Abstract The Palaeoproterozoic Birimian Supergroup of the West African Craton (WAC) consists of volcanic belts composed predominantly of basaltic and andesitic rocks and intervening sedimentary basins composed predominantly of wackes and argillites. Mafic metavolcanic rocks and granitoid-hosted enclaves from the Palaeoproterozoic Lawra Belt of Ghana were analysed for geochemical and Sr–Nd isotopic data to constrain the geological evolution of the southeastern part of the WAC. The metavolcanic rocks display mainly tholeiitic signatures, whereas the enclaves show calc-alkaline signatures. The high SiO 2 contents (48.6–68.9 wt%) of the enclaves are suggestive of their evolved character. The high Th/Yb values of the samples relative to that of the mantle array may indicate derivation of their respective magmas from subduction-modified source(s). The rocks show positive ε Nd values of +0.79 to +2.86 (metavolcanic rocks) and +0.79 to +1.82 (enclaves). These signatures and their Nd model ages ( T DM2 ) of 2.31–2.47 Ga (metavolcanic rocks) and 2.39–2.47 Ga (enclaves) suggest they were probably derived from juvenile mantle-derived protoliths, with possible input of subducted pre-Birimian (Archean?) rocks in their source(s). Their positive Ba–Th and negative Nb–Ta, Zr–Hf and Ti anomalies may indicate their formation through subduction-related magmatism consistent with an arc setting. We propose that the metavolcanic rocks and enclaves from the Lawra Belt formed in a similar island-arc setting. We infer that the granitoids developed through variable degrees of mixing/mingling between basic magma and granitic melt during subduction, when blobs of basic to intermediate parental magma became trapped in the granitic magma to form the enclaves.
The petrographical and geochemical analyses of greywacke and siltstone samples from the Nampala gold deposit of the Paleoproterozoic Birimian supergroup, Southern Mali, have been carried out to make inferences on the provenance, tectonic settings, and weathering history of the sediments. Petrographical investigations revealed that greywackes can be classified as feldspathic wackes, with immature to moderately mature sediments, with the siltstones being immature. Geochemically, greywackes show features that resemble typical wacke sedimentary rocks, whereas the siltstones are arkose to litharenite. Overall, Nampala sedimentary rocks experienced low intensity of paleoweathering with <70 CIA and <90 CIW values and have not undergone significant sediment recycling having >1 CIV values. Their quartz and feldspar contents, together with the ratio of Al 2 O 3 /TiO 2 and La/Sc, suggest the derivation of sediments from felsic igneous rocks, with a possible minor contribution from mafic proto-source rock. The petrographic and geochemical features of the greywackes and siltstones are consistent with siliciclastic rocks formed in an active continental margin, similar to other sedimentary rocks of the Paleoproterozoic Birimian terrane. These findings put positive constraints on the subduction-accretion geodynamic model proposed for the evolution of the Birimian terrane of the West African Craton.
Abstract The study presents detailed petrographical, geophysical, structural and geochemical data of the internal nappes zone to establish the deformational history, origin and tectonic setting and constrain the crustal growth and evolution of the active margin of the Dahomeyide belt. Two main lithological units, (i) deformed meta-granitoids (migmatites and gneisses) and (ii) undeformed granitoids, dominate the internal nappes zone. The granitoids are generally I-type, metaluminous to weakly peraluminous, low-K tholeiite to high-K calc-alkaline and of tonalite, granodiorite and granite affinity. The overall trace element patterns of the studied granitoids characterized by the enriched LILE and depleted HFS, with negative peaks of Nb-Ta, Sr, P and Ti, are indications of arc-related magmatism. Structural analysis reveals four deformation phases (D 1 -D 4 ). D 1 represents Northwest-Southeast (NW-SE) Pan African shortening associated with a continent-continent collision, resulting in westward nappe stacking. Progressive NW-SE shortening resulted in D 2 and D 3 top-to-the-NW dextral and sinistral thrusting events during the Pan-African orogeny. D 4 is an extensional event likely associated with the orogenic collapse phase. The gneisses and migmatites, with dominant axial planar foliations, point to their formation in a collisional setting or influence by the Pan-African collisional processes. Continental-arc signatures in these rocks imply continental subduction during their protolith formation. The intrusive granitoid and pegmatite are undeformed, meaning late- to post-orogenic emplacement. These findings suggest that the internal nappes zone archived the subduction-collision and post-collisional phase of the Pan-African orogeny and recorded large-scale migmatization and granitoid emplacement due to partial melting of thickened lower crust between Mid-Cryogenian and late Ediacaran.
Metavolcanics and mafic intrusive rocks of the Paleoproterozoic Birimian terrane in the southeastern part of the West African Craton, Ghana, were analyzed for major and trace elements and Nd and Sr isotopic data to constrain the geodynamic evolution of the Birimian Supergroup. The metavolcanic rocks consist of metabasalts, meta‐andesites, and amphibolites, whereas the mafic intrusions are mainly gabbros, hornblendites, and dolerites. The rocks are tholeiitic in composition and show the classic features of arc magmatism. The metavolcanics display significant enrichments in large ion lithophile elements (LILE) and light rare earth elements, relative to high field strength elements (HFSE) and heavy rare earth elements. The multielement patterns of the rocks also show positive Pb, Ba, Th, and Sr and negative Nb, Ta, and Ce anomalies that are typical characteristics of subduction‐related magmas. They also have La/Nb ratios <3 and La/Ta ratios <43 that are similar to other Archean and Birimian greenstone belts in West Africa. The rocks have ε Nd (2.1 Ga) values of −0.96 to +2.60, and Nd model ages of 2.24–2.51 Ga (T DM1 ) and 2.16–2.45 Ga (T DM2 ), indicating their juvenile character with possible contributions from pre‐Birimian crustal materials in their sources. The ε Nd values suggest a depleted source and further indicate that they were probably produced in an almost entirely oceanic environment with minor influence from the continental crust. The Nd isotopic results are consistent with the island arc model, which views Paleoproterozoic terranes of the West African Craton in the context of subduction–accretion processes. Accordingly, these processes may have played a role in the formation of the Columbia supercontinent during the Paleoproterozoic (2.1–1.8 Ga) orogenic events.
The metasedimentary rocks of the Sefwi and Lawra volcanic belts in Ghana respectively were analysed for their major and trace elements and Sr‐Nd isotopic compositions to constrain the provenance, palaeo‐weathering conditions, and tectonic setting of the rocks. Geochemical characteristics of the metasedimentary rocks show low to moderate chemical weathering in their source regions and the rocks are interpreted to have been derived from mixture of mafic and felsic rock components. The LREE show much enrichment in relation to the HREE (La N /Lu N , 4.67‐11.66). The ε Nd (2.1 Ga) values of −0.12 to +3.72 strongly suggest that the source of the sedimentary rocks was derived from a depleted mantle source and that they were most likely produced in an almost entirely oceanic environment with minor influence from the continental crust. The Nd model ages ranging from +2.05 to 2.41 Ga suggest possible contributions of a pre‐Birimian crustal material (or Archaean?) in the source material of the volcanic rocks. The rock types that contributed as detritus to the Birimian metasedimentary rocks were mainly pyroclastics and basalts, and their REE patterns suggest that the contribution to the phyllites can be modelled after 20% basalt, 13% andesite, and 67% dacite. Similarly, the schists can be modelled as a mixture of 16% basalt, 34% andesite, and 50% dacite. The Nd isotopic modeling implies that the bulk of the sedimentary detritus was supplied by the Palaeoproterozoic volcanic arc with contributions of less than 10% from the pre‐Birimian crust (Archaean?).
Petrography, major, trace element and Rare Earth Element (REE) data are presented for volcanic rocks from the Eastern Buem Structural Unit (BSU) in south-eastern Ghana to constrain their petrogenesis and tectonic setting. The volcanic rocks are generally aphanitic, ophitic and massive, although some varieties exhibit weak foliation. They are primarily composed of plagioclase and pyroxene. These primary minerals have either partially or wholly altered to chlorite, epidote, sericite and opaque minerals. The basalts have low TiO2 (0.56–1.19 wt. %) content with fairly low magnesium numbers ranging from 38 to 55. They display flat to slightly depleted REE patterns and are mostly more enriched than chondrite. On the primitive mantle (PM) normalised spider diagram, they are variably enriched in Light Rare Earth Elements (LREE) and incompatible elements relative to normal mid-ocean ridge basalt (N-MORB), with similar Large-ion Lithophile Element (LILE) and High Field Strength Element (HFSE) patterns as enriched mid-ocean ridge basalt (E-MORB) but 10 fold more enriched than primitive mantle (PM). They show minor negative and positive Sr, positive Cs, Ba, Ta, La and Ce anomalies and minor negative Rb, Th, Zr and Ti anomalies. The basalts plot within the MORB mantle array on the Th/Yb versus the Nb/Yb diagram and have low Th/Nb ratios (0.07– 0.09) which indicate their derivation from asthenospheric sources with minimal or no contamination from crustal or subducted components. They show affinity to Enriched MORB on multi-trace element normalised diagrams. The E-MORB affinity of the basalts is also confirmed on Th–Hf–Nb, Y–La–Nb and V–Ti tectonic discrimination diagrams. These volcanic rocks may have erupted during rifting along the marginal basin of the WAC prior to peak collision during the Pan-African Orogeny.
Gold-bearing granitoid deposits have recently been discovered in the Birimian of Ghana but their mode of formation and ore genesis remain enigmatic. This study presents petrographic, and geochemical characteristics of mineralised and unmineralised (gold grade >0.05 and <0.05 g/t respectively) granitoids (now gneisses) and schists (metasedimentary) to evaluate their petrogenesis/provenance, and relationship to gold mineralisation in the Abansuoso area. The unmineralised rocks comprise biotite- and hornblende-biotite gneisses, sericite-quartz, carbonate-sericite, and biotite-quartz schist. The mineralised varieties are biotite-, muscovite gneiss, iron-carbonate-sericite, carbonate-sericite-quartz, chlorite-carbonate, and biotite-carbonate schist. The mineralised and unmineralised gneisses are both metaluminous and peraluminous. Both mineralised and unmineraised gneiss and schist show Nb-Ta trough, depleted LILE and enriched HFSE although widespread overall trace element concentrations for the mineralised rocks on UCC-normalised multi-element diagram, suggestive of their formation in an arc setting. This suggests coeval granitic plutonism and sedimentation with subduction-accretion during the Eburnean orogeny, hence, mineralisation may be orogenic-type.
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