Abstract The extent to which solid‐state volume diffusion modifies rare earth element (REE) abundances in accessory minerals during high‐temperature metamorphism governs our ability to link recorded trace‐element compositions to particular thermal events. We model diffusion of REE in zircon under different temperature–time conditions and show that, for both short‐lived (e.g. 1100°C for 1–5 Ma) and more prolonged (e.g. 1050°C for 10–30 Ma or 1000°C for 200 Ma) episodes of ultra‐high‐temperature (UHT) metamorphism, REE diffusion in igneous zircon is sufficiently rapid for REE in a ~50‐μm grain to equilibrate with the new metamorphic mineral assemblage of the host rock. By contrast, unless diffusion is accelerated by recrystallization, the presence of fluids or other processes at temperatures below 900°C zircon will largely retain its original pre‐metamorphic REE abundance pattern, even when the thermal event is long lived (≥100 Ma). Where volume diffusion is dominant, for instance, in the absence of a fluid phase, the sensitivity of REE mobility to temperature can help constrain the temperature–time path of high‐grade metamorphic rocks. Modelling of well‐characterized natural samples from the regional‐scale aureole surrounding the Rogaland Igneous Complex (RIC) in SW Norway shows that variations in REE concentration patterns in zircon indicate a T–t evolution that is consistent with independent P–T–t estimates for regional metamorphism based on phase equilibrium modelling (850–950°C at 7–8 kbar for ~100 Ma). Greater modification of REE abundance patterns in zircons within 2 km of the RIC contact, however, indicates that UHT conditions persisted for ~150 Ma close to the intrusion, with a temperature of ~1100°C for 1–5 Ma at the RIC contact. Thermal modelling suggests that the inferred T–t histories of samples from different distances from the RIC contact are best explained if the complex was emplaced incrementally over 1–5 Ma.
Abstract Garnet grains from an intensely metasomatized mid‐crustal shear zone in the Reynolds Range, central Australia, exhibit a diverse assortment of textural and compositional characteristics that provide important insights into the geochemical effects of fluid–rock interaction. Electron microprobe X‐ray maps and major element profiles, in situ secondary ion mass spectrometry oxygen isotope analyses, and U–Pb and Sm–Nd geochronology are used to reconstruct their thermal, temporal and fluid evolution. These techniques reveal a detailed sequence of garnet growth, re‐equilibration and dissolution during intracontinental reworking associated with the Ordovician–Carboniferous (450–300 Ma) Alice Springs Orogeny. A euhedral garnet porphyroblast displays bell‐shaped major element profiles diagnostic of prograde growth zoning during shear zone burial. Coexisting granulitic garnet porphyroclasts inherited from precursor wall rocks show extensive cation re‐equilibration assisted by fracturing and fragmentation. Oxygen isotope variations in the former are inversely correlated with the molar proportion of grossular, suggesting that isotopic fractionation is linked to Ca substitution. The latter generally show close correspondence to the isotopic composition of their precursor, indicating slow intergranular diffusion of O relative to Fe 2+ , Mg and Mn. Peak metamorphism associated with shearing (∼550 °C; 5.0–6.5 kbar) occurred at c. 360 Ma, followed by rapid exhumation and cooling. Progressive Mn enrichment in rim domains indicates that the retrograde evolution caused partial garnet dissolution. Accompanying intra‐mineral porosity production then stimulated limited oxygen isotope exchange between relict granulitic garnet grains and adjacent metasomatic biotite, resulting in increased garnet δ 18 O values over length scales <200 μ m. Spatially restricted oxygen interdiffusion was thus facilitated by increased fluid access to reaction interfaces. The concentration of Ca in channelled fracture networks suggests that its mobility was enhanced by a similar mechanism. In contrast, the intergranular diffusion of Fe 2+ , Mg and Mn was rock‐wide under the same P–T regime, as demonstrated by a lack of local spatial variations in the re‐equilibration of these components. The extraction of detailed reaction histories from garnet must therefore take into account the variable length‐ and time‐scales of elemental and isotopic exchange, particularly where the involvement of a fluid phase enhances the possibility of measureable resetting profiles being generated for slowly diffusing components such as Ca and O, even at low ambient temperatures and relatively fast cooling rates.
Multi-mineral petrochronology can effectively track changes in the thermochemical environment experienced by rocks during metamorphism. We demonstrate this concept using garnet–chlorite schists from the Walter-Outalpa Shear Zone of the southern Curnamona Province, South Australia, which reveal a cryptic and protracted (c. 39 Myr) record of high thermal gradient metamorphism. Petrochronological data including in situ monazite U–Pb and garnet Lu–Hf and Sm–Nd dating suggest elevated geotherms were persistent between at least c. 519–480 Ma, throughout the duration of garnet growth. Additional in situ xenotime U–Pb dating implies that partial garnet breakdown occurred between c. 480–440 Ma, likely induced by fluid-rock interaction or exhumation. Although metamorphism temporally overlaps with the timing of the regional Delamerian Orogeny (c. 520–480 Ma), the thermal mechanism to sustain elevated temperatures has remained enigmatic. One-dimensional thermal models are used to appraise the role of radiogenic heat production in driving the observed high thermal gradient metamorphism. The models reveal that with only modest crustal thickening during orogenesis, the endogenous radiogenic heat production hosted within the basement rocks could plausibly provide the thermal impetus for metamorphism.
Palaeoproterozoic to early Mesoproterozoic metamorphic rocks of the Curnamona Province, southern Australia, are crosscut by a system of regional-scale shear zones that locally dominate the terrain. Combined metamorphic and geochronological data from localities across the southern Curnamona Province indicate that the peak metamorphic shear-zone assemblages formed during the Cambrian (c. 500 Ma) Delamerian Orogeny, and not during the waning stages of the c. 1600 Ma Olarian Orogeny as has been previously asserted. A combination of monazite chemical U–Th–Pb and garnet Sm–Nd geochronology indicates that shear-zone fabrics formed between 497 and 517 Ma. Peak metamorphic conditions obtained from prograde garnet–staurolite–biotite–muscovite–chlorite–quartz assemblages are between 530 and 600 °C at pressures of around 5 kbar. The apparent absence of significant up-pressure prograde paths recorded by the mineral assemblages, together with modest (10–20%) Delamerian shortening, suggests that attainment of burial to depths of around 18 km was largely a function of pre-Delamerian sedimentation over the interval from c. 700 to 530 Ma. The spatial association between the pattern of basement metamorphism and reactivation during the Delamerian Orogeny is interpreted to reflect in part the distribution of pre-Delamerian sedimentation, and highlights the potential importance of pre-orogenic processes such as basin development in controlling the style and pattern of later terrain reactivation and reworking.
Abstract The Mozambique Ocean closed as Gondwana formed. Its suture has been identified in Madagascar (Betsimisaraka suture), but its continuation, into India, is controversial. The Palghat‐Cauvery shear system appears an ideal candidate as it: (i) lies along strike of the Betsimisaraka suture in Gondwana; (ii) forms a high‐pressure granulite belt; and (iii) separates crustal domains with different geological histories. However, existing age constraints have been used to suggest that the structure is Archaean/Palaeoproterozoic. Here we date metamorphic zircons using secondary ion mass spectrometry (535.0 ± 4.9 Ma) and monazites using electron probe micro‐analysis (537 ± 9, 532 ± 8, 525 ± 10 Ma). No evidence for an earlier metamorphic event was found. The identification of Palghat‐Cauvery high‐pressure metamorphism as Cambrian, and recognition that it bounds crustal domains of contrasting origin, points to it being the southern continuation of the Betsimisaraka suture and southern margin of Neoproterozoic India.
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