Abstract Global ice volume (sea level) and deep‐sea temperature are key measures of Earth's climatic state. We synthesize evidence for multi‐centennial to millennial ice‐volume and deep‐sea temperature variations over the past 40 million years, which encompass the early glaciation of Antarctica at ∼34 million years ago (Ma), the end of the Middle Miocene Climate Optimum, and the descent into bipolar glaciation from ∼3.4 Ma. We compare different sea‐level and deep‐water temperature reconstructions to build a resource for validating long‐term numerical model‐based approaches. We present: (a) a new template synthesis of ice‐volume and deep‐sea temperature variations for the past 5.3 million years; (b) an extended template for the interval between 5.3 and 40 Ma; and (c) a discussion of uncertainties and limitations. We highlight key issues associated with glacial state changes in the geological record from 40 Ma to present that require attention in further research. These include offsets between calibration‐sensitive versus thermodynamically guided deep‐sea paleothermometry proxy measurements; a conundrum related to the magnitudes of sea‐level and deep‐sea temperature change at the Eocene‐Oligocene transition at 34 Ma; a discrepancy in deep‐sea temperature levels during the Middle Miocene; and a hitherto unquantified non‐linear reduction of glacial deep‐sea temperatures through the past 3.4 million years toward a near‐freezing deep‐sea temperature asymptote, while sea level stepped down in a more uniform manner. Uncertainties in proxy‐based reconstructions hinder further distinction of “reality” among reconstructions. It seems more promising to further narrow this using three‐dimensional ice‐sheet models with realistic ice‐climate‐ocean‐topography‐lithosphere coupling, as computational capacities improve.
The Danakil depression marks a progressive change from continental rifting in Afar to seafloor spreading further north in the Red Sea. Extension and volcanism in this incipient spreading centre is localised to the ~70-km-long, 20-km-wide active Erta Ale volcanic segment. Here, we combine remote sensing and major element geochemical analysis to determine the structure and composition of three volcanoes on the Erta Ale Volcanic Segment: the Alu dome, the Dalafilla stratovolcano and the Borale stratovolcano. We investigate the evolution and compositional variation within and between these volcanic complexes. Our results show that most flows are sourced from scoria cones and fissures, representing in total 15 phases of volcanism that occurred within four major eruptive stages, most likely occurring in the last 80 thousand years (kyr). The first stage represents large-scale fissure volcanism, comprising submarine basaltic phases. Stage two involves basaltic fissure volcanism around Alu. The third stage is dominated by trachy-andesite to rhyolitic volcanism from the volcanic edifices of Alu, Dalafilla and Borale and the fourth by a resumption of small-scale basaltic/trachybasalt fissure systems. Geochemical modelling indicates a paucity of crustal assimilation and mixing within the sub-volcanic magmatic system. Spatial analysis of volcanic cones and fissures within the area indicate the presence of a cone sheet and ring faults. The fissures are likely fed by sills connecting the magma source with the volcanic edifices of Alu and Borale. Our results reveal the cyclic nature of both eruption style and composition of major volcanic complexes in rift environments, prior to the onset of seafloor spreading.
<p>The marked increase in seawater Mg/Ca during the Cenozoic is poorly understood, due to the limited availability of proxy data and uncertainty in elucidating the respective contributions of Mg sources and sinks through geological time<sup>1</sup>. Though established as a potentially large source of dissolved Mg over twenty years ago, the weathering of abyssal peridotites<sup>2</sup> is a largely unexplored potential source of Mg to oceanic budgets. The release of magnesium from peridotite weathering can occur in high temperature environments, during serpentinisation near the ridge axis<sup>3</sup>, as well as low temperature off-axis environments where peridotite and serpentinite are altered to clays, carbonates and silicates<sup>4</sup>. The relative magnitude of Mg fluxes from these sources are poorly constrained. Recent studies, however, now provide a general method for estimating bulk crustal lithologies of mid-ocean ridges based on spreading rate (i.e. proportion and mass of basalts, gabbros, peridotites and serpentinised peridotite) through time<sup>5</sup>&#8212;enabling us to quantitatively assess potential Mg contributions from these different environments.</p><p>We constructed a model for oceanic crustal weathering (proportional to depth below the seafloor) to develop estimates of the mass and isotopic composition of magnesium loss from peridotite during alteration in both high- and low-T environments. As Mg fractionation occurs predominantly in low-T reactions, the primary serpentinisation reaction in near-ridge environments is unlikely to result in isotopic differentiation. Comparably, the secondary low-T alterations, of both remaining peridotites (to clays and iron hydroxides) and serpentinite (e.g. to talc and dolomite) are likely to result in the fractionation of Mg. We extend our analysis to incorporate the fractionation of these systems<sup>4</sup> and their release of Mg into the ocean. We completed our analysis by presenting a compilation of fluid data for magnesium concentrations in ultramafic bodies from hydrothermal systems, in order to evaluate our model.</p><p><strong>References</strong></p><p>(1) Staudigel, H. "Chemical fluxes from hydrothermal alteration of the oceanic crust." (2014): 583-606.</p><p>(2) Snow, J.E. and Dick, H.J., 1995. Pervasive magnesium loss by marine weathering of peridotite. Geochimica et Cosmochimica Acta, 59(20), pp.4219-4235.</p><p>(3) Seyfried Jr, W.E., Pester, N.J., Ding, K. and Rough, M., 2011. Vent fluid chemistry of the Rainbow hydrothermal system (36 N, MAR): Phase equilibria and in situ pH controls on subseafloor alteration processes.&#160;Geochimica et Cosmochimica Acta,&#160;75(6), pp.1574-1593.</p><p>(4) Liu, P.P., Teng, F.Z., Dick, H.J., Zhou, M.F. and Chung, S.L., 2017. Magnesium isotopic composition of the oceanic mantle and oceanic Mg cycling.&#160;Geochimica et Cosmochimica Acta,&#160;206, pp.151-165.</p><p>(5) Merdith, A.S., Atkins, S.E. and Tetley, M.G., 2019. Tectonic controls on carbon and serpentinite storage in subducted upper oceanic lithosphere for the past 320 Ma.&#160;Frontiers in Earth Science,&#160;7, p.332.</p>
Abstract Hole U1395B, drilled southeast of Montserrat during Integrated Ocean Drilling Program Expedition 340, provides a long (>1 Ma) and detailed record of eruptive and mass‐wasting events (>130 discrete events). This record can be used to explore the temporal evolution in volcanic activity and landslides at an arc volcano. Analysis of tephra fall and volcaniclastic turbidite deposits in the drill cores reveals three heightened periods of volcanic activity on the island of Montserrat (∼930 to ∼900 ka, ∼810 to ∼760 ka, and ∼190 to ∼120 ka) that coincide with periods of increased volcano instability and mass‐wasting. The youngest of these periods marks the peak in activity at the Soufrière Hills volcano. The largest flank collapse of this volcano (∼130 ka) occurred toward the end of this period, and two younger landslides also occurred during a period of relatively elevated volcanism. These three landslides represent the only large (>0.3 km 3 ) flank collapses of the Soufrière Hills edifice, and their timing also coincides with periods of rapid sea level rise (>5 m/ka). Available age data from other island arc volcanoes suggest a general correlation between the timing of large landslides and periods of rapid sea level rise, but this is not observed for volcanoes in intraplate ocean settings. We thus infer that rapid sea level rise may modulate the timing of collapse at island arc volcanoes, but not in larger ocean‐island settings.
Global ice volume (sea level) and deep-sea temperature are key measures of Earth’s climatic state. We synthesize evidence for multi-centennial to millennial ice-volume and deep-sea temperature variations over the past 40 million years, which encompass the early glaciation of Antarctica at ~34 million years ago (Ma), the end of the Middle Miocene Climate Optimum, and the descent into the bipolar glaciation state from ~3.4 Ma. We compare different sea-level and deep-water temperature reconstructions that are grounded in data to build a resource for validation of long-term numerical model-based approaches. We present: (a) a new ice-volume and deep-sea temperature synthesis for the past 5.3 million years; (b) a single template reconstruction of ice-volume and deep-sea temperature for the interval between 5.3 and 40 Ma; and (c) a discussion of uncertainties and limitations. We highlight key issues associated with glacial state changes in the geological record from 40 Ma to the present that require specific attention in further research. These include offsets between calibration-sensitive versus more thermodynamically guided deep-sea paleothermometry proxy measurements; a conundrum related to the magnitudes of sea-level and deep-sea temperature change at the Eocene-Oligocene transition at 34 Ma; a discrepancy in deep-sea temperature levels during the Middle Miocene between proxy reconstructions and model-based deconvolutions of deep-sea oxygen isotope data; and a hitherto unquantified non-linear reduction of glacial deep-sea temperatures through the past 3.4 million years toward a near-freezing deep-sea temperature asymptote, while sea level stepped down in a more linear manner.
Hergarten et al . interpret our results in terms of erosion and uncertain calibration, rather than requiring an increase in impact flux. Geologic constraints indicate low long-term erosion rates on stable cratons where most craters with diameters of ≥20 kilometers occur. We statistically test their proposed recalibration of the lunar crater ages and find that it is disfavored relative to our original calibration.
Orbital forcing plays a key role in pacing the glacial-interglacial cycles. However, the mechanistic linkages between the orbital parameters - eccentricity, obliquity, and precession - and global ice volume remain unclear. Here, we investigate the effect of Earth's orbitally governed incoming solar radiation (that is, insolation) on global ice volume over the past 800,000 years. We consider a simple linear model of ice volume that imposes minimal assumptions about its dynamics. We find that this model can adequately reproduce the observed ice volume variations for most of the past 800,000 years, with the notable exception of Marine Isotope Stage 11. This suggests that, aside from a few extrema, the ice volume dynamics primarily result from an approximately linear response to orbital forcing. We substantiate this finding by addressing some of the key criticisms of the orbitally forced hypothesis. In particular, we show that eccentricity can significantly vary the ocean temperature without the need for amplification on Earth. We also present a feasible mechanism to explain the absence of eccentricity's 400,000 year period in the ice volume data. This requires part of the forcing from eccentricity to be lagged via a slow-responding mechanism, resulting in a signal that closer approximates the change in eccentricity. A physical interpretation of our model is proposed, using bulk ocean and surface temperatures as intermediate mechanisms through which the orbital parameters affect ice volume. These show reasonable alignment with their relevant proxy data, though we acknowledge that these variables likely represent a combination of mechanisms.
Carbon capture and storage (CCS) is a key technology to potentially mitigate global warming by reducing carbon dioxide (CO2) emissions from industrial facilities and power generation that escape into the atmosphere. To broaden the usage of geological storage as a viable climate mitigation option, it is vital to understand CO2 behaviour after its injection within a storage reservoir, including its potential migration through overlying sediments, as well as biogeochemical and ecological impacts in the event of leakage. The impacts of a CO2 release were investigated by a controlled release experiment that injected CO2 at a known flux into shallow, under-consolidated marine sediments for 37 days. Repeated high-resolution 2D seismic reflection surveying, both pre-release and syn-release, allows the detection of CO2-related anomalies, including: seismic chimneys; enhanced reflectors within the subsurface; and bubbles within the water column. In addition, reflection coefficient and seismic attenuation values calculated for each repeat survey, allow the impact of CO2 flux on sediment acoustic properties to be comparatively monitored throughout the gas release. CO2 migration is interpreted as being predominantly controlled by sediment stratigraphy in the early stages of the experiment. However, either the increasing flow rate, or the total injected volume become the dominant factors determining CO2 migration later in the experiment.
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