Ages derived from various isotope systems in high-pressure (HP) rocks of the western Tianshan orogen of NW China have been interpreted as evidence for late Carboniferous and/or Triassic collision of the accretionary margin of the Central Asian Orogenic Belt (CAOB) with the Tarim Craton. In order to elucidate this controversy, we present new *P-T* data as well as Sm-Nd and ^40^Ar/^39^Ar cooling ages for an eclogite sample from Atbashi in the accretionary mélange of the South Tianshan suture in Kyrgyzstan, some 500 km along strike to the west of the controversial locality in the upper Akeyazhi River Valley in NW China. A clockwise *P-T* path for the eclogite with peak pressures of 18 to 24 kbar at 520 to 600 °C is consistent with near-isothermal decompression and exhumation in a subduction zone before collision of the CAOB with the Tarim Craton. Geochemical data and an initial εNd value of ∼ +9 suggest an N-MORB protolith for the eclogite. The high-pressure mineral assemblage of the eclogite yielded a statistically robust Sm-Nd isochron age of 319 ± 4 Ma (2σ, 5 data points, MSWD = 0.4) for equilibration and closure of the Sm-Nd system during HP metamorphism. ^40^Ar/^39^Ar dating of phengite from the same sample yielded a cooling age of 316 ± 3 Ma (2σ) implying rapid exhumation. Docking of the Tarim Craton with the southern margin of the Middle Tianshan-North Tianshan blocks in Kyrgyzstan during the late Carboniferous is supported by widespread emplacement of A-type granitoids of early Permian age that suggest a setting of consolidated crust. An unmetamorphosed and little deformed molasse-type conglomerate of latest Carboniferous age, overlying the HP rocks, indicates that HP metamorphism, exhumation, and exposure of the HP mélange occurred from 320 to ∼300 Ma. The detrital zircon age spectrum of a metagraywacke sample from the accretionary mélange suggests sources in the Tarim Craton and/or from the Middle and North Tianshan that possibly comprise rifted blocks from Tarim.
Abstract In subduction zones, materials on Earth’s surface can be transported to the deep crust or mantle, but the exact mechanisms and the nature of the recycled materials are not fully understood. Here, we report a set of migmatites from western Yangtze Block, China. These migmatites have similar bulk compositions as forearc sediments. Zircon age distribution and Hf–O isotopes indicate that the precursors of the sediments were predominantly derived from juvenile arc crust itself. Using phase equilibria modelling, we show that the sediments experienced high temperature-to-pressure ratio metamorphism and were most likely transported to deep arc crust by intracrustal thrust faults. By dating the magmatic zircon cores and overgrowth rims, we find that the entire rock cycle, from arc magmatism, to weathering at the surface, then to burial and remelting in the deep crust, took place within ~ 10 Ma. Our findings highlight thrust faults as an efficient recycling channel in compressional arcs and endogenic recycling as an important mechanism driving internal redistribution and differentiation of arc crust.
Abstract: The Trans‐North China Orogen (TNCO) was a Paleoproterozic continent‐continent collisional belt along which the Eastern and Western Blocks amalgamated to form a coherent North China Craton (NCC). Recent geological, structural, geochemical and isotopic data show that the orogen was a continental margin or Japan‐type arc along the western margin of the Eastern Block, which was separated from the Western Block by an old ocean, with eastward‐directed subduction of the oceanic lithosphere beneath the western margin of the Eastern Block. At 2550‐2520 Ma, the deep subduction caused partial melting of the medium‐lower crust, producing copious granitoid magma that was intruded into the upper levels of the crust to form granitoid plutons in the low‐ to medium‐grade granite‐greenstone terranes. At 2530‐2520 Ma, subduction of the oceanic lithosphere caused partial melting of the mantle wedge, which led to underplating of mafic magma in the lower crust and widespread mafic and minor felsic volcanism in the arc, forming part of the greenstone assemblages. Extension driven by widespread mafic to felsic volcanism led to the development of back‐arc and/or intra‐arc basins in the orogen. At 2520‐2475 Ma, the subduction caused further partial melting of the lower crust to form large amounts of tonalitic‐trondhjemitic‐granodioritic (TTG) magmatism. At this time following further extension of back‐arc basins, episodic granitoid magmatism occurred, resulting in the emplacement of 2360 Ma, ∼2250 Ma 2110–21760 Ma and ∼2050 Ma granites in the orogen. Contemporary volcano‐sedimentary rocks developed in the back‐arc or intra‐arc basins. At 2150‐1920 Ma, the orogen underwent several extensional events, possibly due to subduction of an oceanic ridge, leading to emplacement of mafic dykes that were subsequently metamorphosed to amphibolites and medium‐ to high‐pressure mafic granulites. At 1880‐1820 Ma, the ocean between the Eastern and Western Blocks was completely consumed by subduction, and the closing of the ocean led to the continent‐arc‐continent collision, which caused large‐scale thrusting and isoclinal folds and transported some of the rocks into the lower crustal levels or upper mantle to form granulites or eclogites. Peak metamorphism was followed by exhumation/uplift, resulting in widespread development of asymmetric folds and symplectic textures in the rocks.
Abstract The Ruwai skarn deposit is the largest polymetallic skarn deposit in Borneo and is located in the Schwaner Mountains. The skarns and massive orebodies are hosted in marble of the Jurassic Ketapang Complex, which was intruded by Cretaceous Sukadana granitoids. The prograde-stage garnet and retrograde-stage titanite yielded U-Pb ages of 97.0 ± 1.8 to 94.2 ± 10.3 Ma and 96.0 ± 2.9 to 95.0 ± 2.0 Ma, respectively. These ages are similar to Re-Os ages obtained on sulfides (96.0 ± 2.3 Ma) and magnetite (99.3 ± 3.6 Ma). The U-Pb zircon ages reveal that magmatism at Ruwai occurred in three phases, including the Early Cretaceous (ca. 145.7 and 106.7–105.7 Ma; andesite-dacite), Late Cretaceous (ca. 99.7–97.1 Ma; diorite-granodiorite), and late Miocene (ca. 10.94–9.51 Ma; diorite-dolerite). Based on geochemical and stable isotopic data (C-O-S) the Ruwai skarn ores are interpreted to have formed from oxidized fluids at ca. 160 to 670°C. The ore-forming fluids and metals were mostly magmatic in origin but with significant crustal input. Ruwai skarn mineralization occurred in the Late Cretaceous, associated with Paleo-Pacific subduction beneath Sundaland after the Southwest Borneo accretion. Ruwai is the first occurrence of Cretaceous mineralization recognized in the Central Borneo metallogenic belt.
Abstract Primary water and oxygen isotope composition are important tools in tracing magma source and evolution. Metamictization of zircon due to U-Th radioactive decay may introduce external secondary water to the crystal, thereby masking the primary water and oxygen isotope signature. Recently, Raman-based screening has been established to select the low-degree metamict zircons. However, such an approach may not be appropriate for ancient samples, in which nearly all zircons are metamict. It was reported that thermal annealing can potentially heal crystals and retrieve primary water content and δ18O information from metamict zircons, given the weaker hydrogen bond of secondary water than that of primary water. Heating experiments at temperatures of 200–1000 °C over a period of 2–10 h reveal that annealing can effectively recover primary water and oxygen isotopes from metamict zircons. Primary water in crystalline and metamict zircons remains intact when heated at <700 °C, while secondary water can be effectively expelled from metamict zircons when heated at 600 °C for >4 h, which represent the optimal annealing treatment condition. Hydrothermally altered zircon is an exception. It only yields the minimum estimate of its primary water contents at 600 °C over a period of >4 h, probably due to partial primary water loss during metamictization for hydrothermal zircons. Moreover, the proportion of low-δ18O (<4.7‰) zircon grains that may be influenced by secondary water dropped from ~21% at <600 °C to ~9% when annealed at >700 °C. This study therefore provides the basis for applying zircon water and δ18O proxies to geologically ancient samples.