[1] High-resolution compositional data from Moon Mineralogy Mapper (M3) for the Moscoviense region on the lunar farside reveal three unusual, but distinctive, rock types along the inner basin ring. These are designated "OOS" since they are dominated by high concentrations of orthopyroxene, olivine, and Mg-rich spinel, respectively. The OOS occur as small areas, each a few kilometers in size, that are widely separated within the highly feldspathic setting of the basin rim. Although the abundance of plagioclase is not well constrained within the OOS, the mafic mineral content is exceptionally high, and two of the rock types could approach pyroxenite and harzburgite in composition. The third is a new rock type identified on the Moon that is dominated by Mg-rich spinel with no other mafic minerals detectable (<5% pyroxene, olivine). All OOS surfaces are old and undisturbed since basin formation. They are effectively invisible in image data and are only recognized by their distinctive composition identified spectroscopically. The origin of these unusual lithologies appears to be linked to one or more magmatic intrusions into the lower crust, perhaps near the crust-mantle interface. Processes such as fractional crystallization and gravity settling within such intrusions may provide a mechanism for concentrating the mafic components within zones several kilometers in dimension. The OOS are embedded within highly anorthositic material from the lunar crust; they may thus be near contemporaneous with crustal products from the cooling magma ocean.
[1] Changes in observed photometric intensity on a planetary surface are caused by variations in local viewing geometry defined by the radiance incidence, emission, and solar phase angle coupled with a wavelength-dependent surface phase function f(α, λ) which is specific for a given terrain. In this paper we provide preliminary empirical models, based on data acquired inflight, which enable the correction of Moon Mineralogy Mapper (M3) spectral images to a standard geometry with the effects of viewing geometry removed. Over the solar phase angle range for which the M3 data were acquired our models are accurate to a few percent, particularly where thermal emission is not significant. Our models are expected to improve as additional refinements to the calibrations occur, including improvements to the flatfield calibration; improved scattered and stray light corrections; improved thermal model corrections; and the computation of more accurate local incident and emission angles based on surface topography.
[1] Using the Moon Mineralogy Mapper(M3), we examine the Marius Hills volcanic complex for the first time from 0.46 to 2.97 μm. The integrated band depth at 1 μm separates the mare basalts on the plateau in two units: (1) a strong 1 μm band unit of localized lava flows within the plateau that has similar olivine-rich signatures to those of the nearby Oceanus Procellarum and (2) a weaker 1 μm band unit that characterizes most of the basalts of the plateau, which is interpreted as having a high-calcium pyroxene signature. Domes and cones within the complex belong to the high-calcium pyroxene plateau unit and are associated with the weakest 1 μm band observed on the plateau. This difference could be the result of higher silica content, more opaque minerals, and/or a weaker olivine content of the magma. Finally, the floor of Marius crater has one of the strongest olivine-rich signatures of the entire Marius Hills complex. These compositional differences are indicative of the long and complex volcanic history of the region. The first episode started before the emplacement of the surrounding basalts of the plateau and produced the high-calcium pyroxene flows present on the plateau and their associated domes and cones. The second episode occurred concurrently or slightly after the emplacement of the adjacent Procellarum basalts and produced the olivine-rich basalts seen within the plateau, outside the plateau, and in Marius crater. If the olivine content of the lava flows increases with time, the olivine-rich region on the floor of Marius crater may represent one of the latest episodes of volcanism exposed on the Marius Hills complex.
[1] The Mars Exploration Rover (MER) Spirit excavated sulfur-rich soils exhibiting high albedo and relatively white to yellow colors at three main locations on and south of Husband Hill in Gusev crater, Mars. The multispectral visible/near-infrared properties of these disturbed soils revealed by the Pancam stereo color camera vary appreciably over small spatial scales, but exhibit spectral features suggestive of ferric sulfates. Spectral mixture models constrain the mineralogy of these soils to include ferric sulfates in various states of hydration, such as ferricopiapite [Fe2/32+Fe43+(SO4)6(OH)2·20(H2O)], hydronium jarosite [(H3O)Fe3+3(SO4)2(OH)6], fibroferrite [Fe3+(SO4)(OH)·5(H2O)], rhomboclase [HFe3+(SO4)2·4(H2O)], and paracoquimbite [Fe3+2(SO4)3·9(H2O)].
[1] The USGS's Robotic Lunar Observatory (ROLO) dedicated ground-based lunar calibration project obtained photometric observations of the Moon over the spectral range attainable from Earth (0.347–2.39 μm) and over solar phase angles of 1.55°–97°. From these observations, we derived empirical lunar surface solar phase functions for both the highlands and maria that can be used for a wide range of applications. The functions can be used to correct for the effects of viewing geometry to produce lunar mosaics, spectra, and quick-look products for future lunar missions and ground-based observations. Our methodology can be used for a wide range of objects for which multiply scattered radiation is not significant, including all but the very brightest asteroids and moons.
New measurements of thermal infrared emission spectra (250.1400 cm-1; ~7.40 μm) of experimentally shocked basalt and basaltic andesite (17.56 GPa) exhibit changes in spectral features with increasing pressure consistent with changes in the structure of plagioclase feldspars. Major spectral absorptions in unshocked rocks between 350.700 cm-1 (due to Si-O-Si octahedral bending vibrations) and between 1000.1250 cm-1 (due to Si-O antisymmetric stretch motions of the silica tetrahedra) transform at pressures >20.25 GPa to two broad spectral features centered near 950.1050 and 400.450 cm-1. Linear deconvolution models using spectral libraries composed of common mineral and glass spectra replicate the spectra of shocked basalt relatively well up to shock pressures of 20.25 GPa, above which model errors increase substantially, coincident with the onset of diaplectic glass formation in plagioclase. Inclusion of shocked feldspar spectra in the libraries improves fits for more highly shocked basalt. However, deconvolution models of the basaltic andesite select shocked feldspar end-members even for unshocked samples, likely caused by the higher primary glass content in the basaltic andesite sample.
[1] The NASA Discovery Moon Mineralogy Mapper imaging spectrometer was selected to pursue a wide range of science objectives requiring measurement of composition at fine spatial scales over the full lunar surface. To pursue these objectives, a broad spectral range imaging spectrometer with high uniformity and high signal-to-noise ratio capable of measuring compositionally diagnostic spectral absorption features from a wide variety of known and possible lunar materials was required. For this purpose the Moon Mineralogy Mapper imaging spectrometer was designed and developed that measures the spectral range from 430 to 3000 nm with 10 nm spectral sampling through a 24 degree field of view with 0.7 milliradian spatial sampling. The instrument has a signal-to-noise ratio of greater than 400 for the specified equatorial reference radiance and greater than 100 for the polar reference radiance. The spectral cross-track uniformity is >90% and spectral instantaneous field-of-view uniformity is >90%. The Moon Mineralogy Mapper was launched on Chandrayaan-1 on the 22nd of October. On the 18th of November 2008 the Moon Mineralogy Mapper was turned on and collected a first light data set within 24 h. During this early checkout period and throughout the mission the spacecraft thermal environment and orbital parameters varied more than expected and placed operational and data quality constraints on the measurements. On the 29th of August 2009, spacecraft communication was lost. Over the course of the flight mission 1542 downlinked data sets were acquired that provide coverage of more than 95% of the lunar surface. An end-to-end science data calibration system was developed and all measurements have been passed through this system and delivered to the Planetary Data System (PDS.NASA.GOV). An extensive effort has been undertaken by the science team to validate the Moon Mineralogy Mapper science measurements in the context of the mission objectives. A focused spectral, radiometric, spatial, and uniformity validation effort has been pursued with selected data sets including an Earth-view data set. With this effort an initial validation of the on-orbit performance of the imaging spectrometer has been achieved, including validation of the cross-track spectral uniformity and spectral instantaneous field of view uniformity. The Moon Mineralogy Mapper is the first imaging spectrometer to measure a data set of this kind at the Moon. These calibrated science measurements are being used to address the full set of science goals and objectives for this mission.