physical, numerical, and geochemical models of Earth's most violent volcanic eruptions.
Super-eruptions generating hundreds of cubic kilometres of pyroclastic density currents are commonly recorded by thick, welded and lava-like ignimbrites. Despite the huge environmental impact inferred for this type of eruption, little is yet known about the timescales of deposition and post-depositional flow. Without these timescales, the critical question of the duration of any environmental impact, and the ensuing gravity of its effects for the Earth system, eludes us. The eruption and welding of ignimbrites requires three transects of the glass transition. Magma needs to: 1) fragment during ascent, 2) liquefy and relax during deposition, agglutination and welding (sintering), and 3) quench by cooling into the glassy state. Here we show that welding is a rapid, syn-depositional process and that the welded ignimbrite sheet may flow for up to a few hours before passing through the glass transition a final time. Geospeedometry reveals that the basal vitrophyre of the Grey's Landing ignimbrite underwent the glass transition at a rate of ~0.1 °C.min^-1 at 870 °C; that is, 30-180 °C below pre-eruptive geothermometric estimates. Application of a 1-D cooling model constrains the timescale of deposition, agglutination, and welding of the basal vitrophyre to less than 1 hour, and possibly even tens of minutes. Thermo-mechanical iteration of the sintering process indicates an optimal temperature solution for the emplacement of the vitrophyres at 966 °C. The vitrophyres reveal a Newtonian rheology up to 46 MPa, which suggests that the ash particles annealed entirely during welding and that viscous energy dissipation is unlikely from loading conditions alone, unless shear stresses imposed by the overlying ash flow were excessively high and sustained over long distances. The findings underline the value of the term 'lava-like' flow to describe the end rheology of Snake River-type ignimbrites, fully consistent with the typical lithofacies observed.
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