The demand for large format lithium-ion batteries is increasing, because they can be integrated and controlled easier at a system level. However, increasing the size leads to increased heat generation risking overheating. 1865 and 2170 cylindrical cells can be both base cooled or side cooled with reasonable efficiency. Large format 4680 cylindrical cells have become popular after Tesla filed a patent. If these cells are to become widely used, then understanding how to thermally manage them is essential. In this work, we create a model of a 4680 cylindrical cell, and use it to study different thermal management options. Our work elucidates the comprehensive mechanisms how the hot topic 'tabless design' improves the performance of 4680 cell and makes any larger format cell possible while current commercial cylindrical cells cannot be simply scaled up to satisfy power and thermal performance. As a consequence, the model identifies the reason for the tabless cell's release: the thermal performance of the 4680 tabless cell can be no worse than that of the 2170 cell, while the 4680 tabless tab cell boasts 5.4 times the energy and 6.9 times the power. Finally, via the model, a procedure is proposed for choosing the thermal management for large format cylindrical cell for maximum performance. As an example, we demonstrate that the best cooling approach for the 4680 tabless cell is base cooling, while for the 2170 LG M50T cell it is side cooling. We conclude that any viable large format cylindrical cell must include a continuous tab (or 'tabless') design and be cooled through its base when in a pack. The results are of immediate interest to both cell manufacturers and battery pack designers, while the developed modelling and parameterization framework is of wider use for all energy storage system design.
This paper presents a novel policy assessment approach for sustainable transitions using insights from the multilevel perspective (MLP). An analysis of current German and UK policies for sustainable transport is conducted to illustrate its application. For both cases a potential transition pathway, that can satisfy environmental protection and industrial competitiveness goals, is derived from archetypal transition pathways. These are then put in relation to current policies, discussing whether these measures support these pathways. In the UK case, where emission reduction goals and industrial development are pursued together, current policies of promoting the diffusion of electric vehicles as well as industrial niches are supporting the emergence of a reconfiguration pathway. Replacing foreign suppliers, the local automotive industry shall become a significant part of the future regime. In contrast to that, Germany focuses on a careful transformation and conservation of its automotive industry where none of the current actors is left behind.
Lithium sulfur batteries, review of current mechanistic understanding and the gap between experimentally derived mechanisms and those used for modelling.
Traditional equivalent circuit models (ECMs) have difficulties in estimating battery internal states due to the lack of relevant physics, such as the lithium diffusion in active particles. Here we configure a circuit network to describe the lithium diffusion and define it as a new high-level circuit element called diffusion-aware voltage source. The circuit representation is proven equivalent to the discretized diffusion equation. The new voltage source gives the electrode potential as a function of the surface concentration and thus automatically incorporates the diffusion overpotential. We show that an ECM with the proposed diffusion-aware voltage sources (called "shell ECM") can reproduce the single particle model simulation results, making it a trustworthy easy-to-implement substitute. Furthermore, the simplest shell ECM consisting of a single diffusion-aware voltage source and a resistor is validated against experimental constant-current discharges at various rates. The diffusion-aware voltage source can be used to measure diffusivity by fitting the diffusion resistance against experimental data. The viability of the shell ECM for onboard usage is confirmed by implementation into a battery management system of WAE Technologies. By tracking the internal concentration states, the shell ECM demonstrates robustness to dynamic applied-current profiles.
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