Abstract The Ochre-Umm Greifat area is one of the Red Sea areas with high concentrations of iron and zinc, which is formed from hydrothermal solutions as a result of the structural activity that occurred in the Red Sea Zone during the Pleistocene period. These deposits are also accompanied by deposits of low- to high uranium grade. In addition to Zn, Pb, and Cu anomalies, particularly in fault zones and their branches affecting the study area, although there are numerous zinc minerals in the Ocher-Greifat area, uranium minerals are scarce, with only one mineral, compreignacite, being recorded and the majority of the uranium being present as an adsorbed element on iron and/or clay stones. In addition, uranothorite is extremely rare and occurs as fine grains embedded in rocks. A technological sample was taken from an iron-rich clay area in a fault zone and was found to assay 700-ppm uranium. The leachability of uranium from the used sample was investigated using an alkaline solution based on the chemical and mineralogical composition of the used sample. The selected ore is treated with Na 2 CO 3 and NaHCO 3 in the presence of H 2 O 2 as oxidant. Many digestion factors are studied and optimized. Under the optimum leaching conditions, the uranium dissolution efficiency is around 84%. For the uranium separation, the pH of the leach liquor is adjusted at 10, then subjected to a solvent extraction step using 4% Aliquat ® 336/kerosene in the presence of isodecanol as third-phase prevention. The loaded organic solvent was then treated with NaOH/H 2 O 2 solution as a stripping solution. Finally, the resultant solution is subjected to a precipitation step using ammonia solution.
Abstract The studied granitic bodies belong to the south Eastern Desert of Egypt. They extend in a NNW–SSE trend along the same strike of the Nugrus weakness zone by which they are structurally controlled. These rocks are composed of biotite and biotite‐muscovite monzogranites to syenogranites. Geochemically, a higher abundance of Ba and Rb in biotite granites with a relatively low abundance in biotite‐muscovite granites as well as the diversity of Th, U, Nb, Ta, Zr, and REE reflects their origin from different sources and geodynamic settings. The biotite granites are predominantly metaluminous to low peraluminous whereas the biotite‐muscovite granites have a peraluminous nature. Potassium enrichment at the expense of calcium in these rocks reflects a derivation from crustal sources by partial melting in the presence of a volatile system. Radiometric investigation showed high abundances of U (up to 38 ppm) and Th (up to 26 ppm) in biotite‐muscovite granites relative to biotite granites (up to 5 ppm U and 18 ppm Th). Radioactive anomalies furthermore have been recorded in parts of biotite‐muscovite granites that were affected by the faults (up to 116 ppm eU and 97 ppm eTh). Consequently, biotite‐muscovite granites form a potentially fertile source for uranium mineralization.
Abstract Unusual deposits formed by corundum are described from two separate pegmatitic veins in the Hafafit-Nugrus area of the South Eastern Desert of Egypt. Other related minerals are described too. The vein-type of corundum at Locality 1 (Vein 1) crosscuts through exposed rocks of an ophiolitic mélange, whereas at Locality 2 (Vein 2), it crosscuts through exposed serpentinised ultramafic rocks. The main minerals in Vein 1 are plagioclase, corundum, grossular, phlogopite, muscovite and clinochlore, while almandine, xenotime-(Y), allanite-(Ce), zircon, Cr-rich spinel, apatite, titanite, fergusonite-(Y), meta-ankoleite, U-rich thorite (uranothorite), carbonate and illite are the accessories. In Vein 2, the main minerals are plagioclase, corundum, phlogopite and chlorite, while clinochlore, euxenite-(Y), Nb-rich rutile, almandine, xenotime-(Y), allanite-(Ce), zircon, spinel, apatite, titanite, kasolite, dickite, illite, carbonate, antigorite and talc are accessories. The two types of corundum veins differ in their concentrations of Th, U, Zr, Nb, Ta, REE, Y and Li in whole-rock compositions. Field observations, mineralogy and chemical analyses of samples from the two veins of corundum deposits, as well as concentrations of chromophore elements in corundum crystals, suggest metasomatic origins. The present study suggests that the two types of corundum veins formed at different ages from different residual magmas that underwent in-situ hybridisation with the host rocks.