Abstract The microstructures, major‐ and trace‐element compositions of minerals and electron backscattered diffraction (EBSD) maps of high‐ and low‐Cr# [spinel Cr# = Cr 3+ /(Cr 3+ +Al 3+ )] chromitites and dunites from the Zedang ophiolite in the Yarlung Zangbo Suture (South Tibet) have been used to reveal their genesis and the related geodynamic processes in the Neo‐Tethyan Ocean. The high‐Cr# (0.77‐0.80) chromitites (with or without diopside exsolution) have chromite compositions consistent with initial crystallization by interaction between boninitic magmas, harzburgite and reaction‐produced magmas in a shallow, mature mantle wedge. Some high‐Cr# chromitites show crystal‐plastic deformation and grain growth on previous chromite relics that have exsolved needles of diopside. These features are similar to those of the Luobusa high‐Cr# chromitites, possibly recycled from the deep upper mantle in a mature subduction system. In contrast, mineralogical, chemical and EBSD features of the Zedang low‐Cr# (0.49‐0.67) chromitites and dunites and the silicate inclusions in chromite indicate that they formed by rapid interaction between forearc basaltic magmas (MORB‐like but with rare subduction input) and the Zedang harzburgites in a dynamically extended, incipient forearc lithosphere. The evidence implies that the high‐Cr# chromitites were produced or emplaced in an earlier mature arc (possibly Jurassic), while the low‐Cr# associations formed in an incipient forearc during the initiation of a new episode of Neo‐Tethyan subduction at ∼130‐120 Ma. This two‐episode subduction model can provide a new explanation for the coexistence of high‐ and low‐Cr# chromitites in the same volume of ophiolitic mantle.
Abstract Variably serpentinized peridotites from the Zedang ophiolite in southern Tibet were magnetically and petrologically examined to understand the serpentinization process and evaluate the origin of magnetic anomalies in ultramafic‐hosted tectonic settings. Magnetite occurs in the serpentine and brucite veins and is identified as the dominant magnetic carrier by thermomagnetic and petrological analyses. The magnetic susceptibility increases rapidly from <0.001 to ~0.02 SI for the <50% serpentinized samples followed by nearly constant values of 0.02–0.03 SI above 50% serpentinization. This transition corresponds with the formation of Fe‐poor serpentine mesh (2–3 wt% FeO) and magnetite in the early stages and the replacement of mesh center olivine by Fe‐rich serpentine (4–5 wt% FeO) without magnetite in the late stages. Brucite veins occur in the 50–70% serpentinized samples and indicate serpentinization temperatures from ~250 to <100°C. The serpentinization may initiate at an oceanic spreading ridge center under high temperatures (>250–300°C) to produce magnetite and subsequently continue at lower temperatures (<200–250°C) in near‐seafloor settings and limit the magnetite formation, possibly associated with ophiolite emplacement. These serpentinized peridotites have higher magnetization intensities (average 2.26 Am −1 ) than dolerite dykes and basaltic volcanics (mostly <1 A m −1 ) in the area and should be the major source of aeromagnetic highs in the south Tibetan ophiolite belt.
Abstract A diffuse magmatic province covering central‐eastern Asia continent displays a compositional transition at 120–100 Ma and probably reflects melting initiation in isotopically enriched lithospheric mantle, followed by melting of the asthenosphere. However, the cause for the transition across such a vast landmass remains poorly constrained. Here, analyses of newly found Chaoge basalts (∼95 Ma, central Asia) and compiled data from across the basaltic province are combined to reveal the factors controlling the basalt dichotomy. The Chaoge basalts are considered to originate from a hot pyroxenite‐bearing asthenosphere with potential temperatures of ∼1,450°C, overlapping the source thermochemical conditions for most post‐transition basaltic rocks. The asthenosphere in 120–100 Ma is suggested to be hotter and to have controlled the compositional transition in the studied basaltic province. We suggest that asthenospheric warming resulted from prolonged continental thermal blanketing and can account for other diffuse igneous provinces with similar compositional variations and tectonic histories.
The early stages of magmatic processes operating at mantle depths beneath continental arcs are poorly known. The chemical compositions of minerals and rocks, mineral Sr–Nd–Hf–O isotopes and zircon U–Pb ages of garnet clinopyroxenite dykes from the Shenglikou peridotite massif (North Qaidam Orogen, NE Tibet, China) were studied to constrain their sources and genesis, and the dynamic processes that controlled pyroxenite formation beneath an early Paleozoic active continental margin. Major-element compositions of bulkrocks suggest that the pyroxenitic protoliths were cumulates segregated from a melt, which was extracted from a peridotite-dominated mantle source. Bulk-rock and mineral trace-element patterns show strong enrichment in fluid-mobile elements (e.g. Cs, Rb, Ba, Th, U, K, Pb and Li) and marked negative anomalies in the high field strength elements relative to rare earth elements, similar to the characteristics of melts derived from a volatile-rich sub-arc mantle. Enriched Sr and Nd initial isotopic compositions at 500 Ma (87Sr/86Sr of 0·70919–0·71774 and εNd of −16·3 to −3·4) are in contrast to the highly radiogenic Hf isotope compositions (similar to those of the depleted-mantle reservoir) and to the uncontaminated upper-mantle δ18OV-SMOW (garnet: 5·6 ± 0·3‰, 2SD, n = 61; zircon: 5·9 ± 0·3‰, 2SD, n = 28). These decoupled isotopic signatures suggest that the melt source was located in a convective mantle wedge (controlling the Hf and O isotopes) that had been pervasively metasomatized by fluids from a subducted Proto-Tethys oceanic slab (controlling the Sr–Nd isotopes and highly incompatible elements). Zircons with two groups of U–Pb ages (430 ± 5 Ma and 401 ± 7 Ma) were generated by recrystallization events, corresponding to UHP metamorphism and a major uplift stage during the North Qaidam orogeny, respectively. The combined evidence reveals a picture of continental arc magmatism at mantle depths and subsequent continental collision. The subduction of the Proto-Tethys oceanic slab beneath the southern Qilian margin triggered flux melting of the metasomatized convective mantle wedge and generated hydrous arc magmas. These primitive magmas intruded into the overlying lithospheric mantle and segregated the cumulates parental to the Shenglikou pyroxenites. Subsequent continental subduction incorporated fragments of the mantle-wedge peridotite (containing pyroxenite dykes) at ∼430 Ma and carried them to shallow depths during exhumation at ∼400 Ma.