The Keyue Sb–Pb–Zn–Ag deposit is a medium-sized deposit near the super-large Zhaxikang Sb–Pb–Zn–Ag deposit within the North Himalayan Metallogenic Belt (NHMB). These two deposits, separated only by a regional NS-trending normal fault with strike-slip properties, have similar ore-forming elements and mineral associations, ore characteristics, ore paragenetic sequence, wall rocks, and H–O–S–Pb isotopic and fluid inclusion characteristics. Herein, we establish Zn–Cd isotopic connections between these two proximal ore deposits. As a means to draw comparisons, we conducted Zn–Cd isotopic research of the Keyue deposit to compare it with that of the Zhaxikang deposit. Both the δ66Zn and δ114/110Cd values of sphalerite from the Keyue deposit display a temporally decreasing trend from stage 2 (δ66Zn: 0.15‰–0.58‰, average value = 0.29‰; δ114/110Cd: –0.23‰ to 0.38‰, average value = 0.05‰) to stage 3 (δ66Zn: –0.28‰ to 0.12‰, average value = –0.06‰; δ114/110Cd: –0.38‰ to –0.32‰, average value = –0.35‰), which was also found in the Zhaxikang deposit. A simple three-phase separation distillation models this temporally decreasing trend, which resulted from the Zn–Cd isotopic fractionation that is most likely related to vapor–liquid-solid dynamics of ore-forming fluid. This distillation model was further augmented by the general geochemical characteristics and fluid inclusion data. A congruence among several geological and geochemical evidence points to the genetic relationships between these two ore deposits that have the same metal origins and experience similar ore formation processes. A three-phase separation model has been established to imitate this evolution, which reveals substantial exploration potential for Zn–Cd at depths below 4100 m within the Zhaxikang orefield. In summary, Zn–Cd isotopes have the potential to trace metal sources, monitor fluid evolution, constrain ore formation, and provide insights into mineral exploration.
A redox reaction in which Sn2+ oxidizes to Sn4+ is thought to occur during the precipitation of cassiterite (SnO2) and stannite (Cu2FeSnS4) from high-temperature hydrothermal solutions. In four stanniferous regions with differing mineralization environments (South Dakota, U.S.A.; Cornwall, England; Erzgebirge, Germany/Czech Republic; Andean tin belt, Bolivia), the tin isotope composition in stannite (mean value δ124Sn = –1.47 ± 0.54‰, n = 21) is consistently more fractionated toward negative values than that of paragenetically earlier cassiterite (mean value δ124Sn = 0.48 ± 0.62‰, n = 50). Given the oxidation-dependent mechanism for cassiterite precipitation, this isotopic shift is most likely attributable to the oxidation of Sn in solution; precipitation of heavy-Sn-enriched cassiterite results in residual dissolved Sn with lighter isotopic composition, which is expressed in the negative δ124Sn values of later-formed stannite. Equally important is that the mean values for the cassiterite from the various deposits are slightly different and may indicate that the initial Sn isotope composition in early-formed cassiterite relates to variations in the source or magmatic processes. Therefore, the Sn isotopes may provide information on both redox reactions and petrologic sources and processes.
The Kerman copper belt in Iran contains a number of important porphyry copper deposits, including Sarkuh and Iju. Molybdenite Re-Os isotope dating of the Sarkuh and Iju porphyry copper deposits shows that mineralization occurred at 15.14 ± 0.08 and 9.8 ± 0.06 Ma, respectively. Compared with the previous Re-Os dating of molybdenite in the region, it is revealed that Cu mineralization was an ongoing process in an arc setting during the Miocene. The available zircon dates of the granitic rocks from the Sarkuh (15.18 ± 0.43 Ma) and Iju (9.27 ± 0.50 Ma) porphyry copper deposits indicate that the mineralization occurred contemporaneously with the emplacement of collision-related ore-hosting porphyries. The Re content (1,715.40 ppm) of molybdenite and the δ^(34)S_(CDT) values (0.05‰) of pyrite-chalcopyrite from Iju are consistent with its origin of sulfur and metals from a dominantly mantle source. However, the lower Re content (302.21 ppm) of molybdenite and higher δ^(34)S_(CDT) values (3.20‰) of pyrite-chalcopyrite from Sarkuh suggest additional contributions from crustal materials. It is likely that the younger porphyry copper deposits in the Kerman copper belt, such as Iju, are related to the greater contribution of postcollisional mantle-derived magmas, while the older deposits (e.g., Sarkuh) were formed during the collisional event at the Oligocene-Miocene interval where the magma had some additions from the lower crustal melts generated during crustal thickening.
Abstract Ultramafic xenoliths from southeastern Arizona, USA, provide evidence for Cu‐isotope heterogeneity in the lithospheric mantle. We report new data on Type I (Cr‐, Mg‐rich) peridotites, but also the first Cu‐isotope data for Fe‐Ti‐Al‐rich Type II pyroxenite (±amphibole) xenoliths. Whole rock δ 65 Cu values of the pyroxenites and cryptically metasomatized Type I lherzolites range to isotopically heavier compositions than asthenospheric mantle (i.e., up to +1.44‰ and +1.12‰, respectively, vs. ∼ 0‰ ± 0.2‰). Copper leached from the xenoliths using aqua regia, assumed to be hosted in interstitial sulfides, is even more variable (δ 65 Cu −0.78 to +3.88‰), indicating considerable isotopic heterogeneity within individual samples. Host basalts have low δ 65 Cu (−0.23‰ to −1.30‰), so basalt—xenolith interactions are not responsible for the compositional variations observed. While mass‐dependent fractionation may be partly responsible, metasomatism by fluids derived from recycled crustal materials is the predominant control on isotopic variations observed. Amphibole megacrysts and amphiboles separated from Type II amphibole‐bearing clinopyroxenite have normal, mantle‐like 18 O/ 16 O ratios but H‐isotope compositions (δ 2 H SMOW −82‰ to −45‰) that range between that of nominally anhydrous mantle (−80 ± 10‰) and seawater (0‰). Host basalts are also enriched in 34 S relative to depleted asthenospheric mantle, having δ 34 S CDT values up to +8‰, i.e., compositions commonly attributed to a component of recycled seawater or hydrated oceanic crust. These new data suggest that formation of Type II metasomes in the lithospheric mantle beneath the Basin and Range Province was associated with subduction of the Farallon plate and not alkali basalt magmatism associated with Basin and Range extension.
Abstract This paper presents Ag, Cu, and Pb isotopes for five silver and 10 copper artefacts found in the first intact pre‐Columbian tomb of the Wari culture female elite at Castillo de Huarmey, Peru. Ag and Cu isotope data indicate that the metals were extracted from primary, hypogene ore deposits. Most of the Pb isotope data for the Castillo de Huarmey artefacts correlate with the core Wari site of Conchopata, suggesting utilization of ores from similar deposits. The observed spread in Pb isotopes can be explained by the utilization of regional ores with highly variable Pb isotopes, such as the Julcani deposit. Alternatively, the linear nature of the Pb isotope results obtained for these samples may also be a result of the mixing of ores from different deposits or the re‐smelting of metals. Some of the Pb isotope results also indicate imports from other remote regions, providing evidence for long‐distance interactions on a vast regional scale, in the northern (North Coast of Peru) and southern (Southern Peru and Potosi region in Bolivia) spheres of influence of the Wari Empire and the Tiwanaku state.
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