Abstract The presence of major crystalline basement provinces at depth in NW Ireland is inferred from in situ Hf isotope analysis of zircons from granitoid rocks that cut structurally overlying metasedimentary rocks. Granitoids in two of these units, the Slishwood Division and the Tyrone Central Inlier, contain complex zircons with core and rim structures. In both cases, cores have average ϵHf values that differ from the average ϵHf values of the rims at 470 Ma (the time of granitoid intrusion). The Hf data and similarity in U–Pb age between the inherited cores and detrital zircons from the host metasedimentary rocks suggests local contamination during intrusion rather than transport of the grains from the source region at depth. Rims from the Slishwood Division intrusions have average ϵHf 470 values of −7.7, consistent with a derivation from juvenile Palaeoproterozoic crust, such as the Annagh Gneiss Complex or Rhinns Complex of NW Ireland, implying that the deep crust underlying the Slishwood Division is made of similar material. Rims from the Tyrone Central Inlier have extremely negative ϵHf 470 values of approximately −39. This isotopic signature requires an Archaean source, suggesting rocks similar to the Lewisian Complex of Scotland, or sediment derived wholly from it, occurs at depth in NW Ireland.
The Nile is generally regarded as the longest river in the world. Knowledge of the timing of the Nile's initiation as a major river is important to a number of research questions. For example, the timing of the river's establishment as a catchment of continental proportions can be used to document surface uplift of its Ethiopian upland drainage, with implications for constraining rift tectonics. Furthermore, the time of major freshwater input to the Mediterranean is considered to be an important factor in the development of sapropels. Yet the river's initiation as a major drainage is currently constrained no more precisely than Eocene to Pleistocene. Within the modern Nile catchment, voluminous Cenozoic Continental Flood Basalts (CFBs) are unique to the Ethiopian Highlands; thus first detection of their presence in the Nile delta record indicates establishment of the river's drainage at continental proportions at that time. We present the first detailed multiproxy provenance study of Oligocene–Recent Nile delta cone sediments. We demonstrate the presence of Ethiopian CFB detritus in the Nile delta from the start of our studied record (c. 31 Ma) by (1) documenting the presence of zircons with U–Pb ages unique, within the Nile catchment, to the Ethiopian CFBs and (2) using Sr–Nd data to construct a mixing model which indicates a contribution from the CFBs. We thereby show that the Nile river was established as a river of continental proportions by Oligocene times. We use petrography and heavy mineral data to show that previous petrographic provenance studies which proposed a Pleistocene age for first arrival of Ethiopian CFBs in the Nile delta did not take into account the strong diagenetic influence on the samples. We use a range of techniques to show that sediments were derived from Phanerozoic sedimentary rocks that blanket North Africa, Arabian–Nubian Shield basement terranes, and Ethiopian CFB's. We see no significant input from Archaean cratons supplied directly via the White Nile in any of our samples. Whilst there are subtle differences between our Nile delta samples from the Oligocene and Pliocene compared to those from the Miocene and Pleistocene, the overall stability of our signal throughout the delta record, and its similarity to the modern Nile signature, indicates no major change in the Nile's drainage from Oligocene to present day.
New U-Pb dating of zircons separated from felsic volcanic rocks of the Patuxent and Gambacorta formations from the Pensacola Mountains in the Transantarctic Mountains, Antarctica, yields earliest Ordovician ages of 500 ± 8 and 501 ± 3 Ma respectively. The dated felsic volcanic rock of the Gorecki Felsite Member of the Patuxent Formation is important tectonically, as the felsite, together with mafic volcanic rocks, were previously considered to provide key evidence of a Neoproterozoic rifting event prior to separation of Laurentia from East Antarctica. The new data do not necessarily refute this event but indicate a previously unrecognized early Ordovician period of bimodal magmatism and extension along the Transantaractic Mountains.
Abstract Jurassic dykes of western Dronning Maud Land (Antarctica) form a minor component of the Karoo large igneous province. An extensive local dyke swarm intrudes Neoproterozoic gneisses and Jurassic syenite plutons on the margins of the Jutulstraumen palaeo rift in the Svedrupfjella region. The dykes were intruded in three distinct episodes (~204, ~176 and ~170 Ma). The 204 Ma dykes are overwhelminglylow-Ti, olivine tholeiites including some primitive (picritic) compositions (MgO >12 wt.%; Fe 2 O 3 >12 wt.%; Cr >1000 ppm; Ni >600 ppm). This 204 Ma event precedes the main Karoo volcanic event by~25 Ma, so anycorrelations to the wider province are difficult to make. However, it mayrecord the earliest phase of rift activity along the Jutulstraumen. The 176 Ma dyke event is more intimately associated with the two syenite plutons. The dykes are alkaline (basanite/ tephrite) and were small-degree melts from an enriched, locallyderived source and underwent at least some degree of interaction with a syenitic contaminant. This ~176 Ma dyke event is widespread elsewhere in the Karoo (southern Africa and Dronning Maud Land). Later-stage (170 Ma) felsic (phonolite–comendite) dykes intrude the 176 Ma basanite–tephrite suite and represent the last phase of magmatic activityin the region.
U–Pb SHRIMP ages are reported for three rhyolite flows from the Lebombo rift region of the Karoo volcanic province. Two flows are interbedded with the Sabie River Basalt Formation and a third sample is from the overlying rhyolitic Jozini Formation. The interbedded rhyolites yield ages of 182.0 ± 2.1 and 179.9 ± 1.8 Ma, whilst the overlying Jozini Formation rhyolite yields an age of 182.1 ± 2.9 Ma. Combined with existing 40 Ar/ 39 Ar geochronology, the new SHRIMP data fine-tunes the chronology of the Karoo volcanic province and indicates the 12 km succession of volcanic rocks in the Lebombo rift were erupted in 1–2 million years and lends considerable support to the links between the Pleinsbachian–Toarcian extinction event and the global environmental impact of Karoo volcanism.
Mineral dust concentrations are coupled to climate over glacial-interglacial cycles with increased dust deposition occurring during major cold phases over the last ~100 ka. Holocene records suggest considerable spatial and temporal variability in the magnitude, frequency and timing of dust peaks that reflects regional or local drivers of dust emissions and transport. Here, we present stratigraphical, geochemical and isotopic evidence for dust deposition from two high-resolution peat sequences 200 km apart in northern Scotland spanning the last c. 8200 years. εNd isotope data suggest the dominant minerogenic dust source switches between a low latitude (likely Saharan) and a high latitude, Icelandic source. Marked peaks in increased minerogenic dust deposition at: c. 5.4–5.1, 4.0–3.9, 2.8–2.6, 1.0 and 0.3 ka BP occur against a backdrop of low dust deposition during the mid-Holocene (c. 5.0–4.0 ka BP) and increased background levels of dust during the neoglacial period (<4.0 ka BP). These dust peaks coincide with periods of glacial advance in Iceland and heightened storminess in the North Atlantic. Isotope data for additional dust peaks at c. 1.0 and 0.7 ka BP and the last ~50 years suggest these reflect increased dust from the Sahara associated with aridity and land-use change in North Africa during the Late-Holocene, and modern anthropogenic sources. This work highlights the complexity of Holocene records of dust deposition in the North Atlantic and emphasises the role of dynamic sub-Polar glaciers and their meltwater systems as a significant dust source.
<p>Faults, joints and stylolites are ubiquitous features in fold-and-thrust belts commonly used to reconstruct the past fluid flow (or plumbing system) at the scale of folded reservoir/basins. Through the textural and geochemical study of the minerals that fills the fractures, it is possible to understand the history of fluid flow in an orogen, requiring a good knowledge of the burial history and/or of the past thermal gradient. In most of the case, the latter derives from the former, itself often argued over, limiting the interpretations of past fluid temperatures. We present the results of a multi-proxy study that combines novel development in both structural analysis of a fracture-stylolite network and isotopic characterization of calcite vein cements/fault coating. Together with new paleopiezometric and radiometric constraints on burial evolution and deformation timing, these results provide a first-order picture of the regional fluid systems and pathways that were present during the main stages of contraction in the Tuscan Nappe and Umbria-Marche Apennine Ridge (Northern Apennines). We reconstruct four steps of deformation at the scale of the belt: burial-related stylolitization, Apenninic-related layer-parallel shortening with a contraction trending NE-SW, local extension related to folding and late stage fold tightening under a contraction still striking NE-SW. We combine the paleopiezometric inversion of the roughness of sedimentary stylolites - that provides a temperature-free constraint on the range of burial depth of strata prior to layer-parallel shortening -, with burial models and U-Pb absolute dating of fault coatings in order to determine the timing of development of mesostructures. In the western part of the ridge, layer-parallel shortening started in Langhian time (~15 Ma), then folding started at Tortonian time (~8 Ma), late stage fold tightening started by the early Pliocene (~5 Ma) and likely lasted until recent/modern extension occurred (~3 Ma onward). The textural and geochemical (&#948;<sup>18</sup>O, &#948;<sup>13</sup>C, &#8710;<sub>47</sub>CO<sub>2</sub> and <sup>87</sup>Sr/<sup>86</sup>Sr) study of calcite vein cements and fault coatings reveals that most of the fluids involved in the belt during deformation are basinal brines evolved from various degree of fluid rock interactions between pristine marine fluids (&#948;<sup>18</sup>O<sub>fluids</sub> = 0&#8240; SMOW) and surrounding limestones (&#948;<sup>18</sup>O<sub>fluids</sub> = 10&#8240; SMOW). The precipitation temperatures (35&#176;C to 75&#176;C) appear consistent with the burial history unraveled by sedimentary stylolite roughness paleopiezometry (600 m to 1500m in the range) and geothermal gradient (23&#176;C/km). However, the western edge of the ridge recorded isotopically depleted past fluids of which corresponding precipitation temperature (100&#176;C to 130&#176;C) are inconsistent with local burial history (1500m). We interpret then pulses of eastward migration of hydrothermal fluids (>140&#176;C), driven by the tectonic contraction and by the difference in structural style of the subsurface between the eastern Tuscan Nappe and the Umbria-Marche Apennine Ridge. Allowed by an unprecedented combination of paleopiezometry and isotopic geochemistry, this fluid flow model illustrates how the larger scale structures control the fluid system at the scale of the range.</p>
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