Meteorite impacts produce shocked minerals in target rocks that record diagnostic high-pressure deformation microstructures unique to hypervelocity processes. When impact craters erode, detrital shocked minerals can be transported by fluvial processes, as has been demonstrated through studies of modern alluvium at some of the largest known impact structures. However, the ultimate fate of distally transported detrital shocked minerals in fluvial systems is not well understood and is an important parameter for constraining the location of a source crater. In South Africa, detrital shocked minerals from the 2020 Ma Vredefort impact structure have been documented in the Vaal River basin, downriver from the structure. Here, we report results of an extensive microstructural survey of detrital zircon from the Orange River basin and the Atlantic coast of South Africa to search for the presence of far-traveled Vredefort-derived detrital shocked zircon grains in different modern sedimentary environments. Three shocked grains were found out of 11 168 grains surveyed (0.03%) by scanning electron microscopy, including two in beach sand on the Atlantic coast and one from a sandbar 15 km upstream from the mouth of the Orange River. Shock-produced {112} twins documented by electron backscatter diffraction in each of the three grains confirm their impact provenance, and U-Pb ages from 3130 to 3040 Ma are consistent with derivation from bedrock at the Vredefort impact structure. These results demonstrate the transport of Vredefort-derived shocked zircon to the coast via the Vaal-Orange river system, which requires 1940 km of fluvial transport from their point source on the Kaapvaal craton to the Atlantic coast passive margin. These results further demonstrate that shocked zircon grains can be detected in detrital populations at abundances <1%, and can ultimately be transported outside their basin of origin when they arrive at continental margins. Detrital shocked zircon thus constitutes long-lived evidence of former impacts, as they retain microstructural evidence of shock deformation, as well as geochemical (U-Th-Pb) fingerprints of their source terrain. The study of detrital shocked minerals uniquely merges impact cratering with sedimentology, as identification of detrital grains with diagnostic shock microstructures in siliciclastic sediments can be applied to search the sedimentary record for evidence of eroded impact structures of any age, from the Phanerozoic to the Hadean, which can aid in reconstructing the impact record of Earth.
Abstract As a common constituent of metamorphic assemblages, rutile provides constraints on the timing and conditions of rock transformation at high resolution. However, very little is known about the links between trace element mobility and rutile microstructures that result from synmetamorphic deformation. To address this issue, here we combine in situ LA‐ICP‐MS and sensitive high‐resolution ion microprobe trace element data with electron back‐scatter diffraction microstructural analyses to investigate the links between rutile lattice distortions and Zr and U–Pb systematics. Furthermore, we apply this integrated approach to constrain further the temperature and timing of amphibolite facies metamorphism and deformation in the Bergen Arcs of southwestern Norway. In outcrop, the formation of porphyroblastic rutile in dynamically hydrated leucocratic domains of otherwise rutile‐poor statically hydrated amphibolite provides key contextual information on both the ambient conditions of hydration and deformation and the composition of the reactive fluid. Rutile in amphibolite recorded ambient metamorphic temperatures of ~590–730°C during static hydration of the granulitic precursor. By contrast, rutile from leucocratic domains in the directly adjacent shear zone indicates that deformation was accompanied by a localized increase in temperature. These higher temperatures are recorded in strain‐free rutile (~600–860°C) and by Zr concentration measurements on low‐angle boundaries and shear bands (620–820°C). In addition, we also observe slight depletions of Zr and U along rutile low‐angle boundaries relative to strain‐free areas in deformed grains from the shear zone. This indicates that crystal–plastic deformation facilitated the compositional re‐equilibration of rutile upon cooling to slightly below the peak temperature of deformation. Cessation of deformation at mid‐crustal conditions near ~600°C is recorded by late stage growth of small (<150 µm) rutile in the high‐strain zones. U–Pb age data obtained from the strain‐free and distorted rutile grains cluster in distinct populations of 437.4 ± 2.7 Ma and c. 405–410 Ma, respectively. These different ages are interpreted to reflect the difference in closure for thermally induced Pb diffusion between undeformed and deformed rutile during post‐deformation exhumation and cooling. Thus, our results provide a reconstruction of the thermochronological history of the amphibolite facies rocks of the Lindås Nappe and highlight the importance of integration of microstructural data during application of thermometers and geochronometers.
The Miranda do Douro orthogneiss was believed to be the oldest magmatic rock of the Central Iberian Zone, on the base of a U-Pb discordia upper intercept of 618 ± 9 Ma. Nevertheless, new ion-microprobe and LA-ICPMS U-Pb zircon dating revealed that the crystallization age was 483 ± 3 Ma. The orthogneiss also contains a 605 ± 13 Ma zircon population that indicates that the source-rock for the Ordovician magma was Pan-African. Moreover, a few ~3.17 Ga zircon grains were also recorded. These grains are the oldest found so far in Iberia, and its occurrence would suggest the involvement of an Archean crust in the Pan-African orogeny.
Abstract The deformed Paleozoic succession of the Eastern Moroccan Meseta crops out in relatively small and isolated inliers surrounded by Mesozoic and Cenozoic rocks. Two of the largest inliers (Mekkam and Debdou) are characterized by a monotonous succession of slates and greywackes affected by polyphasic folding that occurred at low‐ to very low grade metamorphic conditions. New U‐Pb ages on detrital zircon grains from the Debdou‐Mekkam metasediments constrain the maximal depositional age as Late Devonian, interpreted to be close to the true sedimentation age. Furthermore, the ε Hf values of the Devonian detrital zircons, together with the presence of a series of scattered zircon grains with ages between c. 0.9 and c. 1.9 Ga, suggest provenance from a subduction‐related magmatic arc located on the Avalonian margin. The Debdou‐Mekkam massif is characterized by an Early Carboniferous first deformational event (D1), which gave way to a pervasive cleavage (S1) associated with plurikilometric‐scale, tight to isoclinal, overturned to recumbent folds. Later events (Dc) occurred at Late Carboniferous time and generated variably developed crenulation cleavages (Sc) associated with variously oriented metric‐ to kilometric‐scale folds, which complicate the pattern of both D1 intersection lineations (L1) and axial traces. The restoration of this pronounced curved pattern yields originally SW‐NE‐oriented D1 fold axes with regional SE‐vergence. This important Early Carboniferous shortening and SE‐directed tectonic transport can be explained by closure of the Rheic Ocean and the first phases of the collision between the northern passive margin of Gondwana and an Avalonian promontory.
Abstract The east-northeast-trending Murchison-Thabazimbi Lineament in northern South Africa is one of the world’s most important structures for its control on world-class mineral deposits, Proterozoic sedimentary basins and giant igneous intrusions. The deepest exposed Archaean parts of the lineament are the Murchison Belt. Bounded by granitoids, the belt comprises greenschist to amphibolite facies volcano-sedimentary strata with isoclinal folds and the 7 km thick meta-igneous Rooiwater Complex. The Rooiwater Complex is intruded by a northern regional granitoid dated at 2 929 ± 7 Ma by SHRIMP U-Pb on zircons. Using field relationships, published isotopic age data and new SHRIMP zircon dates we confirm the age Rooiwater Complex at 2 965 Ma, showing it to be contemporaneous with the Archaean volcanic and sedimentary formations, the meta-igneous Complex being the lower sequence in a ~2 980 to 2 960 Ma island arc. Despite being implicated as a source of gold for the world’s largest natural accumulation of gold in the Witwatersrand Basin, the absolute age of Sb-Au mineralisation in the Murchison Belt is poorly constrained. We have utilised SHRIMP U-Pb geochronology to date monazites from a Sb-Au ore sample from the granitoid-hosted Malati Pump orebody and determine ages for two different generations of monazite, both associated with ore minerals. The older age of 2 832 ± 23 Ma is from a minority of grains and is interpreted to date the primary Sb-Au mineralisation, about 120 Ma after belt formation. This age predates, or is possibly synchronous with, sedimentation of the upper-Witwatersrand Central Rand Group. The younger age of 1 968 ± 17 Ma from a majority of monazite grains is unrelated in time to known events and interpreted here as a cryptic hydrothermal reworking of the Sb-Au ores in this deposit.
ABSTRACT Accessory mineral U-Pb geochronometers are crucial tools for constraining the timing of deformation in a wide range of geological settings. Despite the growing recognition that intragrain age variations within deformed minerals can spatially correlate to zones of microstructural damage, the causal mechanisms of Pb loss are not always evident. Here, we report the first U-Pb data for shock-deformed xenotime, from a detrital grain collected at the Vredefort impact structure in South Africa. Orientation mapping revealed multiple shock features, including pervasive planar deformation bands (PDBs) that accommodate up to 40° of lattice misorientation by <100>{010} slip, and also an ~50-µm-wide intragrain shear zone that contains {112} deformation twin lamellae in two orientations. Twenty-nine in situ secondary ion mass spectrometry (SIMS) U-Pb analyses from all microstructural domains yielded a well-defined discordia with upper-intercept age of 2953 ± 15 Ma (mean square of weighted deviates [MSWD] = 0.57, n = 29, 2σ), consistent with derivation from Kaapvaal craton bedrock. However, the 1754 ± 150 Ma lower concordia intercept age falls between the 2020 Ma Vredefort impact and ca. 1100 Ma Kibaran orogenesis and is not well explained by multiple Pb-loss episodes. The pattern and degree of Pb loss (discordance) correlate with increased [U] but do not correlate to microstructure (twin, PDB) or to crystallinity (band contrast) at the scale of SIMS analysis. Numerical modeling of the Pb-loss history using a concordia-discordia-comparison (CDC) test indicated that the lower concordia age is instead best explained by an alteration episode at ca. 1750 Ma, rather than a multiple Pb-loss history. In this example, the U-Pb system in deformed xenotime does not record a clear signature of impact age resetting; rather, the implied high dislocation density recorded by planar deformation bands and the presence of deformation twins facilitated subsequent Pb loss during a younger event that affected the Witwatersrand basin. Microstructural characterization of xenotime targeted for geochronology provides a new tool for recognizing evidence of deformation and can provide insight into complex age data from highly strained grains, and, as is the case in this study, elucidate previously unrecognized alteration events.