Abstract An increasing number of pesticide compounds are being detected in groundwater supplies worldwide. There has, nevertheless, been little research into the mechanisms by which such pollution occurs and the routes via which pesticides move from the land surface into aquifers. In view of the potential time‐lag in the response of groundwater systems to pollution inputs, such knowledge is essential if the current situation is to be appraised adequately and if any necessary controls on pesticide use are to be introduced. From basic data on the physicochemical properties of pesticide compounds and on groundwater flow and pollutant transport in the principal British aquifers, some useful observations can be made about the relative significance of different mechanisms of potential groundwater pollution. These mechanisms and their implications for field research on pesticide pollution of groundwater are discussed. This problem is compared and contrasted to that of nitrate pollution from agricultural land‐use practices.
The exploitation of groundwater resources for human use dates from the earliest civilizations, but massive resource development has been largely restricted to the past 50 years. Although global in scope, the emphasis of this paper is on groundwater-based economies in a developing nation context, where accelerated resource development has brought major social and economic benefits over the past 20 years. This results from groundwater's significant role in urban water supply and in rural livelihoods, including irrigated agriculture. However, little of the economic benefit of resource development has been reinvested in groundwater management, and concerns about aquifer degradation and resource sustainability began to arise. A general review, for a broad-based audience, is given of the mechanisms and significance of three semi-independent facets of aquifer degradation. These are (i) depletion of aquifer storage and its effects on groundwater availability, terrestrial and aquatic ecosystems; (ii) groundwater salinization arising from various different processes of induced hydraulic disturbance and soil fractionation; and (iii) vulnerability of aquifers to pollution from land-use and effluent discharge practices related to both urban development and agricultural intensification. Globally, data with which to assess the status of aquifer degradation are of questionable reliability, inadequate coverage and poor compilation. Recourse has to be made to 'type examples' and assumptions about the extension of similar hydrogeological settings likely to be experiencing similar conditions of groundwater demand and subsurface contaminant load. It is concluded that (i) aquifer degradation is much more than a localized problem because the sustainability of the resource base for much of the rapid socio-economic development of the second half of the twentieth century is threatened on quite a widespread geographical basis; and (ii) major (and long overdue) investments in groundwater resource and quality protection are urgently needed. These investments include appropriate institutional provisions, demand-side management, supply-side enhancement and pollution control.
Abstract Following a monitoring programme of private shallow boreholes a total of 22 different pesticides were detected in 14 shallow boreholes in the Triassic Sherwood Sandstone aquifer of south Yorkshire, UK between January 2002 and November 2003. Of the 294 positive detections made, 34% were detected in excess of the permitted concentration value (PCV) (drinking water standard) for individual pesticides. Pesticides were detected in 11 (78%) of the boreholes, and in eight (57%) at concentrations exceeding the PCV on at least one occasion. These findings were complemented by data from deeper boreholes in which concentrations exceeding the PCV were also detected. Pesticide occurrence could be related to landuse; mecoprop and isoproturon were frequently detected at several locations reflecting the arable landuse, dicamba at a golf course, and atrazine, propazine and terbutryn near a railway. Temporal variations have emerged at individual sites and across the study area as the result of extended and frequent monitoring.
ABSTRACT I ron is not normally considered to be a constituent of health significance, and recommended limits for iron in drinking water supplies are based on aesthetic considerations. Experience in Malawi has demonstrated that, even when present in only trace amounts, iron can influence the consumer's acceptance of an improved borehole supply. The effect of the use of plastic construction materials on the iron content of village groundwater supplies was investigated using a statistical approach. The majority of groundwater points using only plastic materials was found to supply water containing less than the WHO guideline value of 0.3 mg/l iron. In contrast, the use of ferrous‐materials increased the iron content of the water to unacceptable levels, sometimes causing the consumers to reject the borehole as a source of drinking water. Bacteriological data show that the quality of the alternative, traditional supply is far inferior to the new improved supply. An otherwise perfectly safe supply may therefore be abandoned as a direct result of contamination introduced by ‘down the hole’ components. This frustrates efforts to improve the well‐being of rural communities, and is a waste of precious development resources.
Abstract The behavior of the herbicides isoproturon (IPU) and chlortoluron (CTU) in ground water and shallow unsaturated zone sediments were evaluated at a site situated on the Chalk in southern England. Concentrations of IPU in ground water samples varied from <0.05 to 0.23 μg/L over a five‐year period of monitoring, and were found to correlate with application of the pesticide. Concentrations of pesticides in ground water samples collected during periods of rising water table were significantly higher than pumped samples and suggest that rapidly infiltrating recharge water contains higher herbicide concentrations than the native ground water. Significant variations in herbicide concentrations were observed over a three‐month period in ground water samples collected by an automated system, with concentrations of IPU ranging from 0.1 to 0.5 μg/L, and concentrations of a recent application of CTU ranging from 0.2 to 0.8 μg/L. Different extraction methods were used to assess pore water concentrations of herbicides in the unsaturated zone, and samples were analyzed by standard HPLC analysis and immunoassay (ELISA) methods. These data indicated highly variable concentrations of herbicide ranging from 4 to 200 g/ha for HPLC and 0.01 to 0.04 g/ha for ELISA, but indicate a general pattern of decreasing concentrations with depth. The results of this study indicate that transport of IPU and CTU through the unsaturated zone to shallow ground water occurs and that this transport Increases immediately following herbicide application. Measured concentrations of herbicides are generally lower than specified by the European Union Drinking Water Directive, but are observed to spike above this limit. These results imply that, while delivery of pesticides to ground water can occur as a result of normal agricultural practices, the Impact on potable supplies Is likely to be negligible due to the potential for degradation during the relatively long travel time through the unsaturated zone and high degree of dilution that occurs within the aquifer. As a result of the wide variation in concentrations detected by different techniques, it is suggested that for future site Investigations more than one sampling strategy be employed to characterize the occurrence of pesticide residues and elucidate the transport mechanisms.
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