Isotope dilution with a modified alkali fusion procedure and negative thermal ion mass spectrometry yields highly precise and accurate Re-Os ages for molybdenite from two well-studied molybdenite deposits in the East Qinling molybdenum belt, China. Individual Re-Os ages carry a 2Sigma precision of + or - 0.40 to 0.57 percent which includes a 0.31 percent uncertainty in the 187 Re decay constant. For the unusual carbonatite-hosted Mo-Pb deposit at Huanglongpu, the weighted average of seven analyses yields an age of 221.5 + or - 0.3 (0.15%) Ma. The weighted average of two analyses of molybdenite from a porphyry Mo deposit at Jinduicheng, about 10 km to the southwest, yields an age of 138.4 + or - 0.5 (0.39%) Ma. These data provide uncertainties an order of magnitude less than previous Re-Os ages. Molybdenite Re-Os ages are slightly older than ages obtained by other isotopic methods for genetically related host-rock and vein material. It appears that the direct dating of sulfide, rather than altered host and vein material, may be critical to acquiring the correct age for mineralization.The East Qinling molybdenum belt is part of a larger east-west-trending zone that marks the suture between two major cratonic blocks. Consequently, the belt was a site for Early-Middle Triassic compression (Indosinian orogeny) followed by Jurassic-Cretaceous extension (Yenshanian orogeny). We suggest that the Huanglongpu and Jinduicheng deposits provide an analogue for processes that may have been important in generating major molybdenum deposits in the Colorado mineral belt. In Colorado, Late Cretaceous (Laramide) compression-related, alkalic magmatism was followed by Tertiary (Rio Grande) extension-related, granitic magmatism and the development of major Climax-type porphyry Mo deposits. In particular, the Jinduicheng deposit appears to be a nearly perfect match for Climax-type mineralization in Colorado. In contrast, the older Huanglongpu deposit may record a mechanism whereby molybdenum is concentrated in the lower crust. In both the Qinling molybdenum belt and the Colorado mineral belt, a time gap of about 50 to 80 m.y. separates alkalic magmatism and exceptionally evolved granitic magmatism.
Black shales of the basal Lower Cambrian Niutitang Formation, southeast China, host a regionally distributed concordant, several centimeter-thick, sulfide layer which displays extreme metal enrichment, i.e., Mo-NiSe-Re-Os-As-Hg-Sb >1,000 times enriched and Ag-Au-Pt-Pd >100 times enriched over bulk continental crust. Mineable portions have about 5.5 wt percent Mo, 3.5 wt percent Ni, and 1 g/t PGE + Au. A six-point 187 Os/ 188 Os versus 187 Re/ 188 Os isochron on molybdenum-nickel ore samples defines an age of 541 ± 16 Ma (2σ) with an initial 187 Os/ 188 Os ratio of 0.78 ± 0.19. This age is in agreement with the depositional age of the black shale host; the initial ratio is close to present-day seawater. The sulfide layer/average seawater metal ratio is on the order of 10 6 to 10 8 , about 10 to 100 times higher than that for the black shale host and for average metalliferous black shale. Synsedimentary metal enrichment from seawater under anoxic (sulfate-reducing) conditions appears likely but requires an unusually low sedimentation rate and/or high replenishment rate of fresh seawater to the marine basin. The paleogeographic setting of the Lower Cambrian continental margin of the Yangtze craton indicates local basins controlled by synsedimentary rifting. Stagnant water episodically replenished by upwelling oxidized seawater is thought to be responsible for the formation of the polymetallic sulfide layer and of phosphorite, barite, and sapropelic “stone coal” (combustible black shale) beds.
The Zhongdian area in Yunnan, southwestern China, located at the southern end of the Yidun volcano-magmatic arc that was formed during the Triassic westward subduction of the Gaze-Litang Ocean, hosts numerous Triassic large porphyry and skarn deposits. The arc suffered Jurassic to Cretaceous arc-continental orogenic collision and Cenozoic intracontinental strike-slip shearing. The Hongshan Cu (–Mo–Pb–Zn) deposit is potentially a large deposit and contains two ore types: 1) predominant layered skarn Cu–(Pb–Zn) ores along marble-hornfels contacts; and 2) minor crosscutting vein-type Cu–Mo mineralization. Previous research forwards a two-stage genetic model without sufficient dating evidence, supposing the skarn mineralization is related to the Triassic calc-alkalic intrusions and the vein-type mineralization related to Cretaceous quartz monzonite porphyries. Re–Os dating of molybdenite from vein-type ores and quartz monzonite porphyries and that of pyrrhotite from skarn ores are presented here to constrain the mineralization age and rebuild the genetic model. Analyses of eight molybdenite samples yield an isochron age of 79.7 ± 3.1 Ma (MSWD = 9.2) for the vein-type mineralization and a model age of 81.9 ± 1.1 Ma for the quartz monzonite porphyries. Isotope data on seven pyrrhotite samples from the skarn ores yield an isochron age of 79 ± 16 Ma z(MSWD = 8.4). The Re–Os ages for the two ore types are concordant within analytical errors, indicating that the Hongshan deposit was formed in the Late Cretaceous. Elevated Re contents in molybdenite (13.65 to 63.91 μg/g) and extremely radiogenic initial 187Os/188Os ratios in pyrrhotite (0.7673 to 0.8184; weighted average 0.796 ± 0.038), together with elevated γOs values in pyrrhotite (507 to 547; average 528) imply a significant crustal component in the ore-forming materials that was likely derived from a lower crustal reservoir. Combined with the tectonic evolution of the Zhongdian area and geochemical characteristics of corresponding intrusions, the ages of mineralization obtained in this study indicate that the Hongshan deposit was formed in a post-collision setting with a genetic relationship to the emplacement of the quartz monzonite porphyry. These results provide significant new information for the study and exploration of the Late Cretaceous metallogeny in the Zhongdian area.
The Dapingliang Cu deposit is located at the eastern part of the Kuruketage block in NW China. Igneous rocks are widely distributed in the district and skarn are formed at the contact zone between igneous rocks and the carbonates of Beiyixi Formation. The ore is distributed in the skarn. Zircon U-Pb isotopic ages of the plagiogranite, which is related to the Cu deposit, indicate that the lower and upper intercept ages are 826 ± 23 Ma and 1886 ± 61 Ma, respectively. The lower intercept age corresponds to a weighted mean 206Pb/238U age of 826 ± 13 Ma, yielded by ten analysis points. The upper intercept age may represent the age of the source rock, from which the plagiogranite originated. Re-Os isotopic analysis of six molybdenite samples from L7 orebody in the Dapingliang deposit shows an isochron age of 830 ± 26 Ma, which corresponds to the weighted mean model age of 829.4 ± 9.5 Ma. The concordant ages obtained by zircon U-Pb dating and molybdenite Re-Os dating are compatible with the skarn-type mineralization at Dapingling and confirm that the deposit formed during the Tarim orogeny.
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