The chemical equilibrium distribution of 69 elements between gas and melt is modeled for bulk silicate Earth (BSE) material from 1000 - 4500 K and 1e-6 to 100 bar. The BSE melt is modeled as a non-ideal solution and the effects of different activity coefficients and ideal solution are studied. Results include 50% condensation temperatures, major gases of each element, and oxygen fugacity (fO2) of dry and wet BSE material. The dry BSE model excludes H, C, N, F, Cl, Br, I, S, Se, Te. The wet BSE model includes H and the other volatiles. Key conclusions are much higher condensation temperatures in silicate vapor than in solar composition gas at the same total P, a different condensation sequence in silicate vapor than in solar composition gas, good agreement between different activity coefficient models except for the alkalis, agreement, where overlap exists, with prior published work, condensation of Re, Mo, W, Ru, Os oxides instead of metals, a stability field for Ni-rich metal as reported by Lock et al. (2018), agreement between ideal solution (from this work and from Lock et al. 2018) and real solution condensation temperatures for elements with minor deviations from ideality in the oxide melt, similar 50% condensation temperatures, within a few degrees, in the dry and wet BSE models for the major elements Al, Ca, Fe, Mg, Si, and the minor elements Co, Cr, Li, Mn, Ti, V, and much lower 50 percent condensation temperatures for elements such as B, Cu, K, Na, Pb, Rb, which form halide, hydroxide, sulfide, selenide, telluride and oxyhalide gases. The latter results are preliminary because the poorly known solubilities and activities of volatile elements in silicate melts must be considered for the correct equilibrium distribution, condensation temperatures and mass balance of F, Cl, Br, I, H, S, Se and Te bearing species between melt and vapor (abridged).
We continue a systematic study of chemical abundances of the strontium filament found in the ejecta of η Carinae. To this end we interpret the emission spectrum of Sc ii and Cr ii using multilevel non-local thermodynamic equilibrium models. Since the atomic data for these ions were previously unavailable, we carry out ab initio calculations of radiative transition rates and electron impact excitation rate coefficients. The observed spectrum is consistent with an electron density of the order of 107 cm−3 and a temperature between 6000 and 7000 K, conditions previously determined from [Ni ii], [Ti ii] and [Sr ii] diagnostics. The observed spectrum indicates an abundance of Sc relative to Ni more than 40 times the solar value, while the Cr/Ni abundance ratio is roughly solar. Various scenarios of depletion and dust destruction are suggested to explain such abnormal abundances.
Abstract— Condensation calculations for C‐rich circumstellar envelopes are used to model the condensation sequence of C, TiC, and SiC, and trace‐element patterns observed in circumstellar SiC grains. Some properties of carbon star envelopes are briefly discussed, and condensation temperatures for major and trace elements are computed for a wide array of total pressure, C/O‐ratios, and s‐process elemental abundances. The comparison of calculated patterns for trace‐element solid solutions in SiC with the different observed patterns measured by Amari et al. (1995) yields an association of the grains to at least three different groups of carbon stars.
