Abstract The exhumation mechanism of high‐pressure ( HP ) and ultrahigh‐pressure ( UHP ) eclogites formed by the subduction of oceanic crust (hereafter referred to as oceanic eclogites) is one of the primary uncertainties associated with the subduction factory. The phase relations and densities of eclogites with MORB compositions are modelled using thermodynamic calculations over a P–T range of 1–4 GPa and 400–800 °C, respectively, in the NCKFMASHTO ( Na 2 O – CaO – K 2 O – FeO – MgO – Al 2 O 3 – SiO 2 – H 2 O – TiO 2 – Fe 2 O 3 ) system. Our modelling suggests that the mineral assemblages, mineral proportions and density of oceanic crust subducted along a cold P–T path are quite different from those of crust subducted along a warm P–T path, and that the density of oceanic eclogites is largely controlled by the stability of low‐density hydrous minerals, such as lawsonite, chlorite, glaucophane and talc. Along a cold subduction P–T path with a geotherm of ~6 °C km −1 , lawsonite is always present at 1.1 to >4.0 GPa, and chlorite, glaucophane and talc can be stable at pressures of up to 2.3, 2.6 and 3.6 GPa respectively. Along such a P–T path, the density of subducted oceanic crust is always lower than that of the surrounding mantle at depths shallower than 110–120 km (< 3.3–3.6 GPa). However, along a warm subduction P–T path with a geotherm of ~10 °C km −1 , the P–T path is outside the stability field of lawsonite, and the hydrous minerals of chlorite, epidote and amphibole break down completely into dry dense minerals at relatively lower pressures of 1.5, 1.85 and 1.9 GPa respectively. Along such a warm subduction P–T path, the subducted oceanic crust becomes denser than the surrounding mantle at depths >60 km (>1.8 GPa). Oceanic eclogites with high H 2 O content, oxygen fugacity, bulk‐rock X Mg [ = MgO /( MgO + FeO )], X Al [ = Al 2 O 3 /( Al 2 O 3 + MgO + FeO )] and low X Ca [ = CaO /( CaO + MgO + FeO + Na 2 O )] are likely suitable for exhumation, which is consistent with the bulk‐rock compositions of the natural oceanic eclogites on the Earth's surface. On the basis of natural observations and our calculations, it is suggested that beyond depths around 110–120 km oceanic eclogites are not light enough and/or there are no blueschists to compensate the negative buoyancy of the oceanic crust, therefore explaining the lack of oceanic eclogites returned from ultradeep mantle (>120 km) to the Earth's surface. The exhumed light–cold–hydrous oceanic eclogites may have decoupled from the top part of the sinking slab at shallow depths in the forearc region and are exhumed inside the serpentinized subduction channel, whereas the dense–hot–dry eclogites may be retained in the sinking slab and recycled into deeper mantle.
ABSTRACT Raman spectroscopy is used for the first time for distinguishing igneous zircons from metamorphic zircons. Igneous zircons, especially those from granitic rocks, commonly show a Raman peak at 1461 Δcm−1 with significant intensity, whereas metamorphic zircons do not show this peak or the peak is very weak. This may be related to the rare‐earth element (REE) contents in zircon. Thus, Raman spectroscopy provides a new, fast and non‐destructive means for investigating the structure and origin of zircons.
Abstract The Xugou garnet peridotite body of the southern Sulu ultrahigh‐pressure (UHP) terrane is enclosed in felsic gneiss, bounded by faults, and consists of harzburgite and lenses of garnet clinopyroxenite and eclogite. The peridotite is composed of variable amounts of olivine (Fo 91 ), enstatite (En 92−93 ), garnet (Alm 20−23 Prp 53−58 Knr 6−9 Grs 12−18 ), diopside and rare chromite. The ultramafic protolith has a depleted residual mantle composition, indicated by a high‐Mg number, very low CaO, Al 2 O 3 and total REE contents compared to primary mantle and other Sulu peridotites. Most garnet (Prp 44−58 ) clinopyroxenites are foliated. Except for rare kyanite‐bearing eclogitic bands, most eclogites contain a simple assemblage of garnet (Alm 29−34 Prp 32−50 Grs 15−39 ) + omphacite (Jd 24−36 ) + minor rutile. Clinopyroxenite and eclogite exhibit LREE‐depleted and LREE‐enriched patterns, respectively, but both have flat HREE patterns. Normalized La, Sm and Yb contents indicate that both eclogite and garnet clinopyroxenite formed by high‐pressure crystal accumulation (+ variable trapped melt) from melts resulting from two‐stage partial melting of a mantle source. Recrystallized textures and P–T estimates of 780–870 °C, 5–7 GPa and a metamorphic age of 231 ± 11 Ma indicate that both mafic and ultramafic protoliths experienced Triassic UHP metamorphism in the P–T forbidden zone with an extremely low thermal gradient (< 5 °C km −1 ), and multistage retrograde recrystallization during exhumation. Develop of prehnite veins in clinopyroxenite, eclogite, felsic blocks and country rock gneiss, and replacements of eclogitic minerals by prehnite, albite, white mica, and K‐feldspar indicate low‐temperature metasomatism.
The Yangkou gabbro-to-granite complex is a petrotectonic unit of the Su-Lu ultrahigh-pressure (UHP) metamorphic terrane in eastern China. It consists of lherzolites, metagabbro–eclogites, metagranodiorites and deformed granites. Whether or not the felsic members of the complex have undergone UHP metamorphism as is recorded in the metagabbro–eclogites is significant to understanding the relationship between eclogite and host rock. The metagabbro–eclogites have low ε Nd (220 Ma) values (−17 to −12) at the time of UHP metamorphism, indicating that their protoliths are old mafic intrusive rocks emplaced in a continental domain. Geochemical and isotopic studies for the Yangkou unit suggest that the protoliths of the unit (except eclogites) represent a cogenetic magmatic suite, produced by differentiation of a mafic parental magma. The parental magma was derived from melting of a long-term enriched mantle, and was emplaced into a crustal level during continental extension at c . 700–800 Ma. The cogenetic relationship for the protoliths of the unit suggests that the metagranodiorites and deformed granites were also subducted to extreme mantle depths along with the metagabbro–eclogites at c . 220 Ma. The lherzolites, however, are genetically not related to the mafic protoliths; they represent ‘mantle xenoliths’ of tectonic origin.
Abstract Omphacite and garnet coronas around amphibole occur in amphibolites in the Hong'an area, western Dabie Mountains, China. These amphibolites consist of an epidote–amphibolite facies assemblage of amphibole, garnet, albite, clinozoisite, paragonite, ilmenite and quartz, which is incompletely overprinted by an eclogite facies assemblage of garnet, omphacite and rutile. Coronas around amphibole can be divided into three types: an omphacite corona; a garnet–omphacite–rutile corona; and, a garnet–omphacite corona with less rutile. Chemographic analysis for local reaction domains in combination with petrographical observations show that reactions Amp + Ab + Pg = Omp +Czo + Qtz + H 2 O, and Amp + Ab = Omp ± Czo + Qtz + H 2 O may lead to the development of omphacite coronas. The garnet–omphacite–rutile corona was formed from the reaction Amp + Ab + Czo + Ilm ± Qtz = Omp + Grt + Rt + H 2 O. In garnet–omphacite coronas, the garnet corona grew during an early stage of epidote amphibolite facies metamorphism, whereas omphacite probably formed by the reactions forming the omphacite corona during the eclogite facies stage. It is estimated that these reactions occurred at 0.8–1.4 GPa and 480–610 °C using the garnet–clinopyroxene thermometer and omphacite barometer in the presence of albite.
Coesite eclogite is associated with metagranitoid in a 50×100 m 2 outcrop within the regionally developed amphibolite-facies Su-Lu orthogneiss. Primary intrusive relationships between the metagranitoid and basic rocks and bulk-chemistry analyses show that together they represent a composite igneous body that has subsequently been strongly deformed and metamorphosed. The presence of rutile, sodie pyroxene, corona garnet, and possible pseudomorphs after coesite all suggest very high pressures of metamorphism in the metagranitoid. This is the first documented occurrence of ultrahigh-pressure (UHP) metagranitoid outside of the European Alps. The existence of UHP metagranitoid shows that low density of rocks does not necessarily prevent subduction to mantle depths. Even at peak metamorphic conditions the UHP composite igneous body reported here would have a bulk density less than the mantle. Buoyancy forces may, therefore, have been important in the early exhumation of this unit. Other outcrops of coesite eclogite in the Su-Lu region may also have been originally metamorphosed along with low-density granitoid rocks.
Abstract Granulites from Huangtuling in the North Dabie metamorphic core complex in eastern China preserve rare mineralogical and mineral chemical evidence for multistage metamorphism related to Palaeoproterozoic metamorphic processes, Triassic continental subduction‐collision and Cretaceous collapse of the Dabie Orogen. Six stages of metamorphism are resolved, based on detailed mineralogical and petrological studies: (I) amphibolite facies (6.3–7.0 kbar, 520–550 °C); (II) high‐pressure/high‐temperature granulite facies (12–15.5 kbar, 920–980 °C); (III) cooling and decompression (4.8–6.0 kbar, 630–700 °C); (IV) medium‐pressure granulite facies (7.7–9.0 kbar, 690–790 °C); (V) low‐pressure/high‐temperature granulite facies (4.0–4.7 kbar, 860–920 °C); (VI) retrograde greenschist facies overprint (1–2 kbar, 340–370 °C). The P – T history derived in this study and existing geochronological data indicate that the Huangtuling granulite records two cycles of orogenic crustal thickening events. The earlier three stages of metamorphism define a clockwise P – T path, implying crustal thickening and thinning events, possibly related to the assembly and breakup of the Columbia Supercontinent at c . 2000 Ma. Stage IV metamorphism indicates another crustal thickening event, which is attributed to Triassic subduction/collision between the Yangtze and Sino‐Korean Cratons. The dry lower crustal granulite persisted metastably during the Triassic subduction/collision because of the lack of hydrous fluid and deformation. Stage V metamorphism records the Cretaceous collapse of the Dabie Orogen, possibly due to asthenosphere upwelling or removal of the lithospheric mantle resulting in heating of the granulite and partial melting of the North Dabie metamorphic core complex. Comparison of the Huangtuling granulite in North Dabie and the high‐pressure–ultrahigh‐pressure metamorphic rocks in South Dabie indicates that the subducted upper (South Dabie) and lower (North Dabie) continental crusts underwent contrasting tectonometamorphic evolution during continental subduction‐collision and orogenic collapse.
SIMS data demonstrate Archean (2.9 to 2.7 Ga) and Paleoproterozoic (1991 ± 43 Ma) ages for rounded detrital zircon cores and unzoned rims respectively in a graulite sample collected from Huangtuling, Dabie-Sulu orogenic belt, China. The granulite rocks in this locality have pelitic compositions and represent an exposure of the northern margin of the Yangtze Craton. The rounded zircon cores show oscillatory zoning and have Th/U ratios (0.17 − 0.78) systematically higher than those of the unzoned luminescent rims (0.005 − 0.03). The age of the detrital zircon cores and whole rock Nd isotope model age suggest that the Huangtuling granulite was possibly derived from a provenance dominated by Archean rocks similar to the Kongling Complex exposed 200 km in the southwest. Multiple phases of metamorphism have been identified for the granulites, with the dominant granulite-facies mineral assemblage, defining an early clock-wise metamorphic P-T path. Orthopyroxene, plagioclase and whole-rock material define a linear trend in a ^147^Sm/^144^Nd − ^143^Nd/^144^Nd diagram, corresponding to an age of 1926 ± 146 Ma. This result and the U-Pb data for the zircon rims suggest that a collisional event may have occurred along the northern margin of the Yangtze Craton at ∼2.0 Ga, inviting further study on whether the Yangtze Craton was involved in the assembly of the recently-proposed Paleo-Mesoproterozoic supercontinent Columbia.
Abstract Lawsonite is an important hydrous mineral that is stable at low‐temperature ( LT ) and high‐ to ultrahigh‐pressure ( HP – UHP ) conditions in subducted slabs. The occurrence/absence of lawsonite in eclogite is a significant constraint for the construction of the metamorphic, tectonic and fluid/melt evolution histories of an HP–UHP terrane. However, lawsonite is very rarely preserved in natural eclogites, and accurate judgment of its former existence is a significant challenge for petrologists. At present, whether lawsonite has ever existed in lawsonite‐absent eclogite is mainly judged by (i) pseudomorphs after lawsonite, and (ii) phase equilibria modelling. In this study, major element and trace‐element distributions in multistage minerals were examined in the G anghe lawsonite‐absent UHP eclogite in the D abie UHP terrane, eastern C hina. This work demonstrates that the whole‐rock Sr and light rare earth elements ( LREE s) are mainly dominated by epidote; other minerals (garnet, omphacite, quartz, kyanite, barroisite, phengite and accessory minerals) play a very limited role in the Sr and LREE s budgets. Two stages of epidote, which have noticeably different Sr and LREE s contents, were recognized in the eclogite: (i) Epidote porphyroblasts (Ep‐P core), which are suspected to be the pseudomorphic mineral after lawsonite, contain significantly high Sr (7200–10 300 ppm) and LREE s (160–1300 ppm for La). (ii) An earlier stage epidote (Ep‐In core) occurs as inclusions in matrix omphacite, or in omphacite inclusions in the suspected pseudomorphic minerals after lawsonite ( SPMAL ); this early epidote has significantly lower Sr (990–1890 ppm, average 1495 ppm, n = 17) and LREE s contents (60–110 ppm for La, average 91 ppm, n = 17). All of the existing early‐stage minerals predating the SPMAL have very low contents of Sr and LREE s, and the total amounts of these elements in the early‐stage minerals do not balance those in the SPMAL . This indicates that a missing Ca‐, Al‐, Sr‐ and LREE ‐rich mineral, which was previously in equilibrium with the early‐stage minerals, likely existed in the G anghe eclogite. On the basis of the mineral geochemistry and phase equilibria modelling, we confirm that the missing mineral cannot be anything but lawsonite. This study indicates that examining the mass (im)balance of Sr and LREE s between multistage HP – UHP epidote can be used as a potential method to confirm the previous existence of lawsonite in lawsonite‐absent eclogite.
Abstract High‐pressure granulites are generally characterized by the absence of orthopyroxene. However, orthopyroxene is reported in a few high‐pressure, felsic–metapelitic granulites, such as the Huangtuling felsic high‐pressure granulite in the North Dabie metamorphic core complex in east‐central China, which rarely preserves the high‐pressure granulite facies assemblage of garnet + orthopyroxene + biotite + plagioclase + K‐feldspar + quartz. To investigate the effects of bulk‐rock composition on the stability of orthopyroxene‐bearing, high‐pressure granulite facies assemblages in the NCKFMASHTO (Na 2 O–CaO–K 2 O–FeO–MgO–Al 2 O 3 –SiO 2 –H 2 O–TiO 2 –Fe 2 O 3 ) system, a series of P – T – X pseudosections based on the melt‐reintegrated composition of the Huangtuling felsic high‐pressure granulite were constructed. Calculations demonstrate that the orthopyroxene‐bearing, high‐pressure granulite facies assemblages are restricted to low X Al [Al 2 O 3 /(Na 2 O + CaO + K 2 O + FeO + MgO + Al 2 O 3 ) < 0.35, mole proportion] or high X Mg [MgO/(MgO + FeO) > 0.85] felsic–metapelitic rock types. This study also reveals that the X Al values in the residual felsic–metapelitic, high‐pressure granulites could be significantly reduced by a high proportion of melt loss. We suggest that orthopyroxene‐bearing, high‐pressure granulites occur in residual overthickened crustal basement under continental subduction–collision zones and arc–continent collision belts.
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